One-pot synthesis of atomically precise chiral PtAg4 nanoclusters

Yujie Zhang; Hongli Jia; Bingzheng Yan; Jian Hou; Huifang Guo; Qi Li; Chengrui Xin; Simin Li; Jinrun Dong; Hui Shen

doi:10.1039/D5CC03572D

One-pot synthesis of atomically precise chiral PtAg₄ nanoclusters

Yujie Zhang,†^a Hongli Jia,†^b Bingzheng Yan,^a Jian Hou,^a Huifang Guo,^a Qi Li,^a Chengrui Xin,^a Simin Li,^a Jinrun Dong*^a and Hui Shen

*^a

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^a College of Energy Materials and Chemistry, Inner Mongolia University, Hohhot 010021, China
E-mail: shen@imu.edu.cn, dongjrchem@imu.edu.cn

^b State Key Laboratory of Natural and Biomimetic Drugs, School of Pharmaceutical Sciences, Peking University, 38 Xueyuan Road, 100191 Beijing, China

Abstract

We report the synthesis and structural characterization of [PtAg₄Cl(BDPP)₄H]²⁺, a novel bimetallic complex featuring an intrinsically chiral architecture. The heterometallic Pt–Ag core exhibits distinctive optical properties, while the chiral BDPP (BDPP is 2,4-bis(diphenylphosphino)pentane) ligand not only induces structural asymmetry but also fine-tunes the electronic and steric characteristics of the complex.

Chemical Communications

One-pot synthesis of atomically precise chiral PtAg₄ nanoclusters

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One-pot synthesis of atomically precise chiral PtAg₄ nanoclusters

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