Two versatile new routes to dinuclear molybdenum dithiolene complexes

(Note: The full text of this document is currently only available in the PDF Version )

Andrew Abbott, Matthew N. Bancroft, Michael J. Morris, Andrew Abbott, Graeme Hogarth and Simon P. Redmond


Abstract

Two routes to the dithiolene complexes [Mo2S(µ-S)2(SCR1[double bond, length half m-dash]CR2S)(η-C5H5)2] starting from the complexes [Mo2(µ-alkyne)(CO)4(η-C5H5)2] are described; in one case the dithiolene ligand is derived from the alkyne, and in the other from a 1,3-dithiole-2-thione reagent.


References

  1. D. Collison, C. D. Garner and J. A. Joule, Chem. Soc. Rev., 1996, 25, 25 RSC.
  2. M. J. Romao, M. Archer, I. Moura, J. J. G. Moura, J. LeGall, R. Engh, M. Schneider, P. Hof and R. Huber, Science, 1995, 270, 1170 CAS; H. Schindelin, C. Kisker, J. Hilton, K. V. Rajagopalan and D. C. Rees, Science, 1996, 272, 1615 CrossRef CAS; M. K. Chan, S. Mukund, A. Kletzin, M. W. W. Adams and D. C. Rees, Science, 1995, 267, 1463 CAS.
  3. J. A. McCleverty, Prog. Inorg. Chem., 1969, 10, 49; R. Eisenberg, Prog. Inorg. Chem., 1970, 12, 295 CAS; R. P. Burns and C. A. McAuliffe, Adv. Inorg. Chem. Radiochem., 1979, 22, 303 Search PubMed; U. T. Mueller-Westerhoff and B. Vance, in Comprehensive Coordination Chemistry, ed. G. Wilkinson, R. D. Gillard and J. A. McCleverty, Pergamon, Oxford, 1987, vol. 2, ch. 16.5 Search PubMed.
  4. H. Adams, N. A. Bailey, S. R. Gay, T. Hamilton and M. J. Morris, J. Organomet. Chem., 1995, 493, C25 CrossRef CAS; H. Adams, N. A. Bailey, S. R. Gay, L. J. Gill, T. Hamilton and M. J. Morris, J. Chem. Soc., Dalton Trans., 1996, 2403; 3341 Search PubMed.
  5. L. D. Tanner, R. C. Haltiwanger, J. Noordik and M. Rakowski DuBois, Inorg. Chem., 1988, 27, 1736 CrossRef CAS; L. D. Tanner, R. C. Haltiwanger and M. Rakowski DuBois, Inorg. Chem., 1988, 27, 1741 CrossRef CAS.
  6. R. B. King and C. A. Eggers, Inorg. Chem., 1968, 7, 340 CrossRef CAS.
  7. G. N. Schrauzer and V. P. Mayweg, J. Am. Chem. Soc., 1965, 87, 3585 CrossRef CAS.
  8. S. Boyde, C. D. Garner, J. A. Joule and D. J. Rowe, J. Chem. Soc., Chem. Commun., 1987, 800 RSC.
  9. J. Fletcher, G. Hogarth and D. A. Tocher, J. Organomet. Chem., 1991, 403, 345 CrossRef CAS; 405, 207; M. L. H. Green, G. Hogarth, P. C. Konidaris and P. Mountford, J. Chem. Soc., Dalton Trans., 1990, 3781 Search PubMed.
  10. H. Adams, M. N. Bancroft and M. J. Morris, Chem. Commun., 1997, 1445 RSC.
  11. C. T. Pedersen, Adv. Heterocycl. Chem., 1982, 31, 63 CAS; Sulfur Rep., 1995, 16, 173 Search PubMed.
  12. G. M. Sheldrick, SHELXTL PLUS program package for structure solution and refinement, version 4.2, Siemens Analytical Instruments Inc., Madison WI, 1990.
Click here to see how this site uses Cookies. View our privacy policy here.