Main group bimetallic partnerships for cooperative catalysis

Jose M. Gil-Negrete and Eva Hevia

Chem. Sci., 2021, 12, 1982
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Sustainable and practical formation of carbon–carbon and carbon–heteroatom bonds employing organo-alkali metal reagents

Lu-Qiong Huo, Xin-Hao Wang, Zhenguo Zhang, Zhenhua Jia, Xiao-Shui Peng and Henry N. C. Wong

Chem. Sci., 2023, 14, 1342
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Diphenylacetylene stabilised alkali-metal nickelates: synthesis, structure and catalytic applications

Andryj M. Borys and Eva Hevia

Dalton Trans., 2023, 52, 2098
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Heavier alkaline earth and heterobimetallic s-block “ate” complexes of a di(amido)siloxane ligand: solid-state structure and dynamic solution-phase behaviour

Matthew D. Haynes, Andrea O'Reilly, Alice J. M. Poole, Aisling F. Roper, Stefan Thum, Louis J. Morris, Martyn P. Coles, J. Robin Fulton, Sjoerd Harder, Zoë R. Turner and Dermot O'Hare

Dalton Trans., 2025, 54, 4542
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Alkali-metal organomagnesiate complexes as catalysts for highly chemoselective crossed-Tishchenko reactions

Zhiqiang Guo, Tengfei Pang, Yakong Wang, Yongbin Zhang and Xuehong Wei

Dalton Trans., 2020, 49, 6418
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Use of heterometallic alkali metal–magnesium aryloxides in ring-opening polymerization of cyclic esters

Rafał Petrus, Tadeusz Lis and Adrian Kowaliński

Dalton Trans., 2022, 51, 9144
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Structural and metal–halogen exchange reactivity studies of sodium magnesiate biphenolate complexes

Callum Yeardley, Alan R. Kennedy, Philippe C. Gros, Sabrina Touchet, Michael Fairley, Ross McLellan, Antonio J. Martínez-Martínez and Charles T. O'Hara

Dalton Trans., 2020, 49, 5257
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Alkali Metal (Li, Na, K, Rb, Cs) Mediation in Magnesium Hexamethyldisilazide [Mg(HMDS)2] Catalysed Transfer Hydrogenation of Alkenes

Thomas X. Gentner, Alan R. Kennedy, Eva Hevia and Robert E. Mulvey

ChemCatChem, 2021, 13, 2371
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Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali‐Metal Amides under Air

Florian F. Mulks, Leonie J. Bole, Laia Davin, Alberto Hernán‐Gómez, Alan Kennedy, Joaquín García‐Álvarez and Eva Hevia

Angew Chem Int Ed, 2020, 59, 19021
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Alkalimetall‐Mediatoren: Vielfältige Anwendungen in der metallorganischen Chemie der Hauptgruppenelemente

Thomas X. Gentner and Robert E. Mulvey

Angewandte Chemie, 2021, 133, 9331
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Aminometallierung mit einem gemischten K/Li‐Amid: Eine Syntheseroute zu schwer zugänglichen Phenethylamin‐Derivaten

Andreas Hermann, Ulrike Opper, Andreas Voß, Lukas Brieger, Felix Otte, Christian Unkelbach, Donal F. O'Shea and Carsten Strohmann

Angewandte Chemie, 2020, 132, 22688
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Regioselective synthesis of 1,5-disubstituted 1,2,3-triazoles catalyzed by cooperative s-block bimetallics

Marco De Tullio, Andryj M. Borys, Alberto Hernán-Gómez, Alan R. Kennedy and Eva Hevia

Chem Catalysis, 2021, 1, 1308
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Untangling the Complexity of Mixed Lithium/Magnesium Alkyl/Alkoxy Combinations Utilised in Bromine/Magnesium Exchange Reactions

Leonie J. Bole, Neil R. Judge and Eva Hevia

Angew Chem Int Ed, 2021, 60, 7626
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Ambient Moisture Accelerates Hydroamination Reactions of Vinylarenes with Alkali‐Metal Amides under Air

Florian F. Mulks, Leonie J. Bole, Laia Davin, Alberto Hernán‐Gómez, Alan Kennedy, Joaquín García‐Álvarez and Eva Hevia

Angewandte Chemie, 2020, 132, 19183
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Heteroleptic Bis(amido) Ca(II) and Yb(II) NHC Pincer Complexes: Synthesis, Characterization, and Catalytic Activity in Intermolecular Hydrofunctionalization of C═C Bonds

Ivan V. Lapshin, Anton V. Cherkasov and Alexander A. Trifonov

Organometallics, 2023, 42, 2531
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Alkali‐Metal Mediation: Diversity of Applications in Main‐Group Organometallic Chemistry

Thomas X. Gentner and Robert E. Mulvey

Angew Chem Int Ed, 2021, 60, 9247
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Accessing Azetidines through Magnesium‐Mediated Nitrogen Group Transfer from Iminoiodinane to Donor‐Acceptor Cyclopropanes

Ajay H. Bansode, Lifeng Yin, Ning Deng, Mahmoud Afrasi, Yiyi Zhu and Marvin Parasram

Angew Chem Int Ed, 2025, 64
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Mechanistic Insight into Alkali‐Metal‐Mediation of Styrene Transfer Hydrogenation: A DFT Study

Keelan M. Byrne, Stuart D. Robertson, Robert E. Mulvey and Tobias Krämer

ChemCatChem, 2024
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Exploiting chemical cooperativity in main-group bimetallic catalysis

Andryj M. Borys and Eva Hevia

Trends in Chemistry, 2021, 3, 803
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Reactivity studies and structural outcomes of a bulky dialkylaluminium amide in the presence of the N-heterocyclic carbene, ItBu

Victoria A. Pollard, Maria-Angeles Fuentes, Stuart D. Robertson, Catherine Weetman, Alan R. Kennedy, Josh Brownlie, Fraser J. Angus, Cooper Smylie and Robert E. Mulvey

Polyhedron, 2021, 209, 115469
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Impact of the Alkali Metal on the Structural and Dynamic Properties of the Anionic Pentahydride Ruthenium Complexes [M(THF)x][RuH5(PCy3)2] (M = Li, Na, K)

Ramaraj Ayyappan, Koushik Saha, Mary Grellier, Eric Clot, Laure Vendier, Sundargopal Ghosh, Sylviane Sabo-Etienne and Sébastien Bontemps

Organometallics, 2021, 40, 3024
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Gram‐Scale Synthesis, Isolation and Characterisation of Sodium Organometallics:nBuNa and NaTMP

Andreu Tortajada, David E. Anderson and Eva Hevia

Helvetica Chimica Acta, 2022, 105
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Structural and Synthetic Insights on Oxidative Homocouplings of Alkynes Mediated by Alkali‐Metal Manganates

Pasquale Mastropierro, Andrew W. J. Platten, Alan R. Kennedy, Eva Hevia and Marina Uzelac

Chemistry A European J, 2023, 29
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Untangling the Complexity of Mixed Lithium/Magnesium Alkyl/Alkoxy Combinations Utilised in Bromine/Magnesium Exchange Reactions

Leonie J. Bole, Neil R. Judge and Eva Hevia

Angewandte Chemie, 2021, 133, 7704
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Unveiling the Structural Complexity of Lithium Organozinc Alkoxo Clusters and their Applications to Enantioselective Michael Addition Reactions

Marzia Dell'Aera, Filippo Maria Perna, Paola Vitale, Angela Altomare, Eva Hevia and Vito Capriati

Eur J Inorg Chem, 2024, 27
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Aminopotassiation by Mixed Potassium/Lithium Amides: A Synthetic Path to Difficult to Access Phenethylamine Derivates

Andreas Hermann, Ulrike Opper, Andreas Voß, Lukas Brieger, Felix Otte, Christian Unkelbach, Donal F. O'Shea and Carsten Strohmann

Angew Chem Int Ed, 2020, 59, 22500
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Structural and Reactivity Implications of Homo- and Heterobimetallic Co(II) Amides Prepared via Trans(amination) Reactions

Na Jin, Alessandra Logallo and Eva Hevia

Organometallics, 2025, 44, 197
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Room-Temperature Intermolecular Hydroamination of Vinylarenes Catalyzed by Alkali-Metal Ferrate Complexes

Andreu Tortajada and Eva Hevia

ACS Org. Inorg. Au, 2025, 5, 62
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Recent developments in the reduction of unsaturated bonds by magnesium precursors

Indrani Banerjee and Tarun K. Panda

Applied Organom Chemis, 2021, 35
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THF‐solvated Heavy Alkali Metal Benzyl Compounds (Na, Rb, Cs): Defined Deprotonation Reagents for Alkali Metal Mediation Chemistry

Lukas Brieger, Christian Unkelbach and Carsten Strohmann

Chemistry A European J, 2021, 27, 17780
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Hydrophosphinylation of Styrenes Catalysed by Well‐Defined s‐Block Bimetallics

Andrew W. J. Platten, Andryj M. Borys and Eva Hevia

ChemCatChem, 2022, 14
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New Approach to Substrate Activation or How Heterobimetallic Complexes {[(p-tBu-C6H4)2CH]3M}K (M = Ca and Yb) Make Intermolecular Olefin Hydroamination and NH3 Cascade Hydroamination/Hydroaminomethylation Feasible

Alexander N. Selikhov, Anton V. Cherkasov, Yulia V. Nelyubina and Alexander A. Trifonov

ACS Catal., 2023, 13, 12582
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Structural Diversity in Homoleptic Lithium Amidomanganate(II) Complexes: Impact of Amine Substitution

Rebecca S. Jones, Mary F. Mahon and Marina Uzelac

Eur J Inorg Chem, 2024, 27
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A potassium magnesiate complex: Synthesis, structure and catalytic intermolecular hydroamination of styrenes

Xiang-Yu Zhang, Dan-Dan Zhai, Yu-Feng Liu and Bing-Tao Guan

Journal of Organometallic Chemistry, 2022, 961, 122254
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Exploiting Deprotonative Co‐complexation to Access Potassium Metal(ates) Supported by a Bulky Silyl(bis)amide Ligand

Pasquale Mastropierro, Alan R. Kennedy and Eva Hevia

Eur J Inorg Chem, 2021, 2021, 1016
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Accessing Azetidines through Magnesium‐Mediated Nitrogen Group Transfer from Iminoiodinane to Donor‐Acceptor Cyclopropanes

Ajay H. Bansode, Lifeng Yin, Ning Deng, Mahmoud Afrasi, Yiyi Zhu and Marvin Parasram

Angewandte Chemie, 2025, 137
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