Issue 45, 2009
From the journal:

Chemical Communications

Regioselective synthesis of halohydrin esters from epoxides: reaction with acyl halides and rhodium-catalyzed three-component coupling reaction with alkyl halides and carbon monoxide†‡

Koji Nakano,a   Shunsuke Kodama,a   Yessi Permanaa  and  Kyoko Nozaki*a  

* Corresponding authors

a Department of Chemistry and Biotechnology, Graduate School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
E-mail: nozaki@chembio.t.u-tokyo.ac.jp
Fax: +81 3 5841 7263
Tel: +81 3 5841 7261

Abstract

Regioselective synthesis of halohydrin esters was achieved by (1) the reaction of acyl halides with epoxides and (2) the rhodium-catalyzed three-component coupling reaction of alkyl halides, carbon monoxide, and epoxides.

Graphical abstract: Regioselective synthesis of halohydrin esters from epoxides: reaction with acyl halides and rhodium-catalyzed three-component coupling reaction with alkyl halides and carbon monoxide

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Article information

DOI
https://doi.org/10.1039/B912907C
Article type
Communication
Submitted
01 Jul 2009
Accepted
06 Oct 2009
First published
16 Oct 2009

Chem. Commun., 2009, 6970-6972

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Regioselective synthesis of halohydrin esters from epoxides: reaction with acyl halides and rhodium-catalyzed three-component coupling reaction with alkyl halides and carbon monoxide

K. Nakano, S. Kodama, Y. Permana and K. Nozaki, Chem. Commun., 2009, 6970 DOI: 10.1039/B912907C

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