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Abstract | Cited by

Proline and phosphate promote a near-quantitative aldol reaction between glycolaldehyde phosphate and formaldehyde at neutral pH in water. Our results demonstrate the important role of general acid-base catalysis in water and underscore the essential role that amino acid catalysis may have played in early evolution of life's core metabolic pathways.

Graphical abstract: Prebiotic triose glycolysis promoted by co-catalytic proline and phosphate in neutral water

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