Influence of donor point modifications on the assembly of chalcogen-bonded organic frameworks†
Brian J.
Eckstein, 
a
Hannah R.
Martin,
a
Arijit
Halder,
a
Michael J.
Melville,
a
C. Michael
McGuirk
*a
a
Hannah R.
Martin,
a
Arijit
Halder,
a
Michael J.
Melville,
a
C. Michael
McGuirk
*a
Abstract
Incremental, single-atom substitutions of Se-based chalcogen bond (Ch-bond) donors with stronger donating Te centers were implemented in two new triptycene tris(1,2,5-chalcogenadiazole) tectons. The appreciably more favorable Ch-bonding ability of the Te-based donors promotes assembly of low-density networks and more stable Ch-bonded organic frameworks (ChOFs).
- This article is part of the themed collection: 2023 Emerging Investigators
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