Issue 24, 2024

Polyoxometalate-mediated syntheses of three structurally new silver clusters

Abstract

Three structurally new polyoxometalate-templated silver clusters, homometallic [(SiW9O34)@Ag24(iPrS)11(DPPP)6Cl]2(SiW12O40) (Ag24), heterometallic [(SiW9O34)@Ag22Cu(iPrS)11(DPPP)6Cl](SbF6)2 (Ag22Cu) and {Ag16(iPrS)6(DPPP)8(CH3COO)4[Co4(OH)3(H2O)SiW9O33]2}·(CH3CN)4 (Ag16Co8) (iPrS = isopropanethiolate, DPPP = 1,3-bis(diphenylphosphino)propane, SbF6 = hexafluoroantimonate) have been successfully synthesized using a facile solvothermal approach. The introduction of copper and cobalt ions can induce obvious changes in the molecular configuration of the obtained clusters, leading to distinct temperature-dependent photoluminescence and photothermal conversion properties.

Graphical abstract: Polyoxometalate-mediated syntheses of three structurally new silver clusters

Supplementary files

Article information

Article type
Communication
Submitted
09 ሜይ 2024
Accepted
25 ሜይ 2024
First published
27 ሜይ 2024

Nanoscale, 2024,16, 11518-11523

Polyoxometalate-mediated syntheses of three structurally new silver clusters

J. Zhang, Y. Dong, L. Deng, M. Chi, Y. Feng, M. Zhao, H. Lv and G. Yang, Nanoscale, 2024, 16, 11518 DOI: 10.1039/D4NR02016B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements