Porphyrin-based heterojunction photocatalysts: design principles and applications in solar-to-chemical energy conversion

Haibin Niu, Guopeng Zhu, Shaoqing Zhang, Tianye Wang, Quanying Wang, Xiutao Yang, Xiaoming Li, Feng Zhu, Guangfeng Wu and Hongwen Yu

J. Mater. Chem. A, 2025
DOI: 10.1039/D5TA05146K

Sub-m-benziporphyrin: a subcarbaporphyrinoid and its BIII complex with an unprecedented planar tridentate 14π-aromatic network

Le Liu, Shuangji Song, Jiyeon Lee, Yutao Rao, Ling Xu, Mingbo Zhou, Bangshao Yin, Juwon Oh, Jiwon Kim, Atsuhiro Osuka and Jianxin Song

Chem. Sci., 2025, 16, 1155
DOI: 10.1039/D4SC07199A

Magnetic transition and work function modulation of Ti2C MXene via porphine adsorption

Pınar Kaya, Çağıl Kaderoğlu, Ethem Aktürk and Handan Arkın

Phys. Chem. Chem. Phys., 2025, 27, 14829
DOI: 10.1039/D5CP00622H

Advances and prospects of porphyrin derivatives in the energy field

Mingfa Xie, Jinyuan Liu, Lianghong Dai, Hongjian Peng and Youqing Xie

RSC Adv., 2023, 13, 24699
DOI: 10.1039/D3RA04345B

Organic polymer facilitated CO2 photoreduction: a minireview

Wenfeng Zhao, Qinmei Ge, Hu Li, Nan Jiang, Shangwei Chen, Song Yang and Hang Cong

Polym. Chem., 2023, 14, 4877
DOI: 10.1039/D3PY01060K

21‐Carba‐23‐selenaporphyrinoid Dyads—An Azepine Unit as a Merging Motif

Anna Berlicka, Paulina Foryś‐Martowłos, Michał J. Białek, Katarzyna Stasiak, Aleksandra Walczak, Agnieszka Wójcik, Agata Białońska and Lechosław Latos‐Grażyński

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202314925

Corrins and porphyrins: two of nature’s pigments of life

Helder M. Marques

Journal of Coordination Chemistry, 2024, 77, 1161
DOI: 10.1080/00958972.2024.2343109

Isomeric “N-confused” porphyrins: DFT model chemistry study on aza-carbaporphyrins

Oleg V. Mikhailov and Denis V. Chachkov

J. Porphyrins Phthalocyanines, 2025, 29, 101
DOI: 10.1142/S1088424625500026

Dipyrroethanes/Dipyrroethenes: New Precursors for Porphyrinoids

Vratta Grover and Mangalampalli Ravikanth

Top Curr Chem (Z), 2025, 383
DOI: 10.1007/s41061-025-00506-y

Synthesis of Pyrrole‐Sharing Fused Porphyrinoid Hybrids by Post‐fabrication of Ni(II) Porphyrins

Lili Zi, Li Liu, Mingbo Zhou, Le Liu, Boyu Xiao, Ling Xu, Yutao Rao, Bangshao Yin, Jianxin Song and Atsuhiro Osuka

Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202319005

Synthesis of Vanadyl Complexes of N-Confused Porphyrins and Their Bromoperoxidase-like Catalytic Activity

Rajesh Kumar, Ved Prakash and Muniappan Sankar

Inorg. Chem., 2024, 63, 12506
DOI: 10.1021/acs.inorgchem.4c01222

Amine-Release Annulation of Enaminones: Bimetallic Co-Catalytic Synthesis of Cyclopentadienes from Alkynes

Kai Chen, Jie Lv, Jie Chen, Jian Zhang, Ling Li, Min Zhao and Yaojia Jiang

Org. Lett., 2023, 25, 4688
DOI: 10.1021/acs.orglett.3c01568

Synthesis, Reactivity and Aromatic Characteristics of Porphyrinoids Derived from N-Alkylcarbaporphyrin-2-Carbaldehydes: Isolation of Nickel(II) and Palladium(II) Complexes, Weakly Diatropic 21-Oxycarbaporphyrins and Strongly Aromatic Trioxycarbaporphyrins

Kimberly Le, Deyaa I. AbuSalim and Timothy D. Lash

J. Org. Chem., 2025, 90, 202
DOI: 10.1021/acs.joc.4c02145

meso‐Free Porphyrinoids

Takayuki Tanaka, Osamu Iwanaga and Atsuhiro Osuka

Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202500215

Size‐ and charge‐matching effect between porphyrin core and central metal on the stability of cuprous ion

Qiuhua Liu, Junhao Gao, Qin Lin, Borong Liao, Qian Zhang and Zaichun Zhou

Applied Organom Chemis, 2024, 38
DOI: 10.1002/aoc.7318

Abnormal Anti‐Kasha Emission and TADF in Anionic Cycloarylenes

Jianwei Liang, Lingyun Zhu, Yuanping Li, Gang Xu, Haixiang Han, Yuanming Li and Zheng Zhou

Angew Chem Int Ed, 2025
DOI: 10.1002/anie.202512344

Synthesis, Spectral and Theoretical Studies of Phenothiazine Embedded Pentaphyrins(2.1.1.1.1)

Neha Tripathi and Mangalampalli Ravikanth

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401921

Synthesis of Pyrrole‐Sharing Fused Porphyrinoid Hybrids by Post‐fabrication of Ni(II) Porphyrins

Lili Zi, Li Liu, Mingbo Zhou, Le Liu, Boyu Xiao, Ling Xu, Yutao Rao, Bangshao Yin, Jianxin Song and Atsuhiro Osuka

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202319005

Investigation of gas-sensitive properties of N-confused porphyrin-like graphene composites: A viewpoint of first principle

Yuxiu Wang, Yuxuan Zhan, Zhong Xie, Cuicui Sun and Chunhua Yang

Chemical Physics, 2025, 591, 112546
DOI: 10.1016/j.chemphys.2024.112546

Tying a knot between crown ethers and porphyrins

Maksym Matviyishyn and Bartosz Szyszko

Beilstein J. Org. Chem., 2023, 19, 1630
DOI: 10.3762/bjoc.19.120

Metal-centred planar [15]annulenes

Binbin Xu, Dafa Chen, Kaidong Ruan, Ming Luo, Yuanting Cai, Jia Qiu, Wenhao Zhou, Bula Cao, Zhenyang Lin, Jonathan L. Sessler and Haiping Xia

Nature, 2025, 641, 106
DOI: 10.1038/s41586-025-08841-2

Regioselective oxidation of carbaporphyrinoid systems

Timothy D. Lash

J. Porphyrins Phthalocyanines, 2025, 29, 557
DOI: 10.1142/S1088424625300058

21‐Carba‐23‐selenaporphyrinoid Dyads—An Azepine Unit as a Merging Motif

Anna Berlicka, Paulina Foryś‐Martowłos, Michał J. Białek, Katarzyna Stasiak, Aleksandra Walczak, Agnieszka Wójcik, Agata Białońska and Lechosław Latos‐Grażyński

Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202314925

From Porphyrin-Like Rings to High-Density Single-Atom Catalytic Sites: Unveiling the Superiority of p-C2N for Bifunctional Oxygen Electrocatalysis

Mengyi Luo, Xinyong Cai, Yuxiang Ni, Yuanzheng Chen, Chunsheng Guo and Hongyan Wang

ACS Appl. Mater. Interfaces, 2024, 16, 807
DOI: 10.1021/acsami.3c15264

A Doubly meso‐α Linked N‐Confused Porphyrin Tape Silver(III) Complex Comprising an Antiaromatic Pyrrolo[2,3‐f]indole Segment

Akito Nakai, Osamu Iwanaga, Takayuki Tanaka and Atsuhiro Osuka

Chemistry An Asian Journal, 2025, 20
DOI: 10.1002/asia.202401144

Pyridine‐Fused Bis(azacorrole)s: Easily Accessible NIR III Absorbing Cation Radicals and Biradicaloids of Antiaromatic Ground State

Sha Li, Shaowei Zhang, Xiaofang Li, Oskar Smaga, Kinga Szydełko, Miłosz Pawlicki and Piotr J. Chmielewski

Advanced Science, 2025, 12
DOI: 10.1002/advs.202416223

Nanographene-Oxy Radical Stabilized by a Carbaporphyrin Framework

Haodan He, Jaehyeok Ryu, Zhaohui Zong, Jiyeon Lee, Tae Hun Heo, Juwon Oh, Jiwon Kim, Jonathan L. Sessler and Xian-Sheng Ke

J. Am. Chem. Soc., 2025, 147, 29602
DOI: 10.1021/jacs.5c11048

Cobalt‐Assisted α‐Activation of Ketones, Their Arylation and Keto‐Enol Equilibrium Confined into a Macrocycle

Kacper Szymanowski, Wiktoria Bara and Michał J. Białek

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202500906

Complexes of N‐Confused Porphyrin Derivatives as Ortho‐Metallating Ligands. Synthesis, Structure, Redox Properties, and Chirality

Sebastian Koniarz, Kinga Szydełko, Michał J. Białek, Karolina Hurej and Piotr J. Chmielewski

Advanced Science, 2024, 11
DOI: 10.1002/advs.202306696

A Janus carbaporphyrin pseudo-dimer

Haodan He, Jiyeon Lee, Zhaohui Zong, Jiwon Kim, Vincent M. Lynch, Juwon Oh, Dongho Kim, Jonathan L. Sessler and Xian-Sheng Ke

Nat Commun, 2024, 15
DOI: 10.1038/s41467-024-47239-y

In silico catalysis of hydrogen evolution reaction using transition metal loaded oxathiaporphyrin framework as electrocatalyst

Sidra Jabeen, Riaz Hussain, Khalid Mahmood, Muhammad Yar, Ajaz Hussain, Khurshid Ayub and Muhammad Imran

International Journal of Hydrogen Energy, 2025, 165, 150917
DOI: 10.1016/j.ijhydene.2025.150917

Photophysical properties of meso-tetrakis(p-methoxycarbonylphenyl) N-confused porphyrin

Li-Li Wang, Ying-Hong Mu, Wan-Hong Li, Jian-Bin Zhong, Feng Li, Su-Hong Peng, Wei Zhang and Hai-Yang Liu

Journal of Molecular Structure, 2025, 1340, 142536
DOI: 10.1016/j.molstruc.2025.142536

Expanding the Chemistry of Pentafluorophenyl-N-Confused Porphyrin: Diketonate Substitution and Derivatizations at the External 3-C Position of the Inverted Pyrrole Ring

Bhakyaraj Kasi, Belarani Ojha, Wen-Feng Liaw and Chen-Hsiung Hung

ACS Org. Inorg. Au, 2024, 4, 681
DOI: 10.1021/acsorginorgau.4c00065

Abnormal Anti‐Kasha Emission and TADF in Anionic Cycloarylenes

Jianwei Liang, Lingyun Zhu, Yuanping Li, Gang Xu, Haixiang Han, Yuanming Li and Zheng Zhou

Angewandte Chemie, 2025
DOI: 10.1002/ange.202512344

Tuning the Photophysical Properties of Nickel and Zinc Complexes of N-Confused Tetraphenylporphyrin via Trans–Cis Isomerization

Eleftherios Papamichalis, Ioannis D. Petsalakis and Demeter Tzeli

J. Phys. Chem. A, 2025, 129, 5942
DOI: 10.1021/acs.jpca.5c02035

Thieno[3,2‐b]thiophene Incorporated Redox Active 22π and 34π Core‐Modified Expanded Isophlorinoids

Hosahalli S. Udaya and Venkataramanarao G. Anand

Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202403480

Bis(10‐oxacorrole) with Fused Pyridine as a Linker: Synthesis, Structure, and Interaction between the Subunits in the Neutral, Mono‐, and Dicationic States

Qin Liu, Sha Li, Guoru Chen, Xiaofang Li, Aleksandra Gałązka, Michał J. Białek and Piotr J. Chmielewski

Chemistry A European J, 2025, 31
DOI: 10.1002/chem.202501085

Coordination immobilization of palladium ions in the novel three-dimensional cerium porphyrin metal-organic framework for enhanced photocatalytic carbon dioxide reduction

Yuxuan Qi, Zhiquan Cai, Yi-Si Feng, Junru Wang, Zhenhong Dai and Zhifei Cheng

Journal of Colloid and Interface Science, 2025, 700, 138528
DOI: 10.1016/j.jcis.2025.138528

The Intracavity Extension of 28-Hetero-2,7-naphthiporphyrins in Reactions with Alkylamines

Katarzyna Ślusarek, Jędrzej P. Perdek, Agata Białońska, Rafał A. Grzelczak and Bartosz Szyszko

Org. Lett., 2023, 25, 4735
DOI: 10.1021/acs.orglett.3c01715

Three Oxidation States of Cobalt(I/II/III) Complexes by Thiaporphyrin

Fang Wang, Zi-Bin Zhong, Ri-Xin Jia, Kang Xing, Ronghui Cao, Feng Bai and Peng-Cheng Duan

Inorg. Chem., 2024, 63, 7233
DOI: 10.1021/acs.inorgchem.3c04491

Linear Extension of Carbaporphyrin Chromophores: Synthesis, Protonation, and Metalation of Anthro[2,3-b]carbaporphyrins: Evidence for 30π-Electron Aromatic Circuits in a Palladium(II) Complex

Melissa A. Mathius, Justin M. Chhoeun, Riley H. Kaufman, Deyaa I. AbuSalim and Timothy D. Lash

J. Org. Chem., 2024, 89, 124
DOI: 10.1021/acs.joc.3c01839

Pyrrole-Sharing Fused Hybrids of Porphyrins and N-Confused Azaporphyrins

Li Liu, Jiali Liu, Lili Zi, Mingbo Zhou, Ling Xu, Yutao Rao, Bangshao Yin, Tomohiro Higashino, Atsuhiro Osuka and Jianxin Song

Org. Lett., 2025, 27, 8088
DOI: 10.1021/acs.orglett.5c02461

Catalytic oxidation of cyclohexene and thioanisole by oxovanadium N-confused porphyrins

Bhakyaraj Kasi, Su-Hong Peng, Ram Ambre, Sung-Chi Lin, Tzu-Tso Chen, Tanmoy Pain, Kai-Chun Hsu, Wen-Feng Liaw, Belarani Ojha and Chen-Hsiung Hung

J. Porphyrins Phthalocyanines, 2025, 29, 229
DOI: 10.1142/S1088424625500191

43,44,47,48‐Tetrathiaoctaphyrin(2.1.1.1.2.1.1.1) and its Organometallic bis‐RhIII Complex: Coordination‐Driven Switching of Conformation and Aromaticity

Sumit Sahoo, Marcin A. Majewski, Pallab Chatterjee, Marcin Stępień and Harapriya Rath

ChemistryEurope, 2025
DOI: 10.1002/ceur.202500095