New route to monoorganotin oxides and alkoxides from trialkynylorganotins

(Note: The full text of this document is currently only available in the PDF Version )

Pascale Jaumier, Bernard Jousscaume, Pascale Jaumier, Mohammed Lahcini, François Ribot and Clément Sanchez


Abstract

Functional monoorganotin oxides and alkoxides are synthesised in high yield by hydrolysis or alcoholysis of the corresponding trialkynylorganotins; the hydrolytic behaviour of trialkynylorganotins is the same as for trialkoxyorganotins.


References

  1. C. J. Brinker and G. W. Scherer, Sol–Gel Science, Academic Press, London, 1990 Search PubMed.
  2. H. I. J. Wuang, B. Orler and G. L. Wilkes, Macromolecules, 1987, 20, 1322 CrossRef CAS.
  3. B. M. Novak, Adv. Mater., 1993, 5, 422 CrossRef CAS.
  4. H. Schmidt and B. Seiferling, Mater. Res. Soc. Symp. Proc., 1986, 73, 739 CAS; C. Sanchez and F. Ribot, New J. Chem., 1994, 18, 1007 Search PubMed; U. Schubert, N. Hüsing and A. Lorenz, Chem. Mater., 1995, 7, 2010 CrossRef CAS; D. A. Loy and K. J. Shea, Chem. Rev., 1995, 95, 1431 CrossRef CAS.
  5. F. Ribot, F. Banse, C. Sanchez, M. Lahcini and B. Jousseaume, J. Sol–Gel Sci. Technol., 1997, 8, 529 Search PubMed; F. Ribot, F. Banse and C. Sanchez, Mater. Res. Soc. Symp. Proc., 1994, 346, 121 CAS.
  6. B. Jousseaume, M. Lahcini, M.-C. Rascle, F. Ribot and C. Sanchez, Organometallics, 1995, 14, 685 CrossRef CAS.
  7. I. M. Thomas, US Pat., 3946056, 1976 Search PubMed.
  8. A. G. Davies, L. Smith and P. J. Smith, J. Organomet. Chem., 1972, 39, 279 CrossRef CAS; D. P. Gaur, G. Sivastrata and R. C. Mehrotra, J. Organomet. Chem., 1973, 63, 221 CrossRef CAS.
  9. W. Neumann and F. G. Kleiner, Tetrahedron Lett., 1964, 5, 3779 CrossRef; M. W. Logue, J. Org. Chem., 1982, 47, 2549 CrossRef CAS; B. Jousseaume and P. Villeneuve, Tetrahedron, 1989, 45, 1145 CrossRef CAS.
  10. B. Wrackmeyer, G. Kehr, D. Wettinger and W. Milius, Main Group Met. Chem., 1993, 16, 445 Search PubMed.
  11. P. Jaumier, PhD Thesis, University Bordeaux 1, 1997.
  12. H. Puff and H. Reuter, J. Organomet. Chem., 1989, 373, 173 CrossRef CAS; D. Dakternieks, H. Zhu, E. R. T. Tiekink and R. Colton, J. Organomet. Chem., 1994, 476, 33 CrossRef CAS.
  13. F. Banse, F. Ribot, P. Tolédano, J. Maquet and C. Sanchez, Inorg. Chem., 1995, 34, 6371 CrossRef CAS.
  14. M. Biesemans, R. Willem, S. Damoun, P. Geerlings, M. Lahcini, P. Jaumier and B. Jousseaume, Organometallics, 1996, 15, 2237 CrossRef CAS.
  15. V. S. Zavgorodnii, B. I. Ionin and A. A. Petrov, J. Gen. Chem. USSR, 1967, 37, 898.
  16. J. D. Kennedy, W. McFarlane, P. J. Smith, R. F. M. White and L. Smith, J. Chem. Soc., Perkin Trans. 2, 1973, 1785 RSC.
  17. R. J. P. Corriu, J. J. E. Moreau, P. Thepot and M. Wong Chi Man, Chem. Mater., 1996, 8, 100 CrossRef CAS.
Click here to see how this site uses Cookies. View our privacy policy here.