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Regioselective B(3,4)–H arylation of o-carboranes by weak amide coordination at room temperature
Yu-Feng Liang, Long Yang, Becky Bongsuiru Jei, Rositha Kuniyil and Lutz Ackermann
Chem. Sci., 2020, 11, 10764
DOI: 10.1039/D0SC01515F

Planarity of terphenyl rings possessing o-carborane cages: turning on intramolecular-charge-transfer-based emission
Hyunhee So, Jea Ho Kim, Ji Hye Lee, Hyonseok Hwang, Duk Keun An and Kang Mun Lee
Chem. Commun., 2019, 55, 14518
DOI: 10.1039/C9CC07729D

Comment on “Bi-functional Li2B12H12 for energy storage and conversion applications: solid-state electrolyte and luminescent down-conversion dye” by J. A. Teprovich Jr, H. Colón-Mercado, A. L. Washington II, P. A. Ward, S. Greenway, D. M. Missimer, H. Hartman, J. Velten, J. H. Christian and R. Zidan, J. Mater. Chem. A, 2015, 3, 22853
M. Paskevicius, A. S. Jakobsen, M. Bregnhøj, B. R. S. Hansen, K. T. Møller, P. R. Ogilby and T. R. Jensen
J. Mater. Chem. A, 2019, 7, 4185
DOI: 10.1039/C8TA10735A

Substitution of the laser borane anti-B18H22 with pyridine: a structural and photophysical study of some unusually structured macropolyhedral boron hydrides
Michael G. S. Londesborough, Jiří Dolanský, Tomáš Jelínek, John D. Kennedy, Ivana Císařová, Robert D. Kennedy, Daniel Roca-Sanjuán, Antonio Francés-Monerris, Kamil Lang and William Clegg
Dalton Trans., 2018, 47, 1709
DOI: 10.1039/C7DT03823B

A stand-alone cobalt bis(dicarbollide) photoredox catalyst epoxidates alkenes in water at extremely low catalyst load
Isabel Guerrero, Clara Viñas, Isabel Romero and Francesc Teixidor
Green Chem., 2021, 23, 10123
DOI: 10.1039/D1GC03119H

Rhodium(iii)-catalyzed dehydrogenative dialkenylation of the monocarba-closo-decaborate cluster by regioselective B–H activation
Xuewei Liang, Yunjun Shen, Kang Zhang, Jiyong Liu and Simon Duttwyler
Chem. Commun., 2018, 54, 12451
DOI: 10.1039/C8CC05983G

Stimuli-responsive solid-state emission from o-carborane–tetraphenylethene dyads induced by twisted intramolecular charge transfer in the crystalline state
Junfeng Li, Chenglong Yang, Xuelei Peng, Ying Chen, Qi Qi, Xiaoyan Luo, Wen-Yong Lai and Wei Huang
J. Mater. Chem. C, 2018, 6, 19
DOI: 10.1039/C7TC03780E

Facile synthesis, aggregation-induced emission, mechano- and thermochromism of o-carborane–tetraphenylethene dyads with a short CH(OH) linker
Tianrui Li, Hao Zhang, Jinling Miao, Chunyue Xu, Yong Nie, Guangning Liu, Guoxin Sun and Xuchuan Jiang
New J. Chem., 2023, 47, 18243
DOI: 10.1039/D3NJ03431C

Dual emission via remote control of molecular rotation of o-carborane in the excited state by the distant substituents in tolane-modified dyads
Kenta Nishino, Kyoya Uemura, Kazuo Tanaka and Yoshiki Chujo
New J. Chem., 2018, 42, 4210
DOI: 10.1039/C7NJ04283C

A facile approach for the synthesis of nido-carborane fused oxazoles via one pot deboronation/cyclization of 9-amide-o-carboranes
Cai-Yan Zhang, Ke Cao, Tao-Tao Xu, Ji Wu, Linhai Jiang and Junxiao Yang
Chem. Commun., 2019, 55, 830
DOI: 10.1039/C8CC07728B

Efficient blue light emitting materials based on m-carborane–anthracene dyads. Structure, photophysics and bioimaging studies
Mahdi Chaari, Zsolt Kelemen, Duane Choquesillo-Lazarte, Nerea Gaztelumendi, Francesc Teixidor, Clara Viñas, Carme Nogués and Rosario Núñez
Biomater. Sci., 2019, 7, 5324
DOI: 10.1039/C9BM00903E

Nanoscale boron carbonitride semiconductors for photoredox catalysis
Meifang Zheng, Wancang Cai, Yuanxing Fang and Xinchen Wang
Nanoscale, 2020, 12, 3593
DOI: 10.1039/C9NR09333H

New insight into the photophysics and reactivity of trigonal and tetrahedral arylboron compounds
Willy G. Santos, João Pina, Douglas H. Burrows, Malcolm D. E. Forbes and Daniel R. Cardoso
Photochem Photobiol Sci, 2016, 15, 1124
DOI: 10.1039/c6pp00169f

Synthesis and self-assembly of a carborane-containing ABC triblock terpolymer: morphology control on a dual-stimuli responsive system
Roberto Fernandez-Alvarez, Eva Hlavatovičová, Krzysztof Rodzeń, Adam Strachota, Sami Kereïche, Pavel Matějíček, Justo Cabrera-González, Rosario Núñez and Mariusz Uchman
Polym. Chem., 2019, 10, 2774
DOI: 10.1039/C9PY00518H

(7,8-Dicarba-nido-undecaboran-7-yl)acetic acid: synthesis of individual enantiomers and the first example of the determination of the absolute configuration of chiral monosubstituted nido-carborane
Dmitry A. Gruzdev, Angelina A. Telegina, Evgeny N. Chulakov, Galina L. Levit and Victor P. Krasnov
New J. Chem., 2022, 46, 17338
DOI: 10.1039/D2NJ02994D

Transition metal-mediated B(4)–H hydroxylation/halogenation of o-carboranes bearing a 2-pyridylsulfenyl ligand
Shu-Ting Guo, Peng-Fei Cui, Run-Ze Yuan and Guo-Xin Jin
Chem. Commun., 2021, 57, 2412
DOI: 10.1039/D0CC08290B

Regioselectivity of Pd-catalyzedo-carborane arylation: a theoretical view
Jiying Liu, Dongmin Fu, Zitong Chen, Tiantian Li, Ling-Bo Qu, Shi-Jun Li, Wenjing Zhang and Yu Lan
Org. Chem. Front., 2022, 9, 1686
DOI: 10.1039/D2QO00046F

Crystal structure of a carborane endo/exo-dianion and its use in the synthesis of ditopic ligands for supramolecular frameworks
Kang Zhang, Yunjun Shen, Jiyong Liu, Bernhard Spingler and Simon Duttwyler
Chem. Commun., 2018, 54, 1698
DOI: 10.1039/C7CC07724F

Photonic materials derived from the [closo-B10H10]2−anion: tuning photophysical properties in [closo-B10H8-1-X-10-(4-Y-NC5H5)]−
Szymon Kapuściński, Mustapha B. Abdulmojeed, Tegan E. Schafer, Anna Pietrzak, Oleksandr Hietsoi, Andrienne C. Friedli and Piotr Kaszyński
Inorg. Chem. Front., 2021, 8, 1066
DOI: 10.1039/D0QI01353F

Luminescent metal complexes featuring photophysically innocent boron cluster ligands
Kent O. Kirlikovali, Jonathan C. Axtell, Alejandra Gonzalez, Alice C. Phung, Saeed I. Khan and Alexander M. Spokoyny
Chem. Sci., 2016, 7, 5132
DOI: 10.1039/C6SC01146B

Bis(pentafluorophenyl)-o-carborane and its arylthio derivatives: synthesis, electrochemistry and optical properties
Naoki Shida, Satoshi Owaki, Hiroshi Eguchi, Takanobu Nishikawa, Ikuyoshi Tomita and Shinsuke Inagi
Dalton Trans., 2020, 49, 12985
DOI: 10.1039/D0DT02205E

A molecular boron cluster-based chromophore with dual emission
Kierstyn P. Anderson, Mary A. Waddington, Gary J. Balaich, Julia M. Stauber, Nicholas A. Bernier, Justin R. Caram, Peter I. Djurovich and Alexander M. Spokoyny
Dalton Trans., 2020, 49, 16245
DOI: 10.1039/D0DT00826E

Electron-donating abilities and luminescence properties of tolane-substituted nido-carboranes
Kenta Nishino, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo
New J. Chem., 2017, 41, 10550
DOI: 10.1039/C7NJ02438J

Tandem [4 + 2]/[2 + 2] cycloaddition of o-carboryne with enynes: facile construction of carborane-fused tricyclics
Jie Zhang and Zuowei Xie
Chem. Sci., 2021, 12, 5616
DOI: 10.1039/D0SC07047E

Tuning the photophysical properties of carboranyl luminophores by closo- to nido-carborane conversion and application to OFF–ON fluoride sensing
Nguyen Van Nghia, Jihun Oh, Surendran Sujith, Jaehoon Jung and Min Hyung Lee
Dalton Trans., 2018, 47, 17441
DOI: 10.1039/C8DT03771J

Carborane bridged ferrocenyl conjugated molecules: synthesis, structure, electrochemistry and photophysical properties
Jian-Feng Yan, Gai-Ge Zhu, Ye Yuan, Cai-Xia Lin, Shu-Ping Huang and Yao-Feng Yuan
New J. Chem., 2020, 44, 7569
DOI: 10.1039/D0NJ00826E

Enhancing the thermally activated delayed fluorescence of nido-carborane-appended triarylboranes by steric modification of the phenylene linker
Surendran Sujith, Eun Bi Nam, Junseong Lee, Sang Uck Lee and Min Hyung Lee
Inorg. Chem. Front., 2020, 7, 3456
DOI: 10.1039/D0QI00535E

Iridium-catalyzed regioselective B(3,6)-dialkenylation or B(4)-alkenylation of o-carboranes via B–H activation and 1,2-carbon migration of alkynes
Huifang Zhang, Ruofei Cheng, Zaozao Qiu and Zuowei Xie
Chem. Commun., 2023, 59, 740
DOI: 10.1039/D2CC05890A

Circularly polarized laser emission in optically active organic dye solutions
Luis Cerdán, Florencio Moreno, Mizuki Johnson, Gilles Muller, Santiago de la Moya and Inmaculada García-Moreno
Phys. Chem. Chem. Phys., 2017, 19, 22088
DOI: 10.1039/C7CP03303F

Synthesis and photophysical properties of a new tetraphenylethylene-o-carborane-based star-shaped molecule
Xiang Li, Qin Zhou, Miao Zhu, Wei Chen, Beibei Wang, Ye Sha and Hong Yan
New J. Chem., 2021, 45, 7496
DOI: 10.1039/D1NJ01207J

Catalytic asymmetric synthesis of carboranylated diols bearing two adjacent stereocenters located at the α,β-position ofo-carborane cage carbon
Hui-Xin Duan, Hao-Nan Li, Yong Yang, Xiao-Jun Wu and You-Qing Wang
Dalton Trans., 2023, 52, 4077
DOI: 10.1039/D3DT00129F

Photoluminescence in m-carborane–anthracene triads: a combined experimental and computational study
Mahdi Chaari, Zsolt Kelemen, José Giner Planas, Francesc Teixidor, Duane Choquesillo-Lazarte, Abdelhamid Ben Salah, Clara Viñas and Rosario Núñez
J. Mater. Chem. C, 2018, 6, 11336
DOI: 10.1039/C8TC03741H

Blue-shifted emission and enhanced quantum efficiency via π-bridge elongation in carbazole–carborane dyads
Zhaojin Wang, Peng Jiang, Tianyu Wang, Graeme J. Moxey, Marie P. Cifuentes, Chi Zhang and Mark G. Humphrey
Phys. Chem. Chem. Phys., 2016, 18, 15719
DOI: 10.1039/C6CP02870E

Alteration of intramolecular electronic transition via deboronation of carbazole-based o-carboranyl compound and intriguing ‘turn-on’ emissive variation
Seok Ho Lee, Min Sik Mun, Mingi Kim, Ji Hye Lee, Hyonseok Hwang, Wonchul Lee and Kang Mun Lee
RSC Adv., 2021, 11, 24057
DOI: 10.1039/D1RA03716A

Thiaborane clusters with an exoskeletal B–H group
Jan Vrána, Josef Holub, Maksim A. Samsonov, Zdeňka Růžičková, Jindřich Fanfrlík, Drahomír Hnyk and Aleš Růžička
Chem. Commun., 2019, 55, 3375
DOI: 10.1039/C9CC00952C

Electrooxidative o-carborane chalcogenations without directing groups: cage activation by copper catalysis at room temperature
Long Yang, Becky Bongsuiru Jei, Alexej Scheremetjew, Binbin Yuan, A. Claudia Stückl and Lutz Ackermann
Chem. Sci., 2021, 12, 12971
DOI: 10.1039/D1SC02905C

Efficient crystallization-induced emission in fluorenyl-tethered carboranes
Zhaojin Wang, Tianyu Wang, Chi Zhang and Mark G. Humphrey
Phys. Chem. Chem. Phys., 2017, 19, 12928
DOI: 10.1039/C7CP02118F

Cage carbon-substitute does matter for aggregation-induced emission features of o-carborane-functionalized anthracene triads
Xueyan Wu, Jixi Guo, Yangjian Quan, Wei Jia, Dianzeng Jia, Yi Chen and Zuowei Xie
J. Mater. Chem. C, 2018, 6, 4140
DOI: 10.1039/C8TC00380G

Apical functionalization of the [closo-B10H10]2− anion: building blocks for modern materials
Litwin Jacob and Piotr Kaszyński
Inorg. Chem. Front., 2026, 13, 2205
DOI: 10.1039/D5QI02162F

Rhodium catalyzed cascade cyclization featuring B–H and C–H activation: one-step construction of carborane-fused N-polyheterocycles
Hairong Lyu, Yangjian Quan and Zuowei Xie
Chem. Sci., 2018, 9, 6390
DOI: 10.1039/C8SC01568F

Palladium-catalyzed intramolecular oxidative annulation: synthesis of o-carboranoxazoles
Hui Rao, Hairui Jia, Zaozao Qiu and Zuowei Xie
Dalton Trans., 2025, 54, 4866
DOI: 10.1039/D5DT00382B

Palladium catalyzed selective arylation of o-carboranes via B(4)–H activation: amide induced regioselectivity reversal
Tao-Tao Xu, Ke Cao, Cai-Yan Zhang, Ji Wu, Linhai Jiang and Junxiao Yang
Chem. Commun., 2018, 54, 13603
DOI: 10.1039/C8CC08193J

2-Phenylpyridine- and 2-(benzo[b]thiophen-2-yl)pyridine-based o-carboranyl compounds: impact of the structural formation of aromatic rings on photophysical properties
Hyomin Jin, Hye Jin Bae, Seonah Kim, Ji Hye Lee, Hyonseok Hwang, Myung Hwan Park and Kang Mun Lee
Dalton Trans., 2019, 48, 1467
DOI: 10.1039/C8DT04367A

Planarity of N-aryl in appended 1,2,4-triazole-based o-carboranyl luminophores: a key factor to control intramolecular charge transfer
Mingi Kim, Chan Hee Ryu, Ju Hyun Hong, Ji Hye Lee, Hyonseok Hwang and Kang Mun Lee
Inorg. Chem. Front., 2020, 7, 4180
DOI: 10.1039/D0QI00915F

Pd-catalyzed selective tetrafunctionalization of diiodo-o-carboranes
Yixiu Ge, Zaozao Qiu and Zuowei Xie
Chem. Commun., 2021, 57, 8071
DOI: 10.1039/D1CC03449A

Synthesis of 9-borafluorene analogues featuring a three-dimensional 1,1′-bis(o-carborane) backbone
Sam Yruegas, Jonathan C. Axtell, Kent O. Kirlikovali, Alexander M. Spokoyny and Caleb D. Martin
Chem. Commun., 2019, 55, 2892
DOI: 10.1039/C8CC10087J

Fluorescent molecular systems based on carborane-perylenediimide conjugates
Ruben Rodriguez-Madrid, Sohini Sinha, Laura Parejo, Jordi Hernando and Rosario Núñez
Dalton Trans., 2024, 53, 17841
DOI: 10.1039/D4DT02477J

Strategic molecular design of closo-ortho-carboranyl luminophores to manifest thermally activated delayed fluorescence
Dong Kyun You, Hyunhee So, Chan Hee Ryu, Mingi Kim and Kang Mun Lee
Chem. Sci., 2021, 12, 8411
DOI: 10.1039/D1SC00791B

Palladium-catalyzed selective B(3)–H arylation of o-carboranes with arylboronic acids at room temperature
Ziyi Yang, Yuanbo Wu, Yatong Fu, Jianxin Yang, Jian Lu and Ju-You Lu
Chem. Commun., 2021, 57, 1655
DOI: 10.1039/D0CC07591D

Controlled functionalization ofo-carboraneviatransition metal catalyzed B–H activation
Yangjian Quan and Zuowei Xie
Chem. Soc. Rev., 2019, 48, 3660
DOI: 10.1039/C9CS00169G

Manipulation of electronic and structural effects on the solid-state emission of multiple linked anthracenyl-o-carborane dyads
Yongdong Ma, Xueyan Wu, Yan Lv, Xiaoping Jin, Huici Shan and Jixi Guo
New J. Chem., 2022, 46, 542
DOI: 10.1039/D1NJ04463J

Solid-state excimer emission ofo-carborane derivatives and applications for stimuli-responsive luminescent materials
Kazuo Tanaka
Dalton Trans., 2024, 53, 9240
DOI: 10.1039/D4DT01072H

Tuning the architectures and luminescence properties of Cu(i) compounds of phenyl and carboranyl pyrazoles: the impact of 2D versus 3D aromatic moieties in the ligand backbone
Joan Soldevila-Sanmartín, Eliseo Ruiz, Duane Choquesillo-Lazarte, Mark E. Light, Clara Viñas, Francesc Teixidor, Rosario Núñez, Josefina Pons and José G. Planas
J. Mater. Chem. C, 2021, 9, 7643
DOI: 10.1039/D1TC01395E

Highly-efficient solid-state emissions of anthracene–o-carborane dyads with various substituents and their thermochromic luminescence properties
Hirofumi Naito, Kenta Nishino, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo
J. Mater. Chem. C, 2017, 5, 10047
DOI: 10.1039/C7TC02682J

Ru(ii) and Ir(iii) phenanthroline-based photosensitisers bearingo-carborane: PDT agents with boron carriers for potential BNCT
Robert Conway-Kenny, Albert Ferrer-Ugalde, Oriol Careta, Xiaoneng Cui, Jianzhang Zhao, Carme Nogués, Rosario Núñez, Justo Cabrera-González and Sylvia M. Draper
Biomater. Sci., 2021, 9, 5691
DOI: 10.1039/D1BM00730K

Carborane–arene fused boracyclic analogues of polycyclic aromatic hydrocarbons accessed by intramolecular borylation
Yijie Li, Masilamani Tamizmani, Manjur O. Akram and Caleb D. Martin
Chem. Sci., 2024, 15, 7568
DOI: 10.1039/D4SC00990H

Ir-catalyzed selective dehydrogenative cross-coupling of aryls with o-carboranes via a mixed directing-group strategy
Yu Chen, Yangjian Quan and Zuowei Xie
Chem. Commun., 2020, 56, 7001
DOI: 10.1039/D0CC02531C

New global minima of 6-vertex dicarboranes: classical but unexpected
Ying-ying Xue and Yi-hong Ding
Chem. Commun., 2019, 55, 6373
DOI: 10.1039/C9CC02557J

Emissions from a triphenylamine–benzothiadiazole–monocarbaborane triad and its applications as a fluorescent chemosensor and a white OLED component
Zhixing Peng, Kang Zhang, Zongwei Huang, Zaibin Wang, Simon Duttwyler, Yanguang Wang and Ping Lu
J. Mater. Chem. C, 2019, 7, 2430
DOI: 10.1039/C8TC06176A

[3-N2-o-C2B10H11][BF4]: a useful synthon for multiple cage boron functionalizations of o-carborane
Da Zhao and Zuowei Xie
Chem. Sci., 2016, 7, 5635
DOI: 10.1039/C6SC01566B

Functionalization of o-carboranes via carboryne intermediates
Zaozao Qiu and Zuowei Xie
Chem. Soc. Rev., 2022, 51, 3164
DOI: 10.1039/D2CS00024E

Exploring the potential energy surface of B4H42−: an exception of the Wade–Mingos rules
Rodrigo Báez-Grez, Alejandro Vásquez-Espinal and Ricardo Pino-Rios
Phys. Chem. Chem. Phys., 2024, 26, 27530
DOI: 10.1039/D4CP03515A

8-Aminoquinoline as a bidentate traceless directing group for Cu-catalyzed selective B(4,5)–H disulfenylation ofo-carboranes
Yu Chen, Yangjian Quan and Zuowei Xie
Chem. Commun., 2020, 56, 12997
DOI: 10.1039/D0CC05207H

Palladium-catalyzed intramolecular aerobic oxidative cross-coupling of BH/CH between o-carborane and arenes
Zhen Wang, Jiahui Yu, Jie Zhang, Dengsong Zhang, Zaozao Qiu and Zuowei Xie
Chem. Sci., 2025, 16, 3705
DOI: 10.1039/D4SC08496A

Dehydrogenative cross-coupling of o-carborane with thiophenes via Ir-catalyzed regioselective cage B–H and C(sp2)–H activation
Yangjian Quan, Hairong Lyu and Zuowei Xie
Chem. Commun., 2017, 53, 4818
DOI: 10.1039/C7CC01485F

Effects of terminal biphenyl ring geometry on the photophysical properties of closo-o-carboranyl–anthracene dyads
Ju Hyun Hong, Sehee Im, Yung Ju Seo, Na Young Kim, Chan Hee Ryu, Mingi Kim and Kang Mun Lee
J. Mater. Chem. C, 2021, 9, 9874
DOI: 10.1039/D1TC02051J

Synthesis, structure and aromaticity of carborane-fused carbo- and heterocycles
Tek Long Chan and Zuowei Xie
Chem. Sci., 2018, 9, 2284
DOI: 10.1039/C7SC04722C

Impact of deboronation on the electronic characteristics of closo-o-carborane: intriguing photophysical changes in triazole-appended carboranyl luminophores
Mingi Kim, Sehee Im, Chan Hee Ryu, Seok Ho Lee, Ju Hyun Hong and Kang Mun Lee
Dalton Trans., 2021, 50, 3207
DOI: 10.1039/D0DT04038J

o-Carborane decorated diboron-embedded multi-resonance TADF compounds featuring narrowband emission
Nhi Ngoc Tuyet Nguyen, Rafi Muhammad Lutfi, Taehwan Lee, Jaehoon Jung and Min Hyung Lee
Inorg. Chem. Front., 2025, 12, 4503
DOI: 10.1039/D5QI00612K

Insights into the effects of substitution position on the photophysics of mono-o-carborane-substituted pyrenes
Seonah Kim, Ji Hye Lee, Hyunhee So, Mingi Kim, Min Sik Mun, Hyonseok Hwang, Myung Hwan Park and Kang Mun Lee
Inorg. Chem. Front., 2020, 7, 2949
DOI: 10.1039/D0QI00563K

Color-tuning and manipulation of the aggregation-induced emission efficiency of o-carborane-tetraphenylethylene dyads through substituted o-carboranes
Miao Zhu, Qin Zhou, He Cheng, Zhihao Meng, Li Xiang, Ye Sha, Hong Yan and Xiang Li
New J. Chem., 2022, 46, 11382
DOI: 10.1039/D2NJ01920E

Efficient access to amides of the carborane carboxylic acid [1-(COOH)–CB11H11]−
Yunjun Shen, Kai Zheng, Rakesh Dontha, Yani Pan, Jiyong Liu and Simon Duttwyler
RSC Adv., 2018, 8, 22447
DOI: 10.1039/C8RA03067G

Catalytic regioselective 3,4-difunctionalization of 3-iodo-o-carborane via Pd migration
Xianren Jiang, Chang-Hua Ding, Zaozao Qiu and Zuowei Xie
Dalton Trans., 2025, 54, 8764
DOI: 10.1039/D5DT00981B

Iridium-catalyzed selective arylation of B(6)–H of 3-aryl-o-carboranes with arylboronic acid via direct B–H activation
Han-Bo Yang, Yan Guo, Ke Cao, Qi-Jia Jiang, Chao-Chao Teng, Dao-Yong Zhu and Shao-Hua Wang
Chem. Commun., 2024, 60, 1124
DOI: 10.1039/D3CC05630A

B–H functionalization of the monocarba-closo-dodecaborate anion by rhodium and iridium catalysis
Yunjun Shen, Yani Pan, Kang Zhang, Xuewei Liang, Jiyong Liu, Bernhard Spingler and Simon Duttwyler
Dalton Trans., 2017, 46, 3135
DOI: 10.1039/C7DT00269F

Direct observation of the photoinduced electron transfer processes of bis(4-arylphenylamino benzo)-ortho-carborane using transient absorption spectroscopic measurements
Mi Rang Son, Yang-Jin Cho, So-Yeon Kim, Ho-Jin Son, Dae Won Cho and Sang Ook Kang
Phys. Chem. Chem. Phys., 2017, 19, 24485
DOI: 10.1039/C7CP04505K

Alkene insertion reactivity of a o-carboranyl-substituted 9-borafluorene
Tobias Bischof, Xueying Guo, Ivo Krummenacher, Lukas Beßler, Zhenyang Lin, Maik Finze and Holger Braunschweig
Chem. Sci., 2022, 13, 7492
DOI: 10.1039/D2SC02750J

Theoretical investigations of the Ir-catalyzed direct borylation of B(3,6)–H of o-carborane: the actual catalyst, mechanism, and origin of regioselectivity
Huining Bai, Hao Xu, Huimin Zhang, Yuen Guo, Jiankai Shan, Donghui Wei, Yanyan Zhu, Shouren Zhang and Wenjing Zhang
Catal. Sci. Technol., 2018, 8, 5165
DOI: 10.1039/C8CY01322E

Unveiling the role of upper excited electronic states in the photochemistry and laser performance of anti-B18H22
Luis Cerdán, Antonio Francés-Monerris, Daniel Roca-Sanjuán, Jonathan Bould, Jiří Dolanský, Marcel Fuciman and Michael G. S. Londesborough
J. Mater. Chem. C, 2020, 8, 12806
DOI: 10.1039/D0TC02309D

Halogen⋯halogen interactions in decahalo-closo-carboranes: CSD analysis and theoretical study
Maria de las Nieves Piña, Antonio Bauzá and Antonio Frontera
Phys. Chem. Chem. Phys., 2020, 22, 6122
DOI: 10.1039/D0CP00114G

Magnesium-mediated sp3 C–H activation in cascade cyclization of 1-arylethynyl-2-alkyl-o-carboranes: efficient synthesis of carborane-fused cyclopentanes
Jie Zhang, Cen Tang and Zuowei Xie
Chem. Sci., 2020, 11, 9925
DOI: 10.1039/D0SC04465B

Possibility of a magnetic [BN fullerene:B6 cluster]− nanocomposite as a vehicle for the delivery of dapsone
J. Cano Ordaz, E. Chigo Anota, M. Salazar Villanueva and M. Castro
New J. Chem., 2017, 41, 8045
DOI: 10.1039/C7NJ01133D

Bridged o-carborane–anthracene dyads as dual state emission luminogens: synthesis, characterization, and mechanochromic properties
Chunyue Xu, Tianrui Li, Jinling Miao, Kexin Liu, Yong Nie, Guangning Liu and Xuchuan Jiang
New J. Chem., 2023, 47, 4448
DOI: 10.1039/D3NJ00027C

Synthesis and photophysical properties of a porphyrin–BODIPY dyad and a porphyrin–o-carborane–BODIPY triad
Ekin Berksun, Ilgın Nar, Armağan Atsay, İbrahim Özçeşmeci, Ali Gelir and Esin Hamuryudan
Inorg. Chem. Front., 2018, 5, 200
DOI: 10.1039/C7QI00608J

Regiodivergent metal-catalyzed B(4)- and C(1)-selenylation of o-carboranes
Kyungsup Lee, Jordan L. Harper, Tae Hyeon Kim, Hee Chan Noh, Dongwook Kim, Paul Ha-Yeon Cheong and Phil Ho Lee
Chem. Sci., 2023, 14, 643
DOI: 10.1039/D2SC05590B

Fluorescent carborane–vinylstilbene functionalised octasilsesquioxanes: synthesis, structural, thermal and photophysical properties
Justo Cabrera-González, Albert Ferrer-Ugalde, Santanu Bhattacharyya, Mahdi Chaari, Francesc Teixidor, Johannes Gierschner and Rosario Núñez
J. Mater. Chem. C, 2017, 5, 10211
DOI: 10.1039/C7TC03319B

Pd-Catalyzed sequential B(3)–I/B(4)–H bond activation for the synthesis of 3,4-benzo-o-carboranes
Yixiu Ge, Jie Zhang, Zaozao Qiu and Zuowei Xie
Dalton Trans., 2021, 50, 1766
DOI: 10.1039/D0DT03740K

Computational discovery of high-performance B–Al–Ga nanoclusters for oxygen reduction reaction catalysis
Pratik Sarkar, Maya Khatun and Anakuthil Anoop
Phys. Chem. Chem. Phys., 2025, 27, 25014
DOI: 10.1039/D5CP03587B

Steric modulation of o-carborane enables tunable single and dual emission in multi-resonance TADF compounds
Young Hoon Lee, Rafi Muhammad Lutfi, Junseong Lee, Eunsung Lee, Jaehoon Jung and Min Hyung Lee
Inorg. Chem. Front., 2026, 13, 3137
DOI: 10.1039/D5QI02417J

Nucleophilic substitution: a facile strategy for selective B–H functionalization of carboranes
Yangjian Quan, Cen Tang and Zuowei Xie
Dalton Trans., 2019, 48, 7494
DOI: 10.1039/C9DT01140D

Multiple photoluminescence of spiro[acridine-fluorene]-based o-carboranyl compounds with potential as a visual sensory material
Min Sik Mun, Chan Hee Ryu, Hyunhee So, Mingi Kim, Ji Hye Lee, Hyonseok Hwang and Kang Mun Lee
J. Mater. Chem. C, 2020, 8, 16896
DOI: 10.1039/D0TC03801F

Carba-closo-dodecaboranylethynyl ligands facilitating luminescent reversed charge-transfer excited states in gold/silver complexes
Michael Hailmann, Benjamin Hupp, Alexander Himmelspach, Fabian Keppner, Philipp T. Hennig, Rüdiger Bertermann, Andreas Steffen and Maik Finze
Chem. Commun., 2019, 55, 9351
DOI: 10.1039/C9CC05060D

Anthracene–styrene-substituted m-carborane derivatives: insights into the electronic and structural effects of substituents on photoluminescence
Mahdi Chaari, Zsolt Kelemen, Duane Choquesillo-Lazarte, Francesc Teixidor, Clara Viñas and Rosario Núñez
Inorg. Chem. Front., 2020, 7, 2370
DOI: 10.1039/D0QI00127A

A new type of carborane-based electron-accepting material
Sunhee Lee, Jisu Shin, Doo-Hyun Ko and Won-Sik Han
Chem. Commun., 2020, 56, 12741
DOI: 10.1039/D0CC04684A

Intramolecular charge transfer induced emission from triphenylamine-o-carborane dyads
Yi Wan, Junfeng Li, Xuelei Peng, Chao Huang, Qi Qi, Wen-Yong Lai and Wei Huang
RSC Adv., 2017, 7, 35543
DOI: 10.1039/C7RA06237K

Highly selective palladium-catalyzed one-pot, five-fold B–H/C–H cross coupling of monocarboranes with alkenes
Yunjun Shen, Kang Zhang, Xuewei Liang, Rakesh Dontha and Simon Duttwyler
Chem. Sci., 2019, 10, 4177
DOI: 10.1039/C9SC00078J

Palladium catalyzed/silver tuned selective mono-/tetra-acetoxylation of o-carboranes via B–H activation
Ke Cao, Tao-Tao Xu, Ji Wu, Linhai Jiang and Junxiao Yang
Chem. Commun., 2016, 52, 11446
DOI: 10.1039/C6CC06200H

Benchmarking the dynamic luminescence properties and UV stability of B18H22-based materials
Kierstyn P. Anderson, Ash Sueh Hua, John B. Plumley, Austin D. Ready, Arnold L. Rheingold, Thomas L. Peng, Peter I. Djurovich, Christopher Kerestes, Neil A. Snyder, Andrew Andrews, Justin R. Caram and Alexander M. Spokoyny
Dalton Trans., 2022, 51, 9223
DOI: 10.1039/D2DT01225A

Modulation of luminescence chromic behaviors and environment-responsive intensity changes by substituents in bis-o-carborane-substituted conjugated molecules
Hiroki Mori, Kenta Nishino, Keisuke Wada, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo
Mater. Chem. Front., 2018, 2, 573
DOI: 10.1039/C7QM00486A

Rhodium-catalyzed sequential B(3)-, B(4)-, and B(5)-trifunctionalization of o-carboranes with three different substituents
Biao Cheng, Yu Chen, Peng Zhou and Zuowei Xie
Chem. Commun., 2022, 58, 629
DOI: 10.1039/D1CC05936J

Synthesis and full characterization of an iridium B–H activation intermediate of the monocarba-closo-dodecaborate anion
Yunjun Shen, Yani Pan, Jiyong Liu, Tosaporn Sattasathuchana, Kim K. Baldridge and Simon Duttwyler
Chem. Commun., 2017, 53, 176
DOI: 10.1039/C6CC08121E

Substituted (benzoimidazol-2-yl)Methanamines in Silver(I) Complexation in the Presence of Boron Cluster Anions
Svetlana E. Nikiforova, Nadezhda A. Khan, Alexey S. Kubasov, Lyudmila V. Goeva, Anatolii S. Burlov, Lyudmila N. Divaeva, Yurii V. Koshchienko, Varvara V. Avdeeva, Elena A. Malinina and Nikolay T. Kuznetsov
J Clust Sci, 2025, 36
DOI: 10.1007/s10876-025-02816-z

Controllable Photophysical and Nonlinear Properties in Conformation Isomerization of Macrocyclic [32]Octaphyrin(1.0.1.0.1.0.1.0) Involving Hückel and Möbius Topologies
Zeyu Liu and Tian Lu
J. Phys. Chem. C, 2020, 124, 845
DOI: 10.1021/acs.jpcc.9b09033

Macropolyhedral syn-B18H22, the “Forgotten” Isomer
Deepak Kumar Patel, B. S. Sooraj, Kaplan Kirakci, Jan Macháček, Monika Kučeráková, Jonathan Bould, Michal Dušek, Martha Frey, Christof Neumann, Sundargopal Ghosh, Andrey Turchanin, Thalappil Pradeep and Tomas Base
J. Am. Chem. Soc., 2023, 145, 17975
DOI: 10.1021/jacs.3c05530

Iridium(III)-catalyzed remote B(9)−H alkylation of o-carboranes with nitrile template
Kyungsup Lee, Jiwon Kim, Donghun Hwang, Bora Yang, Dayeon Kang, Dongwook Kim, Mu-Hyun Baik and Phil Ho Lee
Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-65616-z

Palladium-Catalyzed Selective Five-Fold Cascade Arylation of the 12-Vertex Monocarborane Anion by B–H Activation
Furong Lin, Jing-Lu Yu, Yunjun Shen, Shuo-Qing Zhang, Bernhard Spingler, Jiyong Liu, Xin Hong and Simon Duttwyler
J. Am. Chem. Soc., 2018, 140, 13798
DOI: 10.1021/jacs.8b07872

Thermochromic Fluorescence from B18H20(NC5H5)2: An Inorganic–Organic Composite Luminescent Compound with an Unusual Molecular Geometry
Michael G. S. Londesborough, Jiří Dolanský, Luis Cerdán, Kamil Lang, Tomáš Jelínek, Josep M. Oliva, Drahomír Hnyk, Daniel Roca‐Sanjuán, Antonio Francés‐Monerris, Jiří Martinčík, Martin Nikl and John D. Kennedy
Advanced Optical Materials, 2017, 5
DOI: 10.1002/adom.201600694

Ortho‐Carborane Decorated Multi‐Resonance TADF Emitters: Preserving Local Excited State and High Efficiency in OLEDs
Taehwan Lee, Jee‐Hun Jang, Nhi Ngoc Tuyet Nguyen, Jaehoon Jung, Jeong‐Hwan Lee and Min Hyung Lee
Advanced Science, 2024, 11
DOI: 10.1002/advs.202309016

Time‐Dependent Emission Enhancement of the Ethynylpyrene‐o‐Carborane Dyad and Its Application as a Luminescent Color Sensor for Evaluating Water Contents in Organic Solvents
Kenta Nishino, Hideki Yamamoto, Junki Ochi, Kazuo Tanaka and Yoshiki Chujo
Chemistry — An Asian Journal, 2019, 14, 1577
DOI: 10.1002/asia.201900396

Reduction of Triple Bond in [B12H11NCR]− Anions by Lithium Aluminum Hydride: A Novel Approach to the Synthesis of N-Monoalkylammonio-Substituted closo-Dodecaborates
Alexey V. Nelyubin, Nikolay K. Neumolotov, Nikita A. Selivanov, Alexander Yu. Bykov, Ilya N. Klyukin, Alexander S. Novikov, Alexey S. Kubasov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov
Inorganics, 2023, 12, 2
DOI: 10.3390/inorganics12010002

Reversible Photothermal Isomerization of Carborane‐Fused Azaborole to Borirane: Synthesis and Reactivity of Carbene‐Stabilized Carborane‐Fused Borirane
Hao Wang, Jiji Zhang and Zuowei Xie
Angew Chem Int Ed, 2017, 56, 9198
DOI: 10.1002/anie.201704642

Catalytic Cage BH Functionalization of Carboranes via “Cage Walking” Strategy
Chenyang Guo, Zaozao Qiu and Zuowei Xie
ACS Catal., 2021, 11, 2134
DOI: 10.1021/acscatal.0c05639

Effects of Multi‐Carborane Substitution on the Photophysical and Electron‐Accepting Properties of o‐Carboranylbenzene Compounds
Dong Kyun You, Ji Hye Lee, Byung Hoon Choi, Hyonseok Hwang, Min Hyung Lee, Kang Mun Lee and Myung Hwan Park
Eur J Inorg Chem, 2017, 2017, 2496
DOI: 10.1002/ejic.201700192

Synthesis and Crystal Structure of 9,12-Dibromo-ortho-Carborane
Olga B. Zhidkova, Anna A. Druzina, Sergey A. Anufriev, Kyrill Yu. Suponitsky, Igor B. Sivaev and Vladimir I. Bregadze
Molbank, 2022, 2022, M1347
DOI: 10.3390/M1347

Old Key Opens the Lock in Carborane: The in Situ NHC-Palladium Catalytic System for Selective Arylation of B(3,6)–H Bonds of o-Carboranes via B–H Activation
Tao-Tao Xu, Ke Cao, Cai-Yan Zhang, Ji Wu, Li-Fang Ding and Junxiao Yang
Org. Lett., 2019, 21, 9276
DOI: 10.1021/acs.orglett.9b03790

Site‐Selective Functionalization of Carboranes at the Electron‐Rich Boron Vertex: Photocatalytic B−C Coupling via a Carboranyl Cage Radical
Meng Chen, Jingkai Xu, Deshi Zhao, Fangxiang Sun, Songlin Tian, Deshuang Tu, Changsheng Lu and Hong Yan
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202205672

Stable squalene-boron cluster nanoemulsions in aqueous media
Antonida V. Kalistratova, Anna Yu. Tomilina, Aleksey A. Nikitin, Aleksey S. Kubasov, Konstantin Yu. Zhizhin, Svetlana E. Gelperina, Nikolay T. Kuznetsov and Evgeniy N. Ofitserov
Nano-Structures & Nano-Objects, 2025, 44, 101572
DOI: 10.1016/j.nanoso.2025.101572

Enhancement of Luminescence Efficiencies by Thermal Rearrangement from ortho‐ to meta‐Carborane in Bis‐Carborane‐Substituted Acenes
Hirofumi Naito, Kyoya Uemura, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo
Eur J Org Chem, 2018, 2018, 1885
DOI: 10.1002/ejoc.201800151

Synthesis, cation exchange, and optical properties of pyrene-based chromophores containing [CB9H9]− and [CB11H11]− cluster units
Junki Ochi, Takumi Yanagihara, Kazuo Tanaka and Yoshiki Chujo
Bulletin of the Chemical Society of Japan, 2024, 97
DOI: 10.1093/bulcsj/uoae005

Boron‐Functionalized Phosphorescent Iridium(III) Complexes
Wen‐Juan Xu, Yan‐Yan Qin, Liu‐Wei Wei, Kenneth Yin Zhang, Shu‐Juan Liu and Qiang Zhao
Eur J Inorg Chem, 2017, 2017, 4393
DOI: 10.1002/ejic.201700566

2D COSY 11B NMR spectroscopy in the interpretation of the structures of iso and trans isomers of the macropolyhedral boron cluster [B20H18]2–
Varvara V. Avdeeva, Viktor I. Privalov, Alexey S. Kubasov, Svetlana E. Nikiforova, Elena A. Malinina and Nikolay T. Kuznetsov
Inorganica Chimica Acta, 2023, 555, 121564
DOI: 10.1016/j.ica.2023.121564

Nido‐Carboranes: Donors for Thermally Activated Delayed Fluorescence
Nguyen Van Nghia, Saibal Jana, Surendran Sujith, Ji Yeon Ryu, Junseong Lee, Sang Uck Lee and Min Hyung Lee
Angew Chem Int Ed, 2018, 57, 12483
DOI: 10.1002/anie.201806922

Free Radical Polymerization of o‐Carborane Functionalized Styrene: Effect of Substitution Position at Carbon and Boron
Xin‐Yu Wen, Ke Cao, Ji Wu, Cai‐Yan Zhang, Xia Li, Linhai Jiang and Junxiao Yang
ChemistrySelect, 2021, 6, 4491
DOI: 10.1002/slct.202100932

ChemInform Abstract: Boron Clusters in Luminescent Materials
Sanjoy Mukherjee and Pakkirisamy Thilagar
ChemInform, 2016, 47
DOI: 10.1002/chin.201609223

Modulation of the cis‐ and trans‐Conformations in Bis‐o‐carborane Substituted Benzodithiophenes and Emission Enhancement Effect on Luminescent Efficiency by Solidification
Kenta Nishino, Kyoya Uemura, Kazuo Tanaka, Yasuhiro Morisaki and Yoshiki Chujo
Eur J Org Chem, 2018, 2018, 1507
DOI: 10.1002/ejoc.201701641

Rhodium‐Catalyzed Regioselective Hydroxylation of Cage B−H Bonds of o‐Carboranes with O2 or Air
Hairong Lyu, Yangjian Quan and Zuowei Xie
Angewandte Chemie, 2016, 128, 12019
DOI: 10.1002/ange.201605880

Methamphetamine detection enabled by a fluorescent carborane derivative of perylene monoimide in film state
Nannan Ding, Ke Liu, Yanyu Qi, Congdi Shang, Xingmao Chang and Yu Fang
Sensors and Actuators B: Chemical, 2021, 340, 129964
DOI: 10.1016/j.snb.2021.129964

Synthesis of Polyhedral Borane Cluster Fused Heterocycles via Transition Metal Catalyzed B-H Activation
Ke Cao, Cai-Yan Zhang, Tao-Tao Xu, Ji Wu, Xin-Yu Wen, Wen-Jun Jiang, Mao Chen and Junxiao Yang
Molecules, 2020, 25, 391
DOI: 10.3390/molecules25020391

Catalytic Cascade Dehydrogenative Cross-Coupling of BH/CH and BH/NH: One-Pot Process to Carborano-Isoquinolinone
Yik Ki Au, Hairong Lyu, Yangjian Quan and Zuowei Xie
J. Am. Chem. Soc., 2019, 141, 12855
DOI: 10.1021/jacs.9b06204

Red light-emitting Carborane-BODIPY dyes: Synthesis and properties of visible-light tuned fluorophores with enhanced boron content
Chiara Bellomo, Davide Zanetti, Francesca Cardano, Sohini Sinha, Mahdi Chaari, Andrea Fin, Andrea Maranzana, Rosario Núñez, Marco Blangetti and Cristina Prandi
Dyes and Pigments, 2021, 194, 109644
DOI: 10.1016/j.dyepig.2021.109644

Deboronation-induced ratiometric emission sensing of fluoride by 1,3,5-tris-(o-carboranyl-methyl)benzene
Dong Kyun You, Ji Hye Lee, Hyonseok Hwang, Hyoshik Kwon, Myung Hwan Park and Kang Mun Lee
Tetrahedron Letters, 2017, 58, 3246
DOI: 10.1016/j.tetlet.2017.07.017

Palladium‐Catalyzed Selective Mono‐Chlorination of o‐Carboranes: Changing the Concept of FeCl3 from Lewis Acid to Chlorine Source in Carboranes
Tao‐Tao Xu, Cai‐Yan Zhang, Ke Cao, Ji Wu, Linhai Jiang, Jing Li, Bo Li and Junxiao Yang
ChemistrySelect, 2017, 2, 3396
DOI: 10.1002/slct.201700704

Photophysical Behavior of Self‐Organizing Derivatives of 10‐ and 12‐Vertex p‐Carboranes, and their Bicyclo[2.2.2]octane and Benzene Analogues
Rafał Jakubowski, Adam Januszko, R. William Tilford, George J. Radziszewski, Anna Pietrzak, Victor G. Young and Piotr Kaszyński
Chemistry A European J, 2023, 29
DOI: 10.1002/chem.202203948

Synthesis of 3-Aryl-ortho-carboranes with Sensitive Functional Groups
Sergey A. Anufriev, Akim V. Shmal’ko, Kyrill Yu. Suponitsky and Igor B. Sivaev
Molecules, 2021, 26, 7297
DOI: 10.3390/molecules26237297

Direct Distinguishing of Methanol over Ethanol with a Nanofilm‐Based Fluorescent Sensor
Tian Han, Jinglun Yang, Rong Miao, Ke Liu, Jing Li, Dan Wang, Taihong Liu and Yu Fang
Adv Materials Technologies, 2021, 6
DOI: 10.1002/admt.202000933

Site- and enantioselective B−H functionalization of carboranes
Kyungsup Lee, Gisela A. González-Montiel, Hyeonsik Eom, Tae Hyeon Kim, Hee Chan Noh, Abdikani Omar Farah, Henry R. Wise, Dongwook Kim, Paul Ha-Yeon Cheong and Phil Ho Lee
Nat Commun, 2025, 16
DOI: 10.1038/s41467-025-59410-0

Ferrocenyl carborane conjugates with allyl functionalities: Synthesis and properties
A.V. Makarenkov, S.M. Peregudova, E.G. Kononova, Yu.A. Borisov, A.S. Peregudov and V.A. Ol'shevskaya
Journal of Organometallic Chemistry, 2024, 1008, 123062
DOI: 10.1016/j.jorganchem.2024.123062

Fine-Tuning Electronic Properties of Luminescent Pt(II) Complexes via Vertex-Differentiated Coordination of Sterically Invariant Carborane-Based Ligands
Kent O. Kirlikovali, Jonathan C. Axtell, Kierstyn Anderson, Peter I. Djurovich, Arnold L. Rheingold and Alexander M. Spokoyny
Organometallics, 2018, 37, 3122
DOI: 10.1021/acs.organomet.8b00475

Visible‐Light‐Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane‐Oxindole‐Pharmaceutical Hybrids
Qiang Liu, Bei‐Bei Zhang, He Sheng, Sen Qiao, Zhi‐Xiang Wang and Xiang‐Yu Chen
Angew Chem Int Ed, 2023, 62
DOI: 10.1002/anie.202305088

Geometry and steric effects on the electronic states of aryl-o-carboranes
So-Yoen Kim, Yang-Jin Cho, Ho-Jin Son, Chul Hoon Kim and Sang Ook Kang
Journal of Organometallic Chemistry, 2018, 865, 152
DOI: 10.1016/j.jorganchem.2018.03.041

Synthetic Emission Tuning of Carborane-Containing Poly(dihexylfluorene)s
Kara L. Martin, Jessica N. Smith, Elizabeth R. Young and Kenneth R. Carter
Macromolecules, 2019, 52, 7951
DOI: 10.1021/acs.macromol.9b01325

Luminescence properties of carborane-containing distyrylaromatic systems
Mahdi Chaari, Justo Cabrera-González, Zsolt Kelemen, Clara Viñas, Albert Ferrer-Ugalde, Duane Choquesillo-Lazarte, Abdelhamid Ben Salah, Francesc Teixidor and Rosario Núñez
Journal of Organometallic Chemistry, 2018, 865, 206
DOI: 10.1016/j.jorganchem.2018.03.002

Synthesis and Physicochemical Properties of C-Borylated Esters and Amides Based on the closo-Dodecaborate Anion
I. N. Klyukin, N. A. Selivanov, A. Yu. Bykov, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov
Russ. J. Inorg. Chem., 2020, 65, 1637
DOI: 10.1134/S0036023620110091

Atomically Defined Monocarborane Copper(I) Acetylides with Structural and Luminescence Properties Tuned by Ligand Sterics
Kang Zhang, Yunjun Shen, Xiaoli Yang, Jiyong Liu, Tao Jiang, Nathaniel Finney, Bernhard Spingler and Simon Duttwyler
Chemistry A European J, 2019, 25, 8754
DOI: 10.1002/chem.201900584

Reaction of the [B10H11]– Anion with Dicyanostilbenes
N. K. Neumolotov, V. V. Voinova, A. P. Zhdanov, N. A. Selivanov, A. Yu. Bykov, A. A. Yakimanskiy, T. G. Chulkova, A. V. Yakimansky, K. Yu. Zhizhin and N. T. Kuznetsov
Russ. J. Inorg. Chem., 2024, 69, 2028
DOI: 10.1134/S0036023624603532

Vertex Differentiation Strategy for Tuning the Physical Properties of closo-Dodecaborate Weakly Coordinating Anions
Yessica A. Nelson, Ahamed Irshad, Sangmin Kim, Mary A. Waddington, Charlene Z. Salamat, Milan Gembicky, Arnold L. Rheingold, Veronica Carta, Sarah H. Tolbert, Sri R. Narayan and Alexander M. Spokoyny
Inorg. Chem., 2023, 62, 15084
DOI: 10.1021/acs.inorgchem.3c01992

Magnesium Reagents Featuring a 1,1′‐Bis(o‐carborane) Ligand Platform
Jonathan C. Axtell, Kent O. Kirlikovali, Rafal M. Dziedzic, Milan Gembicky, Arnold L. Rheingold and Alexander M. Spokoyny
Eur J Inorg Chem, 2017, 2017, 4411
DOI: 10.1002/ejic.201700604

Planar Octagonal Tetranuclear Cobaltacarborane Macrocycle [(η5-C5Me5)Co(2,3-Et2C2B4H3-5-C≡C-7-C≡C)]4 for 2D Nonlinear Optics: Ultra-High-Response and Multistate Controlled Cubic NLO Switch
Hong-Qiang Wang, Li Wang, Jin-Ting Ye, Hai-Ming Xie and Yong-Qing Qiu
J. Phys. Chem. C, 2017, 121, 28462
DOI: 10.1021/acs.jpcc.7b10144

Direct Phenylation of nido-B10H14
Jan Demel, Matouš Kloda, Kamil Lang, Karel Škoch, Jan Hynek, Adam Opravil, Matyáš Novotný, Jonathan Bould, Marcel Ehn and Michael G. S. Londesborough
J. Org. Chem., 2022, 87, 10034
DOI: 10.1021/acs.joc.2c00997

Anti-cancer activity of m-carborane-containing trimethoxyphenyl derivatives through tubulin polymerization inhibition
Asako Kaise, Yasuyuki Endo and Kiminori Ohta
Bioorganic & Medicinal Chemistry, 2019, 27, 1139
DOI: 10.1016/j.bmc.2019.02.018

High-Performance Trichloroacetic Acid Sensor Based on the Intramolecular Hydrogen Bond Formation and Disruption of a Specially Designed Fluorescent o-Carborane Derivative in the Film State
Ke Liu, Gang Wang, Nannan Ding, Jing Zhang, Jinglin Kong, Taihong Liu and Yu Fang
ACS Appl. Mater. Interfaces, 2021, 13, 19342
DOI: 10.1021/acsami.1c03331

Catalyst‐Free Polyhydroboration of Dodecaborate Yields Highly Photoluminescent Ionic Polyarylated Clusters
Mark W. Lee
Angewandte Chemie, 2017, 129, 144
DOI: 10.1002/ange.201608249

Spirobifluorene‐Based o‐Carboranyl Compounds: Insights into the Rotational Effect of Carborane Cages on Photoluminescence
Seonah Kim, Ji Hye Lee, Hyunhee So, Jiyeon Ryu, Junseong Lee, Hyonseok Hwang, Youngjo Kim, Myung Hwan Park and Kang Mun Lee
Chemistry A European J, 2020, 26, 548
DOI: 10.1002/chem.201904491

Improvement in Radiative Efficiency Via Intramolecular Charge Transfer in ortho-Carboranyl Luminophores Modified with Functionalized Biphenyls
Dong Kyun You, Mingi Kim, Dongwook Kim, Namkyun Kim and Kang Mun Lee
Inorg. Chem., 2023, 62, 10003
DOI: 10.1021/acs.inorgchem.3c01242

Palladium-Catalyzed Asymmetric B–H Arylation of o-Carboranes Assisted by a Chiral Transient Directing Group
Yanglong Zou, Jie Zhang, Wei Hong, Dengsong Zhang, Zaozao Qiu and Zuowei Xie
ACS Catal., 2026, 16, 4951
DOI: 10.1021/acscatal.5c08932

Recent Advances in Transition Metal-Catalyzed B—H Bond Activation for Synthesis of o-Carborane Derivatives with B—Heteroatom Bond
Hairui Jia and Zaozao Qiu
Chinese Journal of Organic Chemistry, 2023, 43, 1045
DOI: 10.6023/cjoc202211040

Rhodium‐Catalyzed Regioselective Hydroxylation of Cage B−H Bonds of o‐Carboranes with O2 or Air
Hairong Lyu, Yangjian Quan and Zuowei Xie
Angew Chem Int Ed, 2016, 55, 11840
DOI: 10.1002/anie.201605880

Fe-Catalyzed Intramolecular B–H/C–H Dehydrogenative Coupling: Synthesis of Carborane-Fused Nitrogen Heterocycles
Yu Chen, Hairong Lyu, Yangjian Quan and Zuowei Xie
Org. Lett., 2021, 23, 4163
DOI: 10.1021/acs.orglett.1c01104

Ene Reaction of o-Carboryne with Alkynes and Alkenes at Room Temperature: Synthesis of o-Carboranyl Allenes and Alkenes
Jie Zhang and Zuowei Xie
Org. Lett., 2021, 23, 2971
DOI: 10.1021/acs.orglett.1c00649

Tuning of Sensitivity in Thermochromic Luminescence by Regulating Molecular Rotation Based on Triphenylamine‐Substituted o‐Carboranes
Kenta Nishino, Kazuo Tanaka and Yoshiki Chujo
Asian J Org Chem, 2019, 8, 2228
DOI: 10.1002/ajoc.201900537

Blue Phosphorescent Zwitterionic Iridium(III) Complexes Featuring Weakly Coordinatingnido-Carborane-Based Ligands
Jonathan C. Axtell, Kent O. Kirlikovali, Peter I. Djurovich, Dahee Jung, Vinh T. Nguyen, Brian Munekiyo, A. Timothy Royappa, Arnold L. Rheingold and Alexander M. Spokoyny
J. Am. Chem. Soc., 2016, 138, 15758
DOI: 10.1021/jacs.6b10232

Enhancement of Aggregation-Induced Emission by Introducing Multiple o-Carborane Substitutions into Triphenylamine
Kenta Nishino, Kyoya Uemura, Masayuki Gon, Kazuo Tanaka and Yoshiki Chujo
Molecules, 2017, 22, 2009
DOI: 10.3390/molecules22112009

N‐Ligand‐Enabled Aromatic Nucleophilic Amination of 1,2‐Diaryl‐o‐Carboranes with (R2N)2Mg for Selective Synthesis of 4‐R2N‐o‐Carboranes and 2‐R2N‐m‐Carboranes
Jie Zhang and Zuowei Xie
Angew Chem Int Ed, 2022, 61
DOI: 10.1002/anie.202202675

Palladium catalyzed/counter ion tuned selective methylation of o-carboranes
Ke Cao, Cai-Yan Zhang, Tao-Tao Xu, Ji Wu, Li-Fang Ding, Linhai Jiang and Junxiao Yang
Journal of Organometallic Chemistry, 2019, 902, 120956
DOI: 10.1016/j.jorganchem.2019.120956

Design for a Solid‐State Luminescent Sensor Through Photo‐Induced Electron Transfer Based on Pyrene‐Modified o‐Carborane
Shunsuke Nishiyama, Junki Ochi and Kazuo Tanaka
Asian J Org Chem, 2025, 14
DOI: 10.1002/ajoc.202400513

Synthesis, aggregation-induced emission and mechanochromism of a new carborane-tetraphenylethylene hybrid
Yong Nie, Hao Zhang, Jinling Miao, Xiaoqing Zhao, Yexin Li and Guoxin Sun
Journal of Organometallic Chemistry, 2018, 865, 200
DOI: 10.1016/j.jorganchem.2018.03.034

Palladium-Catalyzed Selective B(3)-Esterification of o-Carboranes with CO and Alcohols
Shuai Zhu, Yizhen Liu and Zuowei Xie
Org. Lett., 2025, 27, 2429
DOI: 10.1021/acs.orglett.5c00308

Synthesis, Photophysical and Electronic Properties of a D‐π‐A Julolidine‐Like Pyrenyl‐o‐Carborane
Johannes Krebs, Lisa Brändler, Ivo Krummenacher, Alexandra Friedrich, Holger Braunschweig, Maik Finze, Basile F. E. Curchod and Todd B. Marder
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202401704

Chlorination of the terminal hydrogen atoms in the hydrogen-rich group 5 dimetallaboranes (Cp*M)2(B2H6)2 (M = Nb, Ta)
Rini Prakash, K. Bakthavachalam, Babu Varghese and Sundargopal Ghosh
Journal of Organometallic Chemistry, 2017, 846, 372
DOI: 10.1016/j.jorganchem.2017.07.008

Zwitterionic nido-Carborane-Fused Phospholes
Guanyu Tao, Zheng Duan and Francois Mathey
Org. Lett., 2019, 21, 2273
DOI: 10.1021/acs.orglett.9b00562

Synthesis of C-mercuro derivatives of ortho-carborane. Crystal structure of bis(2-phenyl-ortho-carboran-1-yl)mercury
S. А. Anufriev, S. V. Timofeev, D. I. Nasyrova, I. B. Sivaev and V. I. Bregadze
Žurnal neorganičeskoj himii, 2024, 69, 659
DOI: 10.31857/S0044457X24050014

Blue Emitting Star-Shaped and Octasilsesquioxane-Based Polyanions Bearing Boron Clusters. Photophysical and Thermal Properties
Justo Cabrera-González, Mahdi Chaari, Francesc Teixidor, Clara Viñas and Rosario Núñez
Molecules, 2020, 25, 1210
DOI: 10.3390/molecules25051210

1,3,7-Triazapyrene-Basedortho-Carborane Fluorophores: Convenient Synthesis, Theoretical Studies, and Aggregation-Induced Emission Properties
Lidia A. Smyshliaeva, Mikhail V. Varaksin, Ekaterina I. Fomina, Margarita V. Medvedeva, Tatiana S. Svalova, Alisa N. Kozitsina, Oleg P. Demidov, Ivan V. Borovlev, Carl Mensch, Pieter Mampuys, Bert U. W. Maes, Valery N. Charushin and Oleg N. Chupakhin
Organometallics, 2021, 40, 2792
DOI: 10.1021/acs.organomet.1c00234

Impact of the Electronic Environment in Carbazole-Appended o-Carboranyl Compounds on the Intramolecular-Charge-Transfer-Based Radiative Decay Efficiency
Seok Ho Lee, Min Sik Mun, Ji Hye Lee, Sehee Im, Wonchul Lee, Hyonseok Hwang and Kang Mun Lee
Organometallics, 2021, 40, 959
DOI: 10.1021/acs.organomet.1c00060

Synthesis, luminescent properties and application opportunities of С-substituted ortho-carborane π-conjugated luminophores: a mini review
Timofey D. Moseev, Tair A. Idrisov, Mikhail V. Varaksin, Valery N. Charushin and Oleg N. Chupakhin
Chim.Tech.Acta, 2025, 12
DOI: 10.15826/chimtech.2025.12.2.13

Reversible Photothermal Isomerization of Carborane‐Fused Azaborole to Borirane: Synthesis and Reactivity of Carbene‐Stabilized Carborane‐Fused Borirane
Hao Wang, Jiji Zhang and Zuowei Xie
Angewandte Chemie, 2017, 129, 9326
DOI: 10.1002/ange.201704642

Molecular design and application of luminescent materials composed of group 13 elements with an aggregation-induced emission property
Shunichiro Ito, Masayuki Gon, Kazuo Tanaka and Yoshiki Chujo
National Science Review, 2021, 8
DOI: 10.1093/nsr/nwab049

Chiral recognition of chiral-at-cage o-carboranes using NMR spectroscopy
Jumi Kim, Kyungsup Lee, Hee Chan Noh, Phil Ho Lee and Hyunwoo Kim
Cell Reports Physical Science, 2025, 6, 102958
DOI: 10.1016/j.xcrp.2025.102958

Two New Octaborates Constructed of Two Different Sub-clusters and Supported by Metal Complexes
Rui Pan, Chong-An Chen, Bai-Feng Yang and Guo-Yu Yang
J Clust Sci, 2017, 28, 1237
DOI: 10.1007/s10876-016-1137-1

Chelating 1,2-Bis(2′-picolyl)-o-carborane as a Supporting Ligand for Pd-Catalyzed Selective B(3,6)–H Difunctionalization of o-Carboranes
Qiang-Qiang Ma, Peng Zhou, Yizhen Liu and Zuowei Xie
Inorg. Chem., 2025, 64, 5707
DOI: 10.1021/acs.inorgchem.5c00383

Iridium-catalysed regioselective borylation of carboranes via direct B–H activation
Ruofei Cheng, Zaozao Qiu and Zuowei Xie
Nat Commun, 2017, 8
DOI: 10.1038/ncomms14827

Carborane-based BODIPY dyes: synthesis, structural analysis, photophysics and applications
Javier Ordóñez-Hernández, José Giner Planas and Rosario Núñez
Front. Chem., 2024, 12
DOI: 10.3389/fchem.2024.1485301

Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal–Organic Chalcogenolate Assemblies
Harrison A. Mills, Christopher G. Jones, Kierstyn P. Anderson, Austin D. Ready, Peter I. Djurovich, Saeed I. Khan, J. Nathan Hohman, Hosea M. Nelson and Alexander M. Spokoyny
Chem. Mater., 2022, 34, 6933
DOI: 10.1021/acs.chemmater.2c01319

Development of Solid-State Emissive Materials Based on Multifunctional o-Carborane–Pyrene Dyads
Kenta Nishino, Hideki Yamamoto, Kazuo Tanaka and Yoshiki Chujo
Org. Lett., 2016, 18, 4064
DOI: 10.1021/acs.orglett.6b01920

Thermodynamic Hydricity of Small Borane Clusters and Polyhedral closo-Boranes
Igor E. Golub, Oleg A. Filippov, Vasilisa A. Kulikova, Natalia V. Belkova, Lina M. Epstein and Elena S. Shubina
Molecules, 2020, 25, 2920
DOI: 10.3390/molecules25122920

Tetraphenylethylene–Carborane–Tetraphenylethylene Triad: Influence of Steric Bridge on Aggregation‐Induced Emission Properties
Yongheng Yin, Xiang Li, Senbo Yan, Hong Yan and Changsheng Lu
Chemistry — An Asian Journal, 2018, 13, 3155
DOI: 10.1002/asia.201801172

Physicochemical Fundamentals of the Synthesis of a Cu@BN Composite Consisting of Nanosized Copper Enclosed in a Boron Nitride Matrix
Elena A. Malinina, Ivan I. Myshletsov, Grigorii A. Buzanov, Irina V. Kozerozhets, Nikolay P. Simonenko, Tatiana L. Simonenko, Svetlana E. Nikiforova, Varvara V. Avdeeva, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov
Inorganics, 2023, 11, 345
DOI: 10.3390/inorganics11080345

Thermal and Photophysical Properties of Highly Quadrupolar Liquid‐Crystalline Derivatives of the [closo‐B12H12]2− Anion
Muhammad O. Ali, John C. Lasseter, Remigiusz Żurawiński, Anna Pietrzak, Jacek Pecyna, Jakub Wojciechowski, Andrienne C. Friedli, Damian Pociecha and Piotr Kaszyński
Chemistry A European J, 2019, 25, 2616
DOI: 10.1002/chem.201805392

Synthesis and electropolymerization of a series of 2,2′-(ortho-carboranyl)bisthiophenes
Ning Zhao, Bruno Fabre, Petia Bobadova-Parvanova, Frank R. Fronczek and M. Graça H. Vicente
Journal of Organometallic Chemistry, 2017, 828, 157
DOI: 10.1016/j.jorganchem.2016.11.029

[closo-B10H8-1-CN-10-Azinium]− Anions: Photoactive Heteroditopic Ligands for Metal Complexes
Rafał Jakubowski, Mustapha B. Abdulmojeed, Oleksandr Hietsoi, Andrienne C. Friedli and Piotr Kaszyński
Inorg. Chem., 2024, 63, 17774
DOI: 10.1021/acs.inorgchem.4c02670

Improvement of Solid‐State Excimer Emission of the Aryl–Ethynyl‐o‐Carborane Skeleton by Acridine Introduction
Junki Ochi, Kazuo Tanaka and Yoshiki Chujo
Eur J Org Chem, 2019, 2019, 2984
DOI: 10.1002/ejoc.201900212

Geometric structural insights for enhanced radiative efficiency: Spiro[fluorene–carbazole]‐based ortho‐carboranyl luminophores
Chan Hee Ryu, Seok Ho Lee, Mingi Kim and Kang Mun Lee
Bulletin Korean Chem Soc, 2022, 43, 918
DOI: 10.1002/bkcs.12540

Transition Metal Catalyzed, Regioselective B(4)‐Halogenation and B(4,5)‐Diiodination of Cage B−H Bonds in o‐Carboranes
Hairong Lyu, Yangjian Quan and Zuowei Xie
Chemistry A European J, 2017, 23, 14866
DOI: 10.1002/chem.201703006

Rhodium(III)-Catalyzed B(4)-Azo Coupling of o-Carboranes with Aryl Diazonium Tetrafluoroborates
Kyungsup Lee, Sugyeong Yoon, Hee Chan Noh, Dongwook Kim and Phil Ho Lee
Org. Lett., 2024, 26, 8410
DOI: 10.1021/acs.orglett.4c03250

Features of the Reaction of Ortho-Carboranyl Lithium with 3,6-Bis(3,5-dimethyl-1H-pyrazol-1-yl)-1,2,4,5-tetrazine
T. D. Moseev, L. A. Smyshlyaeva, D. S. Kopchuk, R. I. Ishmetova, P. A. Slepukhin, A. V. Rybakova, G. L. Rusinov, G. V. Zyryanov, M. V. Varaksin, V. N. Charushin and O. N. Chupakhin
Žurnal obŝej himii, 2024, 94, 705
DOI: 10.31857/S0044460X24060048

Cu(OTf)2/NBS-Mediated Tandem Reaction of 1-Cinnamyl Alcohol-o-Carboranes via Ring Opening of Oxetane with Arenes: An Alternative Approach for the Synthesis of C-Alkenyl-o-Carboranes
Cai-Yan Zhang, Ke Cao, Han-Bo Yang, Li-Fang Ding and Junxiao Yang
J. Org. Chem., 2022, 87, 10928
DOI: 10.1021/acs.joc.2c01217

Catalyst‐Free Polyhydroboration of Dodecaborate Yields Highly Photoluminescent Ionic Polyarylated Clusters
Mark W. Lee
Angew Chem Int Ed, 2017, 56, 138
DOI: 10.1002/anie.201608249

Synthesis of C-Allenyl o-Carboranes through Copper(I)-Catalyzed Coupling Reaction of Ethynyl o-Carboranes with N-Tosylhydrazones
Yurim Park, Hee Chan Noh, Euijae Lee and Phil Ho Lee
J. Org. Chem., 2026, 91, 1036
DOI: 10.1021/acs.joc.5c02511

Solid‐State Emission of the Anthracene‐o‐Carborane Dyad from the Twisted‐Intramolecular Charge Transfer in the Crystalline State
Hirofumi Naito, Kenta Nishino, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo
Angewandte Chemie, 2017, 129, 260
DOI: 10.1002/ange.201609656

Rh-Catalyzed Regioselective Dialkylation of Cage B–H bonds in o-Carboranes: Oxidative Heck Reactions via an Enol Isomerization
Qian Wang, Song Tian, Chuyi Zhang, Jiangwei Li, Zhixuan Wang, Yongmei Du, Ling Zhou and Jian Lu
Org. Lett., 2019, 21, 8018
DOI: 10.1021/acs.orglett.9b03009

Reversibly Switchable Fluorescent Molecular Systems Based on Metallacarborane–Perylenediimide Conjugates
Laura Parejo, Mahdi Chaari, Sara Santiago, Gonzalo Guirado, Francesc Teixidor, Rosario Núñez and Jordi Hernando
Chemistry A European J, 2021, 27, 270
DOI: 10.1002/chem.202002419

Reactivity Features of ortho-Carboranillithium towards 3,6-Diaryl-1,2,4,5-tetrazines
T. D. Moseev, D. S. Kopchuk, L. A. Smyshliaeva, A. N. Tsmokaluk, P. A. Slepukhin, A. V. Rybakova, M. V. Varaksin, G. V. Zyryanov, V. N. Charushin and O. N. Chupakhin
Russ J Org Chem, 2025, 61, 1004
DOI: 10.1134/S1070428025601578

Carborane‐BODIPY Dyads: New Photoluminescent Materials through an Efficient Heck Coupling
Chiara Bellomo, Mahdi Chaari, Justo Cabrera‐González, Marco Blangetti, Chiara Lombardi, Annamaria Deagostino, Clara Viñas, Nerea Gaztelumendi, Carme Nogués, Rosario Nuñez and Cristina Prandi
Chemistry A European J, 2018, 24, 15622
DOI: 10.1002/chem.201802901

Structure- and Size-Dependent Properties of BnCu20/– (n = 2–14) Clusters: DFT Calculations
J. M. Guevara-Vela, P. L. Rodríguez-Kessler, J. L. Cabellos-Quiroz, T. Rocha-Rinza, A. Vásquez-Espinal and A. Muñoz-Castro
J. Phys. Chem. A, 2025, 129, 4855
DOI: 10.1021/acs.jpca.4c08443

Photophysical Properties of Spirobifluorene-Based o-Carboranyl Compounds Altered by Structurally Rotating the Carborane Cages
Seonah Kim, Hyunhee So, Ji Hye Lee, Hyonseok Hwang, Hyoshik Kwon, Myung Hwan Park and Kang Mun Lee
Molecules, 2019, 24, 4135
DOI: 10.3390/molecules24224135

Palladium-Catalyzed Regioselective B(3,5)-Dialkenylation and B(4)-Alkenylation of o-Carboranes
Shasha Yuan, Huifang Zhang, Zaozao Qiu and Zuowei Xie
J. Org. Chem., 2024, 89, 2474
DOI: 10.1021/acs.joc.3c02496

Unveiling Non-Covalent Interactions in Novel Cooperative Photoredox Systems for Efficient Alkene Oxidation in Water
Isabel Guerrero, Clara Viñas, Francesc Teixidor and Isabel Romero
Molecules, 2024, 29, 2378
DOI: 10.3390/molecules29102378

An aluminoborate directed by [Zn(H2O)4]2+ complex: Synthesis, structure and properties
Rui Pan, Bai-Bai Yang, Guo-Ming Wang and Guo-Yu Yang
Inorganic Chemistry Communications, 2017, 76, 26
DOI: 10.1016/j.inoche.2016.12.009

Carboranes in drug discovery, chemical biology and molecular imaging
Anita Marfavi, Poya Kavianpour and Louis M. Rendina
Nat Rev Chem, 2022, 6, 486
DOI: 10.1038/s41570-022-00400-x

Charge Transfer Complex-Enabled Synthesis of (Hetero)arylated m-Carboranes from m-Carborane Phosphonium Salts
Qing-Shuang Zhang, Lin He, Qiang Liu and Xiang-Yu Chen
Org. Lett., 2023, 25, 5768
DOI: 10.1021/acs.orglett.3c01989

Electrochemistry and Photoluminescence of Icosahedral Carboranes, Boranes, Metallacarboranes, and Their Derivatives
Rosario Núñez, Màrius Tarrés, Albert Ferrer-Ugalde, Fabrizia Fabrizi de Biani and Francesc Teixidor
Chem. Rev., 2016, 116, 14307
DOI: 10.1021/acs.chemrev.6b00198

Iridium-Catalyzed Annulation of o-Carboranyl Carboxylic Acids with Alkynes: Synthesis of Carborano-Isocoumarins
Biao Cheng, Yu Chen and Zuowei Xie
J. Org. Chem., 2021, 86, 12412
DOI: 10.1021/acs.joc.1c01395

Design of Thermochromic Luminescent Dyes Based on the Bis(ortho‐carborane)‐Substituted Benzobithiophene Structure
Kenta Nishino, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo
Chemistry — An Asian Journal, 2019, 14, 789
DOI: 10.1002/asia.201801529

closo‐Carboranyl Analogs of β‐Arylethylamines: Direct Synthesis from Alkenes via EnT‐Catalysis
Fritz Paulus, Corinna Heusel, Marc Jaspers, Lilli M. Amrehn, Florian Schreiner, Debanjan Rana, Constantin G. Daniliuc, Michael Ryan Hansen and Frank Glorius
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202504793

Electronic Structure of Superoxidized Radical Cationic Dodecaborate-Based Clusters
Bo Li, Xinglong Zhang, Julia M. Stauber, Thomas F. Miller and Alexander M. Spokoyny
J. Phys. Chem. A, 2021, 125, 6141
DOI: 10.1021/acs.jpca.1c03927

Palladium‐Catalyzed Direct B—H Oxygenation: Facile Synthesis of o‐Carboranofuranones†
Chenyang Guo, Zaozao Qiu and Zuowei Xie
Chin. J. Chem., 2024, 42, 3083
DOI: 10.1002/cjoc.202400571

Color‐tunable and Highly Emissive Solid Materials Constructed from Tetraphenylethylene‐o‐carborane‐based Building Blocks: Synthesis, Aggregation‐induced emission, and Photophysics
Xiang Li, Qin Zhou, Miao Zhu, Wei Chen, Beibei Wang, Ye Sha and Hong Yan
Chemistry — An Asian Journal, 2021, 16, 757
DOI: 10.1002/asia.202100150

Palladium‐Catalyzed Carbonylative Annulation of 1‐Hydroxy‐o‐Carborane and Internal Alkynes via Regioselective B‐H Activation
Yik Ki Au, Yangjian Quan and Zuowei Xie
Chemistry — An Asian Journal, 2020, 15, 2170
DOI: 10.1002/asia.202000642

Redox-Active Boron Clusters
Austin D. Ready, Yessica A. Nelson, Daniel F. Torres Pomares and Alexander M. Spokoyny
Acc. Chem. Res., 2024, 57, 1310
DOI: 10.1021/acs.accounts.4c00040

Copper catalyzed/mediated direct B–H alkenylation/alkynylation in carboranes
Yu Chen, Yik Ki Au, Yangjian Quan and Zuowei Xie
Sci. China Chem., 2019, 62, 74
DOI: 10.1007/s11426-018-9388-3

One‐Pot Process to Carborano‐Coumarin via Catalytic CascadeDehydrogenative Cross‐Coupling
Yik Ki Au, Hairong Lyu, Yangjian Quan and Zuowei Xie
Chin. J. Chem., 2020, 38, 383
DOI: 10.1002/cjoc.201900475

Coordination-based molecular nanomaterials for biomedically relevant applications
Chunfei Wang, Wenjing Wang, Jingyun Tan, Xuanjun Zhang, Daqiang Yuan and Hong-Cai Zhou
Coordination Chemistry Reviews, 2021, 438, 213752
DOI: 10.1016/j.ccr.2020.213752

B-Substituted Anthracenyl and Pyrenyl Derivatives of meta-Carborane: Synthesis and Preliminary Study of Luminescent Properties
A. V. Shmal’ko, S. A. Anufriev, K. Yu. Suponitsky, N. Zhou, D. Tu, H. Yan, V. I. Bregadze and I. B. Sivaev
Russ. J. Inorg. Chem., 2025, 70, 2174
DOI: 10.1134/S003602362560426X

In silico studies of the magnetic octahedral B6 − cluster—nitric oxide and [B6 −–NO]−–O2 interactions
E. Chigo-Anota, M. Salazar Villanueva, S. Valdez and M. Castro
Struct Chem, 2017, 28, 1757
DOI: 10.1007/s11224-017-0953-8

Synthesis and Photophysical Properties of Vinyl-conjugated o-Carborane–isoxazole Dyads
Tair A. Idrisov, Timofey D. Moseev, Mikhail V. Varaksin, Nikolay A. Belyaev, Anton Tsmokalyuk, Valery Charushin, Oleg N. Chupakhin and Vasiliy Bakulev
Synthesis, 2025, 57, 3629
DOI: 10.1055/a-2697-1591

(N,Se) and (Se,N,Se) Ligands Based on Carborane and Pyridine Fragments – Reactivity of 2,6‐[(1′‐Me‐1′,2′‐closo‐C2B10H10)SeCH2]2C5H3N towards Copper and Silver
Adriana Ilie, Olga Crespo, M. Concepción Gimeno, Max C. Holthausen, Antonio Laguna, Martin Diefenbach and Cristian Silvestru
Eur J Inorg Chem, 2017, 2017, 2643
DOI: 10.1002/ejic.201700075

Second-Order Nonlinear Optical Properties of Carboranylated Square-Planar Pt(II) Zwitterionic Complexes: One-/Two-Dimensional Difference and Substituent Effect
Hong-Qiang Wang, Li Wang, Rong-Rong Li, Jin-Ting Ye, Zhen-Zhen Chen, He Chen, Yong-Qing Qiu and Hai-Ming Xie
J. Phys. Chem. A, 2016, 120, 9330
DOI: 10.1021/acs.jpca.6b09797

Di‐(2‐picolyl)‐N‐(2‐quinolinylmethyl)amine‐Functionalized Triarylboron: Lewis Acidity Enhancement and Fluorogenic Discrimination Between Fluoride and Cyanide in Aqueous Solution
Mao‐Sen Yuan, Xianchao Du, Zhiqiang Liu, Tianbao Li, Wenji Wang, Eric V. Anslyn and Jinyi Wang
Chemistry A European J, 2018, 24, 9211
DOI: 10.1002/chem.201800884

Transition‐Metal‐Catalyzed Selective Cage B−H Functionalization of o‐Carboranes
Yangjian Quan, Zaozao Qiu and Zuowei Xie
Chemistry A European J, 2018, 24, 2795
DOI: 10.1002/chem.201704937

A Hot Exciton Luminogen Constructed by an o‐Carborane Scaffold
Xiao Yu, Jingkai Xu, Mengmeng Wang, Xiaofei Miao, Quli Fan, Deshuang Tu, Zhaojin Wang, Chunbo Duan, Changsheng Lu, Hui Xu and Hong Yan
Advanced Optical Materials, 2024, 12
DOI: 10.1002/adom.202302218

Tuning the Liquid Crystallinity of Cholesteryl-o-Carborane Dyads: Synthesis, Structure, Photoluminescence, and Mesomorphic Properties
Albert Ferrer-Ugalde, Arántzazu González-Campo, José Giner Planas, Clara Viñas, Francesc Teixidor, Isabel M. Sáez and Rosario Núñez
Crystals, 2021, 11, 133
DOI: 10.3390/cryst11020133

Transition Metal Complexes of a Monocarba‐closo‐dodecaborate Ligand via B–H Activation
Yunjun Shen, Jiyong Liu, Tosaporn Sattasatchuchana, Kim K. Baldridge and Simon Duttwyler
Eur J Inorg Chem, 2017, 2017, 4420
DOI: 10.1002/ejic.201700677

Adsorption and possible dissociation of glucose by the [BN fullerene-B6]− magnetic nanocomposite. In silico studies
E. Chigo Anota, M. Salazar Villanueva, E. Shakerzadeh and M. Castro
Appl Nanosci, 2018, 8, 455
DOI: 10.1007/s13204-018-0664-5

Enantioselective Alkenylation of o-Carboranes via Ir-Catalyzed Asymmetric B–H Activation
Huifang Zhang, Jie Zhang, Zaozao Qiu and Zuowei Xie
ACS Catal., 2023, 13, 13856
DOI: 10.1021/acscatal.3c03997

Metal-Catalyzed and Metal-Free Nucleophilic Substitution of 7-I-B18H21
Kierstyn P. Anderson, Peter I. Djurovich, Victoria P. Rubio, Aimee Liang and Alexander M. Spokoyny
Inorg. Chem., 2022, 61, 15051
DOI: 10.1021/acs.inorgchem.2c02116

Reaction of o‐Carboryne with Furans: Facile Synthesis of Carborane‐ Fused Oxanorbornenes and Their Derivatives
Rongyi Zhang, Yinggen Yuan, Zaozao Qiu and Zuowei Xie
Chin. J. Chem., 2018, 36, 273
DOI: 10.1002/cjoc.201700772

Unraveling the defect-induced photoluminescence of a donor-acceptor AIE luminogen
Xunxue Zhang, Jiangting Hu, Hongliang Han, Zhongfeng Li and Tianyu Han
Dyes and Pigments, 2021, 193, 109566
DOI: 10.1016/j.dyepig.2021.109566

Manipulating the AIE and low-temperature phosphorescence properties of o-carborane-imidazole derivatives via fine tuning their structural features
Huici Shan, Anjie Liu, Yan Lv, Xueyan Wu, Yongdong Ma, Xiaoping Jin and Jixi Guo
Dyes and Pigments, 2020, 180, 108400
DOI: 10.1016/j.dyepig.2020.108400

Supramolecular Nanostructures Constructed from Cluster-based Hybrid Macromolecules
Jiancheng Luo, Xinyu Sun, Jia-Fu Yin, Panchao Yin and Tianbo Liu
Giant, 2020, 2, 100013
DOI: 10.1016/j.giant.2020.100013

[Zn(H2O)4][B6O10]: An open-framework borate with acentric structure
Rui Pan, Bai-Feng Yang, Guo-Ming Wang and Guo-Yu Yang
Inorganic Chemistry Communications, 2017, 76, 15
DOI: 10.1016/j.inoche.2016.11.017

Naphthyl‐ and Quinoline‐Appended o‐Carboranyl Luminophores: Intramolecular Charge Transfer‐Based Radiative Decay Controlled by Structural Geometry around C−C Bond Axis
Chan Hee Ryu, Seok Ho Lee, Sanghee Yi, Ju Hyun Hong, Sehee Im and Kang Mun Lee
Eur J Inorg Chem, 2021, 2021, 4875
DOI: 10.1002/ejic.202100768

Visible‐Light‐Induced Photoreduction of Carborane Phosphonium Salts: Efficient Synthesis of Carborane‐Oxindole‐Pharmaceutical Hybrids
Qiang Liu, Bei‐Bei Zhang, He Sheng, Sen Qiao, Zhi‐Xiang Wang and Xiang‐Yu Chen
Angewandte Chemie, 2023, 135
DOI: 10.1002/ange.202305088

Deep red donor-acceptor type thermally activated delayed fluorescence emitter with o-carborane as an acceptor
Kiun Cheong, Seung Chan Kim and Jun Yeob Lee
Dyes and Pigments, 2023, 215, 111278
DOI: 10.1016/j.dyepig.2023.111278

Basic Hydrolysis of Glycine Ester Derivatives Based on the closo-Dodecaborate Anion: From Thermodynamic to Kinetic Control
A. Sychyov, M. N. Ryabchikova, A. V. Nelyubin, I. N. Klyukin, A. P. Zhdanov, K. Yu. Zhizhin and N. T. Kuznetsov
Russ. J. Inorg. Chem., 2025, 70, 2077
DOI: 10.1134/S0036023625603976

Going to Extreme Lengths: Bicyclic Diborane(6) Anions and the Limits of Boron–Boron σ Bonding
Douglas Turnbull, Elaina Bourque, Nathan D. D. Hill and Marc-André Légaré
J. Am. Chem. Soc., 2025, 147, 23900
DOI: 10.1021/jacs.5c06498

Electrochemical B−H Nitrogenation: Access to Amino Acid and BODIPY‐Labeled nido‐Carboranes
Long Yang, Becky Bongsuiru Jei, Alexej Scheremetjew, Rositha Kuniyil and Lutz Ackermann
Angew Chem Int Ed, 2021, 60, 1482
DOI: 10.1002/anie.202012105

Controlling the aggregation and assembly of boron‐containing molecular and polymeric materials
Daisuke Shimoyama and Frieder Jäkle
Aggregate, 2022, 3
DOI: 10.1002/agt2.149

Boron Cluster Anions Dissolve En Masse in Lipids Causing Membrane Expansion and Thinning
Andrea Barba‐Bon, Alae El Haitami, Coralie Pasquier, Ivana Nikšić‐Franjić, Olivier Diat, Pierre Bauduin, Sophie Cantin and Werner M. Nau
Angewandte Chemie, 2024, 136
DOI: 10.1002/ange.202412834

Elektrochemische B‐H‐Nitrogenierung: Zugang zu Aminosäure‐ und BODIPY‐markierten nido‐Carboranen
Long Yang, Becky Bongsuiru Jei, Alexej Scheremetjew, Rositha Kuniyil and Lutz Ackermann
Angewandte Chemie, 2021, 133, 1504
DOI: 10.1002/ange.202012105

Combining Two Types of Boron in One Molecule (To the 60th Anniversary of the First Synthesis of Carborane)
Igor B. Sivaev
Chemistry, 2023, 5, 834
DOI: 10.3390/chemistry5020059

Asymmetric Palladium Migration for Synthesis of Chiral‐at‐Cage o‐Carboranes
Chenyang Guo, Jie Zhang, Yixiu Ge, Zaozao Qiu and Zuowei Xie
Angew Chem Int Ed, 2025, 64
DOI: 10.1002/anie.202416987

N‐Ligand‐Enabled Aromatic Nucleophilic Amination of 1,2‐Diaryl‐o‐Carboranes with (R2N)2Mg for Selective Synthesis of 4‐R2N‐o‐Carboranes and 2‐R2N‐m‐Carboranes
Jie Zhang and Zuowei Xie
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202202675

N‐Donor/Fluorenyl o‐Carborane Fluorophores with Strong Crystallization‐Induced Emission
Zhaojin Wang, Tianyu Wang, Chi Zhang and Mark G. Humphrey
ChemPhotoChem, 2018, 2, 369
DOI: 10.1002/cptc.201700199

Site‐Selective Functionalization of Carboranes at the Electron‐Rich Boron Vertex: Photocatalytic B−C Coupling via a Carboranyl Cage Radical
Meng Chen, Jingkai Xu, Deshi Zhao, Fangxiang Sun, Songlin Tian, Deshuang Tu, Changsheng Lu and Hong Yan
Angewandte Chemie, 2022, 134
DOI: 10.1002/ange.202205672

Facile Construction of New Hybrid Conjugation via Boron Cage Extension
Fangxiang Sun, Shuaimin Tan, Hou-Ji Cao, Chang-sheng Lu, Deshuang Tu, Jordi Poater, Miquel Solà and Hong Yan
J. Am. Chem. Soc., 2023, 145, 3577
DOI: 10.1021/jacs.2c12526

Biphenyl- and Fluorene-Based o-Carboranyl Compounds: Alteration of Photophysical Properties by Distortion of Biphenyl Rings
Nara Shin, Seokhyeon Yu, Ji Hye Lee, Hyonseok Hwang and Kang Mun Lee
Organometallics, 2017, 36, 1522
DOI: 10.1021/acs.organomet.7b00093

Copper-Catalyzed Sonogashira-Type Coupling Reaction of Vinylacetylene ortho-Carborane with Boronic Acid in the Synthesis of Luminophores with Phosphorescent Emission
Timofey D. Moseev, Tair A. Idrisov, Mikhail V. Varaksin, Anton N. Tsmokaluk, Valery N. Charushin and Oleg N. Chupakhin
Reactions, 2024, 5, 868
DOI: 10.3390/reactions5040046

Synthesis of Carboranylated Dihydropyrrolo[1,2-a]quinoxalines and Dihydroindolo[1,2-a]quinoxalines by BF3·OEt2-Catalyzed Heterocyclization of C-Formyl-o-carboranes and Investigation of Their Oxidation Stability
Zhen-Zhen Sun, Pan Gao, Yong Yang, Tao Wang, Xiao-Jun Wu and You-Qing Wang
J. Org. Chem., 2024, 89, 3573
DOI: 10.1021/acs.joc.3c02443

Novel Dimeric o-Carboranyl Triarylborane: Intriguing Ratiometric Color-Tunable Sensor via Aggregation-Induced Emission by Fluoride Anions
Byung Hoon Choi, Ji Hye Lee, Hyonseok Hwang, Kang Mun Lee and Myung Hwan Park
Organometallics, 2016, 35, 1771
DOI: 10.1021/acs.organomet.6b00172

Fusing Carborane Carboxylic Acids with Alkynes: 3D Analogues of Isocoumarins via Regioselective B−H Activation
Furong Lin, Yunjun Shen, Yuanbin Zhang, Yuji Sun, Jiyong Liu and Simon Duttwyler
Chemistry A European J, 2018, 24, 551
DOI: 10.1002/chem.201703802

N–N bond cleavage and ring expansion at the surface of exchange and substitutional antisite defective boron nitride nanotubes by boron cluster: A density functional theory study
Maryam Anafcheh, Nasrin Shahbaz and Mansour Zahedi
Pramana - J Phys, 2019, 93
DOI: 10.1007/s12043-019-1825-0

Pd-Catalyzed One-Pot Synthesis of Difunctionalized o-Carboranes via Construction of B—C and B—Heteroatom Bonds※
Yixiu Ge, Zaozao Qiu and Zuowei Xie
Acta Chimica Sinica, 2022, 80, 432
DOI: 10.6023/A21120597

Effect of Planarity of Aromatic Rings Appended to o-Carborane on Photophysical Properties: A Series of o-Carboranyl Compounds Based on 2-Phenylpyridine- and 2-(Benzo[b]thiophen-2-yl)pyridine
Hyomin Jin, Seonah Kim, Hye Jin Bae, Ji Hye Lee, Hyonseok Hwang, Myung Hwan Park and Kang Mun Lee
Molecules, 2019, 24, 201
DOI: 10.3390/molecules24010201

Luminescence Color Tuning from Blue to Near Infrared of Stable Luminescent Solid Materials Based on Bis‐o‐Carborane‐Substituted Oligoacenes
Hirofumi Naito, Kenta Nishino, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo
Chemistry — An Asian Journal, 2017, 12, 2134
DOI: 10.1002/asia.201700815

Multinuclear “Staircase” Oligomers Based on the (Et2C2B4H4)Fe(η6-C6H6) Sandwich Unit: Quantitative Tailorable and Redox Switchable Nonlinear Optics
Hong-Qiang Wang, Li Wang, Yang-Yang Xia, Jin-Ting Ye, Hong-Yan Zhao and Yong-Qing Qiu
J. Phys. Chem. C, 2017, 121, 16470
DOI: 10.1021/acs.jpcc.7b03834

Effect of Iodination on the Photophysics of the Laser Borane anti-B18H22: Generation of Efficient Photosensitizers of Oxygen
Michael G. S. Londesborough, Jiří Dolanský, Jonathan Bould, Jakub Braborec, Kaplan Kirakci, Kamil Lang, Ivana Císařová, Pavel Kubát, Daniel Roca-Sanjuán, Antonio Francés-Monerris, Lenka Slušná, Eva Noskovičová and Dušan Lorenc
Inorg. Chem., 2019, 58, 10248
DOI: 10.1021/acs.inorgchem.9b01358

Catalytic Oxidative Dehydrogenative Coupling of Cage B–H/B–H Bonds for Synthesis of Bis(o-carborane)s
Ji Wu, Ke Cao, Cai-Yan Zhang, Tao-Tao Xu, Li-Fang Ding, Bo Li and Junxiao Yang
Org. Lett., 2019, 21, 5986
DOI: 10.1021/acs.orglett.9b02129

Solid‐State Emission of the Anthracene‐o‐Carborane Dyad from the Twisted‐Intramolecular Charge Transfer in the Crystalline State
Hirofumi Naito, Kenta Nishino, Yasuhiro Morisaki, Kazuo Tanaka and Yoshiki Chujo
Angew Chem Int Ed, 2017, 56, 254
DOI: 10.1002/anie.201609656

How substituents at boron atoms affect the CH-acidity and the electron-withdrawing effect of the ortho-carborane cage: A close look on the 1H NMR spectra
Igor B. Sivaev, Sergey A. Anufriev and Akim V. Shmalko
Inorganica Chimica Acta, 2023, 547, 121339
DOI: 10.1016/j.ica.2022.121339

Isomeric Impact of o-Carborane-Decorated Diboron-Embedded Multiresonance TADF Compounds on Photophysical Properties
Nhi Ngoc Tuyet Nguyen, Rafi Muhammad Lutfi, Jaemin Yun, Jaehoon Jung and Min Hyung Lee
Inorg. Chem., 2025, 64, 23030
DOI: 10.1021/acs.inorgchem.5c04375

Fused 1,2-Diboraoxazoles Based on closo-Decaborate Anion–Novel Members of Diboroheterocycle Class
Vera V. Voinova, Nikita A. Selivanov, Ivan V. Plyushchenko, Mikhail F. Vokuev, Alexander Yu. Bykov, Ilya N. Klyukin, Alexander S. Novikov, Andrey P. Zhdanov, Mikhail S. Grigoriev, Igor A. Rodin, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov
Molecules, 2021, 26, 248
DOI: 10.3390/molecules26010248

The in Situ NHC-Palladium Catalyzed Selective Activation of B(3)–H or B(6)–H Bonds of o-Carboranes for Hydroboration of Alkynes: An Efficient Approach to Alkenyl-o-carboranes
Ke Cao, Tao-Tao Xu, Ji Wu, Cai-Yan Zhang, Xin-Yu Wen and Junxiao Yang
Inorg. Chem., 2021, 60, 1080
DOI: 10.1021/acs.inorgchem.0c03203

Cage–···Cage– Interaction: Boron Cluster-Based Noncovalent Bond and Its Applications in Solid-State Materials
Deshuang Tu, Jiaxin Li, Fangxiang Sun, Hong Yan, Jordi Poater and Miquel Solà
JACS Au, 2021, 1, 2047
DOI: 10.1021/jacsau.1c00348

Boron Cluster Anions Dissolve En Masse in Lipids Causing Membrane Expansion and Thinning
Andrea Barba‐Bon, Alae El Haitami, Coralie Pasquier, Ivana Nikšić‐Franjić, Olivier Diat, Pierre Bauduin, Sophie Cantin and Werner M. Nau
Angew Chem Int Ed, 2024, 63
DOI: 10.1002/anie.202412834

Specificity of the reaction between carboryne and 3,6-diaryl-1,2,4,5-tetrazines
T. D. Moseev, D. S. Kopchuk, L. A. Smyshlyaeva, I. A. Khalymbadzha, P. A. Slepukhin, A. N. Tsmokalyuk, A. V. Rybakova, G. V. Zyryanov, M. V. Varaksin, V. N. Charushin and O. N. Chupakhin
Russ Chem Bull, 2025, 74, 2125
DOI: 10.1007/s11172-025-4696-1

Luminescent o-carboranyl-containing molecules: A promising platform for stimuli-responsive smart materials
Zhiyu Ran, Mengmeng Zhao, Junqing Shi and Lei Ji
Dyes and Pigments, 2025, 232, 112484
DOI: 10.1016/j.dyepig.2024.112484

Theoretical Insight into B–C Chemical Bonding in Closo-Borate [BnHn−1CH3]2− (n = 6, 10, 12) and Monocarborane [CBnHnCH3]− (n = 5, 9, 11) Anions
Ilya N. Klyukin, Anastasia V. Kolbunova, Alexander S. Novikov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov
Inorganics, 2022, 10, 186
DOI: 10.3390/inorganics10110186

Chemical bonding and nonadiabatic electron wavepacket dynamics in densely quasi-degenerate excited electronic state manifold of boron clusters
Yasuki Arasaki and Kazuo Takatsuka
The Journal of Chemical Physics, 2019, 150
DOI: 10.1063/1.5094149

Influence of Electronic Environment on the Radiative Efficiency of 9-Phenyl-9H-carbazole-Based ortho-Carboranyl Luminophores
Seok Ho Lee, Ji Hye Lee, Min Sik Mun, Sanghee Yi, Eunji Yoo, Hyonseok Hwang and Kang Mun Lee
Molecules, 2021, 26, 1763
DOI: 10.3390/molecules26061763

Relationship between the Molecular Geometry and the Radiative Efficiency in Naphthyl-Based Bis-Ortho-Carboranyl Luminophores
Sanghee Yi, Mingi Kim, Chan Hee Ryu, Dong Kyun You, Yung Ju Seo and Kang Mun Lee
Molecules, 2022, 27, 6565
DOI: 10.3390/molecules27196565

Amphiphilic Polycarbonates from Carborane-Installed Cyclic Carbonates as Potential Agents for Boron Neutron Capture Therapy
Hejian Xiong, Xing Wei, Dongfang Zhou, Yanxin Qi, Zhigang Xie, Xuesi Chen, Xiabin Jing and Yubin Huang
Bioconjugate Chem., 2016, 27, 2214
DOI: 10.1021/acs.bioconjchem.6b00454

[2 + 2] Cycloaddition of o-Carboryne with Vinyl Ethers: Synthesis of Carborane-Fused Cyclobutanes
Jie Zhang and Zuowei Xie
Organometallics, 2020, 39, 4214
DOI: 10.1021/acs.organomet.0c00163

Advances in the Synthesis of Biscarboranes
Ke Cao and Cai‐Yan Zhang
Eur J Org Chem, 2022, 2022
DOI: 10.1002/ejoc.202200737

Synthesis of Derivatives of closo-Dodecaborate Anion Based on Amino Acid Esters
A. V. Burdenkova, A. P. Zhdanov, I. N. Klyukin, N. A. Selivanov, A. Yu. Bykov, K. Yu. Zhizhin and N. T. Kuznetsov
Russ. J. Inorg. Chem., 2021, 66, 1616
DOI: 10.1134/S0036023621110036

Tetrakis{[(p‐dodecacarboranyl)methyl]stilbenyl}ethylene: A Luminescent Tetraphenylethylene (TPE) Core System
Justo Cabrera‐González, Santanu Bhattacharyya, Begoña Milián‐Medina, Francesc Teixidor, Norberto Farfán, Rafael Arcos‐Ramos, Verónica Vargas‐Reyes, Johannes Gierschner and Rosario Núñez
Eur J Inorg Chem, 2017, 2017, 4575
DOI: 10.1002/ejic.201700453

Deboronation-Induced Ratiometric Emission Variations of Terphenyl-Based Closo-o-Carboranyl Compounds: Applications to Fluoride-Sensing
Hyunhee So, Min Sik Mun, Mingi Kim, Jea Ho Kim, Ji Hye Lee, Hyonseok Hwang, Duk Keun An and Kang Mun Lee
Molecules, 2020, 25, 2413
DOI: 10.3390/molecules25102413

Visible-Light-Induced Olefin Activation Using 3D Aromatic Boron-Rich Cluster Photooxidants
Marco S. Messina, Jonathan C. Axtell, Yiqun Wang, Paul Chong, Alex I. Wixtrom, Kent O. Kirlikovali, Brianna M. Upton, Bryan M. Hunter, Oliver S. Shafaat, Saeed I. Khan, Jay R. Winkler, Harry B. Gray, Anastassia N. Alexandrova, Heather D. Maynard and Alexander M. Spokoyny
J. Am. Chem. Soc., 2016, 138, 6952
DOI: 10.1021/jacs.6b03568

closo‐Carboranylanaloga von β‐Arylethylaminen: Direkte Synthese aus Alkenen mittels EnT‐Katalyse
Fritz Paulus, Corinna Heusel, Marc Jaspers, Lilli M. Amrehn, Florian Schreiner, Debanjan Rana, Constantin G. Daniliuc, Michael Ryan Hansen and Frank Glorius
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202504793

Palladium‐Catalyzed Oxidative Annulation of 1‐Hydroxy‐o‐Carborane with Internal Alkynes: Facile Synthesis of Carborane‐Fused Oxaboroles†
Ruofei Cheng, Zaozao Qiu and Zuowei Xie
Chin. J. Chem., 2020, 38, 1575
DOI: 10.1002/cjoc.202000307

Water-Stable Carborane-Based Eu3+/Tb3+ Metal–Organic Frameworks for Tunable Time-Dependent Emission Color and Their Application in Anticounterfeiting Bar-Coding
Zhen Li, Rosario Núñez, Mark E. Light, Eliseo Ruiz, Francesc Teixidor, Clara Viñas, Daniel Ruiz-Molina, Claudio Roscini and José Giner Planas
Chem. Mater., 2022, 34, 4795
DOI: 10.1021/acs.chemmater.2c00323

Palladium‐Catalyzed Enantioselective B(4)−H Chlorination of o‐Carboranes by Chiral Transient Directing Groups
Yanglong Zou, Jie Zhang, Wei Hong, Zaozao Qiu and Zuowei Xie
Chin. J. Chem., 2026
DOI: 10.1002/cjoc.70552

Catalytic Regioselective Cage B(8)–H Arylation of o-Carboranes via “Cage-Walking” Strategy
Hairong Lyu, Jie Zhang, Jingting Yang, Yangjian Quan and Zuowei Xie
J. Am. Chem. Soc., 2019, 141, 4219
DOI: 10.1021/jacs.9b00302

Reaction of 4‐Bpin‐o‐Carborane with Ketones: Sequential Carbon Vertex Alkylation and B−B Bond Activation
Zhen Nie, Ruofei Cheng, Zaozao Qiu and Zuowei Xie
Chemistry — An Asian Journal, 2023, 18
DOI: 10.1002/asia.202300598

Iridium-Catalyzed Cyclative Indenylation and Dienylation through Sequential B(4)–C Bond Formation, Cyclization, and Elimination from o-Carboranes and Propargyl Alcohols
Yonghyeon Baek, Kiun Cheong, Gi Hoon Ko, Gi Uk Han, Sang Hoon Han, Dongwook Kim, Kooyeon Lee and Phil Ho Lee
J. Am. Chem. Soc., 2020, 142, 9890
DOI: 10.1021/jacs.0c02121

Far‐Red and Near‐Infrared Boron Schiff Bases (BOSCHIBAs) Dyes Bearing Anionic Boron Clusters
María M. Corona‐López, Blanca M. Muñoz‐Flores, Mahdi Chaari, Rosario Nuñez and Víctor M. Jiménez‐Pérez
Eur J Inorg Chem, 2021, 2021, 2047
DOI: 10.1002/ejic.202100144

Geometries of 11‐Vertex Carborane Monoanion Radicals with 2n+3 Skeletal Electron Counts
Natasha C. D. Patel, Josep M. Oliva‐Enrich and Mark A. Fox
Eur J Inorg Chem, 2017, 2017, 4568
DOI: 10.1002/ejic.201700419

Amidine-Linked Closo-Dodecaborate–Silica Hybrids: Synthesis and Characterization
Alexey V. Nelyubin, Nikolay K. Neumolotov, Vsevolod A. Skribitsky, Maria A. Teplonogova, Nikita A. Selivanov, Alexander Yu. Bykov, Victor P. Tarasov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov
Inorganics, 2026, 14, 27
DOI: 10.3390/inorganics14010027

Palladium‐Catalyzed Direct Cross‐Coupling of Carboranyllithium with (Hetero)Aryl Halides
Ju‐You Lu, Hong Wan, Jianwei Zhang, Zhixuan Wang, Yang Li, Yongmei Du, Chunying Li, Zhao‐Tie Liu, Zhong‐Wen Liu and Jian Lu
Chemistry A European J, 2016, 22, 17542
DOI: 10.1002/chem.201603967

Selective B(3)‐H Activation Affording Multinuclear Ir(III) Complexes with (o‐Carboranyl)dithioester Ligands
Yong‐Xiao Zhu, Run‐Ze Yuan, Hai‐Ning Zhang and Guo‐Xin Jin
Chemistry A European J, 2024, 30
DOI: 10.1002/chem.202401154

New sulfur derivatives of carboranes and metallacarboranes
Igor B. Sivaev, Marina Yu Stogniy, Sergei A. Anufriev, Maria V. Zakharova and Vladimir I. Bregadze
Phosphorus, Sulfur, and Silicon and the Related Elements, 2017, 192, 192
DOI: 10.1080/10426507.2016.1255616

Asymmetric Palladium Migration for Synthesis of Chiral‐at‐Cage o‐Carboranes
Chenyang Guo, Jie Zhang, Yixiu Ge, Zaozao Qiu and Zuowei Xie
Angewandte Chemie, 2025, 137
DOI: 10.1002/ange.202416987

Synthesis of C-Mercuro Derivatives of ortho-Carborane. Crystal Structure of Bis(2-phenyl-ortho-carboran-1-yl)mercury
S. A. Anufriev, S. V. Timofeev, D. I. Nasyrova, I. B. Sivaev and V. I. Bregadze
Russ. J. Inorg. Chem., 2024, 69, 625
DOI: 10.1134/S0036023624600187

Unraveling origin of chemoselectivity and regioselectivity of iridium‐catalyzed B(4)–H functionalization of o‐carborane by alkyne
Zitong Chen, Jiying Liu, Jiabin Liu, Panpan Bao, Hailing He, Hui Xia and Wenjing Zhang
J of Physical Organic Chem, 2023, 36
DOI: 10.1002/poc.4430

p-Terphenyl-based di-o-carboranyl compounds: Alteration of electronic transition state by terminal phenyl groups
Ji Hye Lee, Hyonseok Hwang and Kang Mun Lee
Journal of Organometallic Chemistry, 2016, 825-826, 69
DOI: 10.1016/j.jorganchem.2016.10.028

Covalent functionalization of octagraphene with magnetic octahedral B6− and non-planar C6− clusters
E. Chigo-Anota, G. Cárdenas-Jirón, M. Salazar Villanueva, A. Bautista Hernández and M. Castro
Physica E: Low-dimensional Systems and Nanostructures, 2017, 94, 196
DOI: 10.1016/j.physe.2017.08.012

Palladium-Catalyzed Selective Mono-/Tetraacetoxylation of o-Carboranes with Acetic Acid via Cross Dehydrogenative Coupling of Cage B–H/O–H Bonds
Tao-Tao Xu, Ke Cao, Ji Wu, Cai-Yan Zhang and Junxiao Yang
Inorg. Chem., 2018, 57, 2925
DOI: 10.1021/acs.inorgchem.8b00038

Analysis of closo-Decaborate Anion and Its Derivatives by Capillary Zone Electrophoresis
A. V. Kalistratova, D. V. Novikova, A. S. Kubasov, K. Yu. Zhizhin and N. T. Kuznetsov
Russ. J. Inorg. Chem., 2025, 70, 1318
DOI: 10.1134/S0036023625602168

Nucleophilic addition of hydrazine and benzophenone hydrazone to 2-acetonitrilium closo-decaborate cluster: Structural and photophysical study
Valeria K. Burianova, Dmitrii S. Bolotin, Alexander S. Novikov, Ilya E. Kolesnikov, Vitalii V. Suslonov, Andrey P. Zhdanov, Konstantin Yu. Zhizhin and Nikolay T. Kuznetsov
Inorganica Chimica Acta, 2018, 482, 838
DOI: 10.1016/j.ica.2018.07.038

Nido‐Carboranes: Donors for Thermally Activated Delayed Fluorescence
Nguyen Van Nghia, Saibal Jana, Surendran Sujith, Ji Yeon Ryu, Junseong Lee, Sang Uck Lee and Min Hyung Lee
Angewandte Chemie, 2018, 130, 12663
DOI: 10.1002/ange.201806922

Reversible Optical Data Storage via Two-Photon Micropatterning of o-Carboranes-Embedded Switchable Materials
Stephania Abdallah, Rana Mhanna, Justo Cabrera-González, Rosario Núñez, Amine Khitous, Fabrice Morlet-Savary, Olivier Soppera, Davy-Louis Versace and Jean-Pierre Malval
Chem. Mater., 2023, 35, 6979
DOI: 10.1021/acs.chemmater.3c01249

Solid‐State Thermochromic Luminescence through Twisted Intramolecular Charge Transfer and Excimer Formation of a Carborane−Pyrene Dyad with an Ethynyl Spacer
Kenta Nishino, Hideki Yamamoto, Kazuo Tanaka and Yoshiki Chujo
Asian J Org Chem, 2017, 6, 1818
DOI: 10.1002/ajoc.201700390