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Visible-light-promoted oxidative halogenation of alkynes

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Chemoselective synthesis of multi-functionalized alkynes and alkenes via transition-metal-free iodination of terminal alkynes

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Divergent synthesis of 3-formylpyrazolo[1,5-a]pyrimidines and methylene-bridged bis(pyrazolo[1,5-a]pyrimidines) using DMSO as a single carbon synthon

Papiya Sikdar, Sourav Das, Sheetal Saini, Sanghapal D. Sawant and Avik Kumar Bagdi

Org. Biomol. Chem., 2025, 23, 7566
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Decarboxylative chlorination of α,β-unsaturated acids

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Application of DMSO as a methylthiolating reagent in organic synthesis

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KF-catalyzed direct thiomethylation of carboxylic acids with DMSO to access methyl thioesters

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Selective difunctionalization of electron-deficient alkynes: access to (E)-2-iodo-3-(methylthio)acrylate

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Review of application of the I2 and dimethyl sulfoxide combined reagent system to aryl methyl ketones for diverse transformations

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DMSO promoted catalyst-free oxidative C–N/C–O couplings towards synthesis of imidazoles and oxazoles

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Iodine and ammonium persulfate mediated activation of DMSO: an approach to N-formylation of amides and synthesis of isatins

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I2/DMSO-mediated oxidative C–C and C–heteroatom bond formation: a sustainable approach to chemical synthesis

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Additive-free oxychlorination of unsaturated C–C bonds with tert-butyl hypochlorite and water

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Org. Biomol. Chem., 2024, 22, 3080
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Halogen bonded metal bis(dithiolene) 2D frameworks

Hadi Hachem, Olivier Jeannin, Marc Fourmigué, Frédéric Barrière and Dominique Lorcy

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Electrohalogenation of organic compounds

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Org. Biomol. Chem., 2021, 19, 2578
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Oxidant- and additive-free simple synthesis of 1,1,2-triiodostyrenes by one-pot decaroboxylative iodination of propiolic acids

Subhankar Ghosh, Rajat Ghosh and Shital K. Chattopadhyay

Tetrahedron Letters, 2020, 61, 152378
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I2‐Mediated Oxidative Amidation of Aryl Methyl Ketones: Synthesis of Primary α‐Ketoamides Using Ammonium Carbamodithioate as Amine Surrogate

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Eur J Org Chem, 2023, 26
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Outstanding lithium storage performance of a copper coordination complex [Cu(DMSO)2]Cl2 as anode material for lithium-ion batteries

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Electrochemical synthesis of α,α-dihaloacetophenones from terminal alkyne derivatives

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Chinese Chemical Letters, 2020, 31, 1855
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Ruthenium‐Catalyzed Intermolecular Cyclization and N‐Methylation of Salicyl N‐Tosylhydrazones

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Eur J Org Chem, 2022, 2022
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Recent Advances in the Synthesis and Applications of α‐Ketothioesters

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A Convenient Iodine‐Promoted Synthesis of α‐Ketothioesters

Zhengzheng Zhao, Pan Gao, Lei Meng, Qingyi Wu and Yu Yuan

ChemistrySelect, 2022, 7
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Methanesulfinylation of Benzyl Halides with Dimethyl Sulfoxide

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J. Org. Chem., 2020, 85, 2752
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Synthetic Access to Aromatic α-Haloketones

Marre Porré, Gianmarco Pisanò, Fady Nahra and Catherine S. J. Cazin

Molecules, 2022, 27, 3583
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Recent Advances of Green Catalytic System I2/DMSO in C–C and C–Heteroatom Bonds Formation

Jia-Qi Wang, Zhen-Yu Zuo and Wei He

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One-pot and metal-free synthesis of 3-arylated-4-nitrophenols via polyfunctionalized cyclohexanones from β-nitrostyrenes

Haruyasu Asahara, Minami Hiraishi and Nagatoshi Nishiwaki

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Nature of the Nucleophilic Oxygenation Reagent Is Key to Acid-Free Gold-Catalyzed Conversion of Terminal and Internal Alkynes to 1,2-Dicarbonyls

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Switching Over of the Chemoselectivity: I2-DMSO-Enabled α,α-Dichlorination of Functionalized Methyl Ketones

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J. Org. Chem., 2022, 87, 15101
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Synthetic Routes Towards the Synthesis of Geminal α‐Difunctionalized Ketones

David P. Day, Jorge A. M. Vargas and Antonio C. B. Burtoloso

The Chemical Record, 2021, 21, 2837
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Visible‐Light‐Induced Oxidative α‐keto‐Dichlorination of Arylalkynes by CuCl2 at Room Temperature

Vaibhav Pramod Charpe, Mahima Gupta and Kuo Chu Hwang

ChemSusChem, 2022, 15
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I2-DMSO Promoted Deaminative Coupling Reactions of Glycine Esters: Access to 5-(Methylthio)pyridazin-3(2H)-ones

Showkat Ahmad Bhat, Mohammad Yaqoob Bhat, Suhail Ahmad Rather, Salman Jameel, Khursheed Ahmad Bhat and Qazi Naveed Ahmed

Org. Lett., 2023, 25, 2382
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Iodine/persulfate-promoted site-selective direct thiolation of quinolones and uracils

Danupat Beukeaw, Medena Noikham and Sirilata Yotphan

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Synthesis of α,α-dibromoketones via oxidative dibromination reaction of readily available alkynes using N-bromo,N-fluorobenzenesulfonamide (BFBSA)

Chunyan Ma, Chaolin Li and Xianjin Yang

Tetrahedron, 2026, 196, 135264
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CuCl2‐Catalyzed α‐Chloroketonation of Aromatic Alkenes via Visible‐Light‐Induced LMCT

Xing‐Xian He, Huan‐Huan Chang, Ying‐Xue Zhao, Xiang‐Jie Li, Sheng‐An Liu, Zhong‐Lin Zang, Cheng‐He Zhou and Gui‐Xin Cai

Chemistry An Asian Journal, 2023, 18
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Radical-Mediated Methylenation of N-Heterocyclic Carboxylic Acids with DMSO to Access Exocyclic Olefinic Azacycles

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Access to α,α-dihaloacetophenones through anodic C C bond cleavage in enaminones

Zhenlei Zhang, Jiusi Yang, Kairui Wu, Renjie Yu, Jiping Bu, Zijun Huang, Shaoke Li and Xiantao Ma

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Employing Arylacetylene as a Diene Precursor and Dienophile: Synthesis of Quinoline via the Povarov Reaction

Xiao-Xiao Yu, Peng Zhao, You Zhou, Chun Huang, Li-Sheng Wang, Yan-Dong Wu and An-Xin Wu

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Reaction of 4-(Alkynyloxy)cyclohexa-2,5-dienones with Dimethyl Sulfoxide: A Catalyst-Free Formation of 6/5/3-Fused Tricyclic Enones

Archana Rai and Utpal Das

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Synthesis of 3‐Methylthioindolesvia Intramolecular Cyclization of 2‐Alkynylanilines Mediated by DMSO/DMSO‐d6 and SOCl2

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HFIP‐Triggered Reduction Radical Coupling of Enamides with Alkynes Towards β‐Keto Alkylamides via H‐Bonding Electron Transfer

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ChemCatChem, 2024, 16
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Microwave-assisted safe and efficient synthesis of α-ketothioesters from acetylenic sulfones and DMSO

Jiayi Wang, Duo Fu and Jiaxi Xu

Journal of Sulfur Chemistry, 2023, 44, 232
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Transformation of Unactivated Alkenes into Iodohydrins and β‐Iodoethers using Iodine‐DMSO as a Reagent Combination

Reetu Reetu, Raghuram Gujjarappa, Yaqoob Ahmad Teli, Mayur Jagdishbhai Patel, Sangita Kalita, Sonali Dash, Susanta Ghanta, Kavya S. Keremane, Virender Singh, Adel El‐marghany and Chandi C. Malakar

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Research on Selective Dehalogenation of α,α,α-Trihalogen (Chloro, Bromo) methyl Ketones Under Electrochemical Conditions

Kanbinuer Nuermaimaiti, Chao Wang, Shiwei Luo and Abudu Rexit Abulikemu

Acta Chimica Sinica, 2023, 81, 582
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Electrochemical Oxidative Functionalization of Arylalkynes: Access to α,α‐Dibromo Aryl Ketones

Dan Wang, Zhaohua Wan, Heng Zhang and Aiwen Lei

Adv Synth Catal, 2021, 363, 1022
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Electrochemical Oxidative Oxydihalogenation of Alkynes for the Synthesis of α,α-Dihaloketones

Xiangtai Meng, Yu Zhang, Jinyue Luo, Fei Wang, Xiaoji Cao and Shenlin Huang

Org. Lett., 2020, 22, 1169
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Electrochemical Methylthiolation of Terminal Alkynes Using Dimethyl Sulfoxide

Tianci Chen, Xiaoxiao Chen, Mingming Yu and Chuan‐Ying Li

ChemElectroChem, 2025, 12
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Direct 1,2‐Oxosulfenylation of Acetylenic Sulfones with DMSO

Duo Fu, Jun Dong, Jiayi Wang and Jiaxi Xu

Asian J Org Chem, 2021, 10, 1756
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Switchable Synthesis of α,α‐Dihalomethyl and α,α,α‐Trihalomethyl Ketones by Metal‐Free Decomposition of Enaminone C=C Double Bond

Yunyun Liu, Jin Xiong, Li Wei and Jie‐Ping Wan

Adv Synth Catal, 2020, 362, 877
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Selectfluor-Mediated Synthesis of β-Acyl Allyl Sulfones/β-Acyl Allyl Benzotriazoles from Ketones/Acetylenes, Aryl Sulfinates/Benzotriazole, and DMSO as a Dual-Carbon Synthon

Saradhi Kalari, Uttam B. Karale and Haridas B. Rode

J. Org. Chem., 2022, 87, 2435
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Oxidative Thioesterification of Alkenes Mediated by 1,3‐Dibromo‐5,5‐dimethylhydantoin and DMSO for the Synthesis of α‐Ketothioesters

Jiawei Hua, Jiaqi Xu, Jia Xu, Bochao Zhou, Dong Zhang, Zhao Yang, Zheng Fang and Kai Guo

Eur J Org Chem, 2019, 2019, 4056
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