By summarising recent examples in coordination chemistry, this perspective highlights the advantages of mechanochemistry in tackling synthetic challenges which are impossible for traditional methods.
This review explores sustainable synthetic methodologies, highlighting advances in solvent use, catalysis, raw materials, and flow chemistry for pharmaceutical and agrochemical production.
Herein, we present the state of the art technology on the recycling, reuse, thermal decomposition, and the life cycle assessment of fluoropolymers (FPs, ranging from PTFE and PVDF to various fluorinated copolymers based on VDF and TFE).
We review recent progress in metalloporphyrin-catalyzed fluorinated carbene transfer reactions covering the transfer of various carbene species.
A process to shuttle HF from a fluoroalkane to alkynes has been developed. The consecutive dehydrofluorination and hydrofluorination steps are catalysed by an amorphous zirconium chlorofluoride at room temperature.