Reaction of the hindered, substituted electron-withdrawing cyclopentadienyl zirconium complex [Zr{C5H2(SiMe3)3}2(Me)2] with CO leads, via the acyl intermediate [Zr{C5H2(SiMe3)3}2(COMe)(Me)] detected during the course of the reaction, to the metal hydride enolate [Zr{C5H2(SiMe3)3}2(H){OC(Me)![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CH2}].
R. Choukroun, B. Douziech and F. Soleil, J. Chem. Soc., Chem. Commun., 1995, 2017 DOI: 10.1039/C39950002017
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