Are N-heterocyclic carbene radical cations relevant intermediates in radical transformations?

Preslav Smits, Ludivine Delfau, Sheima Bougoffa, Florian Molton, Jacques Pecaut, Julie Broggi, Eder Tomás-Mendivil and David Martin

Org. Chem. Front., 2026, 13, 54
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Evaluating the thermal behaviour of benzimidazolylidene sources for thin-film applications

Alex J. Veinot, Matthew B. E. Griffiths, Ishwar Singh, Joseph A. Zurakowski, Paul A. Lummis, Seán T. Barry and Cathleen M. Crudden

Mater. Adv., 2022, 3, 6446
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Impact of Carbene Ligands on the Properties and Reactivity of Diazoboranes

Chonghe Zhang, Agustin Valles, Junyi Wang, Noah D. McMillion, Christopher C. Cummins and Robert J. Gilliard

J. Am. Chem. Soc., 2025, 147, 36604
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In Situ Generation of n‐Type Dopants by Thermal Decarboxylation

Filip Aniés, Mohamad I. Nugraha, Arona Fall, Julianna Panidi, Yuxi Zhao, Patrice Vanelle, Leonidas Tsetseris, Julie Broggi, Thomas D. Anthopoulos and Martin Heeney

Adv Funct Materials, 2023, 33
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Triaminoalkenes Derived from Cyclic (Alkyl)(amino)carbenes with a 1,1′‐Ferrocenylene Backbone and N‐Heterocyclic Carbenes: fcCAAC–NHC Heterodimers

Suman Yadav, Clemens Bruhn, Clemens Lücke, Richard Rudolf, Tabea Pfister, Biprajit Sarkar and Ulrich Siemeling

ChemistryOpen, 2025, 14
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Synthesis of Para- and Meta-Phenylene Free Dicarbenes and Their Application as Proligands for Mo and Zr Complexes

Samuel D. Juárez-Escamilla, Anna C. Hopkins, Bruno Donnadieu and T. Keith Hollis

Organometallics, 2026, 45, 516
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A Strongly Reducing sp2 Carbon‐Conjugated Covalent Organic Framework Formed by N‐Heterocyclic Carbene Dimerization

Tristan A. Pitt, Tyler J. Azbell, Jaehwan Kim, Zixiao Shi, David A. Muller, Matthew A. Addicoat and Phillip J. Milner

Angewandte Chemie, 2025, 137
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Abstraction of Trifluoroborane from Tetrafluoroborate: Li+‐Assisted Borylation of Nucleophilic Carbenes

Eliza‐Jayne Y. Boisvert, Richard Ramos Castellanos, Michael J. Ferguson and Deryn E. Fogg

ChemCatChem, 2024, 16
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A Strongly Reducing sp2 Carbon‐Conjugated Covalent Organic Framework Formed by N‐Heterocyclic Carbene Dimerization

Tristan A. Pitt, Tyler J. Azbell, Jaehwan Kim, Zixiao Shi, David A. Muller, Matthew A. Addicoat and Phillip J. Milner

Angew Chem Int Ed, 2025, 64
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Harnessing Carbenoid Reactivity From Imidazoles and Oxiranes

Matthias R. Steiner, Johanna M. Uher, Jürgen Lindner, Cordula M. Zeiler and Christian Slugovc

Adv Synth Catal, 2026, 368
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Über Carbenintermediate in der AlI vermittelten Homologisierung von Isocyaniden

Cuijuan Zhang, Fabian Dankert, Ziang Jiang, Baolu Wang, Dominik Munz and Jiaxiang Chu

Angewandte Chemie, 2023, 135
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Evidence for Carbene Intermediates in Isocyanide Homologation by Aluminium(I)

Cuijuan Zhang, Fabian Dankert, Ziang Jiang, Baolu Wang, Dominik Munz and Jiaxiang Chu

Angew Chem Int Ed, 2023, 62
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Exploiting the Reversible Dimerization of N-Heterocyclic Carbenes to Access Dynamic Polymer Networks with an Organocatalytic Activity

Karine Abou-Ezze, Audrey Llevot and Daniel Taton

ACS Macro Lett., 2024, 13, 1008
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Bi(benzimidazole)-Based Super-Electron-Donors in Redox Polymers as Battery Electrode Materials

Philipp Penert, Bernd Schulz, Axel Florent, Philippe Poizot and Birgit Esser

ACS Appl. Polym. Mater., 2026
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