Mix and match – controlling the functionality of spin-crossover materials through solid solutions and molecular alloys

Malcolm A. Halcrow

Dalton Trans., 2024, 53, 13694
DOI: 10.1039/D4DT01855A

Questing for homoleptic mononuclear manganese complexes with monodentate O-donor ligands

Alberto Pérez-Bitrián, Julen Munárriz, Konstantin B. Krause, Johanna Schlögl, Kurt F. Hoffmann, Johanna S. Sturm, Amiera N. Hadi, Christian Teutloff, Anja Wiesner, Christian Limberg and Sebastian Riedel

Chem. Sci., 2024, 15, 5564
DOI: 10.1039/D4SC00543K

Probing the need for a very low axial zero-field splitting in MnII systems with slow relaxation of the magnetization

Evangelos Pilichos, Júlia Mayans and Albert Escuer

Dalton Trans., 2026, 55, 917
DOI: 10.1039/D5DT02349A

Combined experimental and theoretical investigation on the magnetic properties derived from the coordination of 6-methyl-2-oxonicotinate to 3d-metal ions

Laura Razquin-Bobillo, Oier Pajuelo-Corral, Beñat Artetxe, Andoni Zabala-Lekuona, Duane Choquesillo-Lazarte, Antonio Rodríguez-Diéguez, Eider San Sebastian and Javier Cepeda

Dalton Trans., 2022, 51, 9780
DOI: 10.1039/D2DT00838F

Coordination of dissolved transition metals in pristine battery electrolyte solutions determined by NMR and EPR spectroscopy

Jennifer P. Allen, Conrad Szczuka, Holly E. Smith, Erlendur Jónsson, Rüdiger-A. Eichel, Josef Granwehr and Clare P. Grey

Phys. Chem. Chem. Phys., 2024, 26, 19505
DOI: 10.1039/D4CP01663G

Spin state solvomorphism in a series of rare S = 1 manganese(iii) complexes

Andrew Barker, Conor T. Kelly, Irina A. Kühne, Stephen Hill, J. Krzystek, Paul Wix, Kane Esien, Solveig Felton, Helge Müller-Bunz and Grace G. Morgan

Dalton Trans., 2019, 48, 15560
DOI: 10.1039/C9DT02476J

Red-emitting K3HF2WO2F4:Mn4+ for application in warm-white phosphor-converted LEDs – optical properties and magnetic resonance characterization

Thomas Jansen, Lena Marie Funke, Jürgen Gorobez, David Böhnisch, Rolf-Dieter Hoffmann, Lukas Heletta, Rainer Pöttgen, Michael Ryan Hansen, Thomas Jüstel and Hellmut Eckert

Dalton Trans., 2019, 48, 5361
DOI: 10.1039/C9DT00091G

Binuclear cobalt(ii) and two-dimensional manganese(ii) coordination compounds self-assembled by mixed bipyridine-tetracarboxylic ligands with single-ion magnet properties

Dong-Qing Wu, Kusum Kumari, Yi Wan, Xueling Gao, Mengxi Guo, Genyan Liu, Dong Shao, Bin Zhai and Saurabh Kumar Singh

Dalton Trans., 2023, 52, 16197
DOI: 10.1039/D3DT03016D

K2SiF6:Mn4+ red-luminescent crystals with high external quantum efficiency (EQEmax of 78%) and high thermal quenching temperature (T1/2 > 500 K) enabling high brightness warm white LEDs

Wenrui Zhang, Yayun Zhou, Ce Shi, Jiajun Ren, Liying Zhang and Haipeng Ji

J. Mater. Chem. C, 2025, 13, 2337
DOI: 10.1039/D4TC04035J

Bulky ligands shape the separation between the large spin carriers to condition field-induced slow magnetic relaxation

Jedrzej Kobylarczyk, Michal Liberka, Piotr Konieczny, Stanisław Baran, Maciej Kubicki, Tomasz Korzeniak and Robert Podgajny

Dalton Trans., 2020, 49, 300
DOI: 10.1039/C9DT03903A

Rationalization of single-molecule magnet behavior in a three-coordinate Fe(iii) complex with a high-spin state (S= 5/2)

Ning Ge, Yuan-Qi Zhai, Yi-Fei Deng, You-Song Ding, Tao Wu, Zhen-Xing Wang, Zhongwen Ouyang, Hiroyuki Nojiri and Yan-Zhen Zheng

Inorg. Chem. Front., 2018, 5, 2486
DOI: 10.1039/C8QI00701B

Investigation of protonation induced metal-to-metal electron transfer in a cyano-bridged MnIII–FeIII dinuclear complex

Prashurya Pritam Mudoi, Niku Ahmed, Anup Choudhury, Yanling Li, Rodrigue Lescouëzec, Benjamin Kintzel, Oluseun Akintola, Winfried Plass, Marimuthu Rajendiran and Nayanmoni Gogoi

Dalton Trans., 2025, 54, 14161
DOI: 10.1039/D5DT01885D

Mn4+ non-equivalent doped fluoride phosphors with a short fluorescence decay time for backlighting

Jie Li, Xinyi Yang, Tong Li, Yanqing Ye, Yayun Zhou, Qin Wang, Qiang Zhou and Zhengliang Wang

Dalton Trans., 2022, 51, 2512
DOI: 10.1039/D1DT04191F

Orbital energy mismatch engenders high-spin ground states in heterobimetallic complexes

Scott C. Coste, Tyler J. Pearson, Alison B. Altman, Ryan A. Klein, Brian A. Finney, Michael Y. Hu, E. Ercan Alp, Bess Vlaisavljevich and Danna E. Freedman

Chem. Sci., 2020, 11, 9971
DOI: 10.1039/D0SC03777J

Organic chelate-free and azido-rich metal clusters and coordination polymers from the use of Me3SiN3: a new synthetic route to complexes with beautiful structures and diverse magnetic properties

Theocharis C. Stamatatos and Eva Rentschler

Chem. Commun., 2019, 55, 11
DOI: 10.1039/C8CC08854C

Quinol-containing ligands enable high superoxide dismutase activity by modulating coordination number, charge, oxidation states and stability of manganese complexes throughout redox cycling

Laura Senft, Jamonica L. Moore, Alicja Franke, Katherine R. Fisher, Andreas Scheitler, Achim Zahl, Ralph Puchta, Dominik Fehn, Sidney Ison, Safaa Sader, Ivana Ivanović-Burmazović and Christian R. Goldsmith

Chem. Sci., 2021, 12, 10483
DOI: 10.1039/D1SC02465E

Modulating the relaxation dynamics of the Na2Mn3 system via an auxiliary anion change

Yongfei Li, Xiao Sun, Peiqiong Chen, Hou-Ting Liu, Jing Li, Dan Liu, Dacheng Li, Jianmin Dou and Haiquan Tian

Dalton Trans., 2021, 50, 14774
DOI: 10.1039/D1DT01237A

Benchmarking magnetic and spectroscopic properties on highly stable 3d metal complexes with tuneable bis(benzoxazol-2-yl)methanide ligands

Christina M. Legendre, Daniel Lüert, Regine Herbst-Irmer and Dietmar Stalke

Dalton Trans., 2021, 50, 16810
DOI: 10.1039/D1DT03230E

Occurrence of slow relaxation of the magnetization in a family of copper(ii)/manganese(ii) quasi-isotropic complexes with different ground spin states

Evangelos Pilichos, Mercè Font-Bardia, Albert Escuer and Júlia Mayans

Dalton Trans., 2022, 51, 17653
DOI: 10.1039/D2DT02807G

Principles and applications of EPR spectroscopy in the chemical sciences

Maxie M. Roessler and Enrico Salvadori

Chem. Soc. Rev., 2018, 47, 2534
DOI: 10.1039/C6CS00565A

Thermally-induced hysteretic valence tautomeric conversions in the solid state via two-step labile electron transfers in manganese-nitronyl nitroxide 2D-frameworks

Constance Lecourt, Yuuta Izumi, Lhoussain Khrouz, François Toche, Rodica Chiriac, Nicolas Bélanger-Desmarais, Christian Reber, Oscar Fabelo, Katsuya Inoue, Cédric Desroches and Dominique Luneau

Dalton Trans., 2020, 49, 15646
DOI: 10.1039/D0DT03243C

Exchange coupling and single molecule magnetism in redox-active tetraoxolene-bridged dilanthanide complexes

Peng Zhang, Mauro Perfetti, Michal Kern, Philipp P. Hallmen, Liviu Ungur, Samuel Lenz, Mark R. Ringenberg, Wolfgang Frey, Hermann Stoll, Guntram Rauhut and Joris van Slageren

Chem. Sci., 2018, 9, 1221
DOI: 10.1039/C7SC04873D

Investigation of the magnetic anisotropy in a series of trigonal bipyramidal Mn(ii) complexes

Moya A. Hay, Arup Sarkar, Katie E. R. Marriott, Claire Wilson, Gopalan Rajaraman and Mark Murrie

Dalton Trans., 2019, 48, 15480
DOI: 10.1039/C9DT02187F

Rigid versions of PDTA4− incorporating a 1,3-diaminocyclobutyl spacer for Mn2+ complexation: stability, water exchange dynamics and relaxivity

Rocío Uzal-Varela, Daniela Lalli, Isabel Brandariz, Aurora Rodríguez-Rodríguez, Carlos Platas-Iglesias, Mauro Botta and David Esteban-Gómez

Dalton Trans., 2021, 50, 16290
DOI: 10.1039/D1DT02498A

A new eco-friendly and highly emitting Mn-based hybrid perovskite toward high-performance green down-converted LEDs

Asmae Ben Abdelhadi, Mario Gutiérrez, Boiko Cohen, Luis Lezama, Mohammed Lachkar and Abderrazzak Douhal

J. Mater. Chem. C, 2024, 12, 286
DOI: 10.1039/D3TC03821A

Amplified electron–spin thermal sensitivity in Mn(ii) complexes

Anthony J. Campanella, Amanda Gin, Siyoung Sung, Cassidy E. Jackson, Roxanna Martinez, Ökten Üngör, Srikanth Dasari, Andrew Ozarowski, Indrani Bhowmick and Joseph M. Zadrozny

Dalton Trans., 2026, 55, 5139
DOI: 10.1039/D5DT02920A

Crystal structures and magnetic properties of one-dimensional compounds constructed from Mn2(salen)2 building blocks and organic selenite acid ligands

Shao-Liang Zhang, Xin-Chao Li, Shi-Yu Gu, Shi Guo, Zi-Yu Liu, Su-Yuan Zeng and Shan-Shan Li

New J. Chem., 2021, 45, 21599
DOI: 10.1039/D1NJ03338G

Exploring the magnetic anisotropy and slow relaxation in heterometallic CoII–LnIII–CoII complexes: from synthesis to ab initio insights

Sukhendu Bikash Samanta, Soumalya Roy, Piotr Konieczny, Robert Pełka, Stanisław Baran, Mo Himchan, Atanu Dey, Junseong Lee and Sourav Das

Dalton Trans., 2025, 54, 16492
DOI: 10.1039/D5DT02024G

Slow magnetic relaxation in O–Se–O bridged manganese(iii) Schiff base complexes

Shao-Liang Zhang, Shan-Shan Li, Su-Yuan Zeng, Yang Shi, Da-Qi Wang and Lei Chen

New J. Chem., 2020, 44, 2408
DOI: 10.1039/C9NJ05837K

Triple responsive room temperature luminescence, photochromism and photomagnetism in a Dy(iii)-based linear chain complex

Wu-Ji Wei, Qian Zhang, Qi Li, Yao-Yao Chen, Pei Gao, Li Wei, Ji-Xiang Hu and Guo-Ming Wang

CrystEngComm, 2020, 22, 7538
DOI: 10.1039/D0CE01268H

Heavy ligand atom induced large magnetic anisotropy in Mn(ii) complexes

Sabyasachi Roy Chowdhury and Sabyashachi Mishra

Phys. Chem. Chem. Phys., 2017, 19, 16914
DOI: 10.1039/C7CP02957H

Isolation of EPR spectra and estimation of spin-states in two-component mixtures of paramagnets

Sonia Chabbra, David M. Smith and Bela E. Bode

Dalton Trans., 2018, 47, 10473
DOI: 10.1039/C8DT00977E

A preformed 1-D {CuII2}n helical chain as precursor to a decanuclear 0-D {CuII8MnII2} cluster: synthesis, structure and magnetism

Konstantinos N. Pantelis, Dimitris I. Alexandropoulos, Albert Escuer, George E. Kostakis and Theocharis C. Stamatatos

CrystEngComm, 2026, 28, 112
DOI: 10.1039/D5CE01110H

Water-Induced Dual Switching of Magnetic Properties and Proton Conduction in a Hydrogen-Bonded Manganese(II)-Organosulfonate Framework

Yi Chen, Fu-Wan Dong, Tao Xu, Lu-Yao Ma, Qi-Juan Cai, Zhengfang Tian, Jiong Yang, Le Shi and Dong Shao

Crystal Growth & Design, 2025, 25, 7752
DOI: 10.1021/acs.cgd.5c00940

Molecular Identification of a High-Spin Deprotonated Intermediate during the S2 to S3 Transition of Nature’s Water-Oxidizing Complex

Thomas A. Corry and Patrick J. O’Malley

J. Am. Chem. Soc., 2020, 142, 10240
DOI: 10.1021/jacs.0c01351

Mononuclear Manganese(III) Superoxo Complexes: Synthesis, Characterization, and Reactivity

Yen-Hao Lin, Hanna Hinrika Cramer, Maurice van Gastel, Yi-Hsuan Tsai, Chi-Yi Chu, Ting-Shen Kuo, I-Ren Lee, Shengfa Ye, Eckhard Bill and Way-Zen Lee

Inorg. Chem., 2019, 58, 9756
DOI: 10.1021/acs.inorgchem.9b00767

Electronic properties of the S = 5/2 Mn(II) complexes [Mn{PhC(O)NP(O)PPh2}(N,N)(NO3)], (N,N) = phenanthroline, neocuproine, 2,2′-bipyridine

Konstantina Nano, Georgia Zahariou, Polydoros-Chrisovalantis Ioannou, Md Mehboob Alam, Dimitrios A. Pantazis, Catherine P. Raptopoulou, Vassilis Psycharis, Yiannis Sanakis and Panayotis Kyritsis

Polyhedron, 2021, 207, 115374
DOI: 10.1016/j.poly.2021.115374

Field-Induced Slow Magnetic Relaxation in a Mononuclear Manganese(II) Complex

C. Rajnák, J. Titiš, J. Moncol, R. Mičová and R. Boča

Inorg. Chem., 2019, 58, 991
DOI: 10.1021/acs.inorgchem.8b02675

Correlating Bridging Ligand with Properties of Ligand-Templated [MnII3X3]3+Clusters (X = Br–, Cl–, H–, MeO–)

Kevin J. Anderton, David M. Ermert, Pedro A. Quintero, Mackenzie W. Turvey, Majed S. Fataftah, Khalil A. Abboud, Mark W. Meisel, Erik Čižmár and Leslie J. Murray

Inorg. Chem., 2017, 56, 12012
DOI: 10.1021/acs.inorgchem.7b02004

Modulation of Jahn–Teller distortion and electromechanical response in a Mn3+ spin crossover complex

Irina A Kühne, Andrew Barker, Fengyuan Zhang, Plamen Stamenov, Oisín O’Doherty, Helge Müller-Bunz, Matthias Stein, Brian J Rodriguez and Grace G Morgan

J. Phys.: Condens. Matter, 2020, 32, 404002
DOI: 10.1088/1361-648X/ab82d1

Syntheses, paramagnetism, and semiconducting characteristics of polynuclear manganese carbonyl chalcogenide anions: A review

Minghuey Shieh and Yu-Huei Li

Journal of Organometallic Chemistry, 2024, 1006, 123020
DOI: 10.1016/j.jorganchem.2024.123020

Mn(III) Chain Coordination Polymers Assembled by Salicylidene-2-ethanolamine Schiff Base Ligands: Synthesis, Crystal Structures, and HFEPR Study

Oleh Stetsiuk, Nataliya Plyuta, Narcis Avarvari, Evgeny Goreshnik, Vladimir Kokozay, Svitlana Petrusenko and Andrew Ozarowski

Crystal Growth & Design, 2020, 20, 1491
DOI: 10.1021/acs.cgd.9b01150

Family of Quasi-Isotropic MnII and Mn2II Complexes Exhibiting Slow Relaxation of the Magnetization

Evangelos Pilichos, Mercè Font-Bardia, Gabriel Aullón, Júlia Mayans and Albert Escuer

Inorg. Chem., 2024, 63, 20415
DOI: 10.1021/acs.inorgchem.4c02826

Spectroscopic and Magnetic Studies of Co(II) Scorpionate Complexes: Is There a Halide Effect on Magnetic Anisotropy?

Laxmi Devkota, Daniel J. SantaLucia, Amelia M. Wheaton, Alexander J. Pienkos, Sergey V. Lindeman, J. Krzystek, Mykhaylo Ozerov, John F. Berry, Joshua Telser and Adam T. Fiedler

Inorg. Chem., 2023, 62, 5984
DOI: 10.1021/acs.inorgchem.2c04468

Near-infrared 2Eg → 4A2g and visible LMCT luminescence from a molecular bis-(tris(carbene)borate) manganese(IV) complex

Joe P. Harris, Christian Reber, Hannah E. Colmer, Timothy A. Jackson, Adam P. Forshaw, Jeremy M. Smith, R. Adam Kinney and Joshua Telser

Can. J. Chem., 2017, 95, 547
DOI: 10.1139/cjc-2016-0607

Interpretation of EPR and optical spectra of Ni(II) ions in crystalline lattices at ambient temperature

Kamalon Amrutha and Velavan Kathirvelu

Magnetic Reson in Chemistry, 2022, 60, 414
DOI: 10.1002/mrc.5237

Direct evidence of hydration and temperature effects on the structure, spectroscopy and dynamics of a novel Mn-based organic-inorganic metal halide material for high-performance LEDs

Francisco Sánchez, Asmae Ben Abdelhadi, Mario Gutiérrez, Boiko Cohen, Luis Lezama and Abderrazzak Douhal

Materials Today Sustainability, 2025, 29, 101075
DOI: 10.1016/j.mtsust.2025.101075

Magnetospectroscopic Studies of a Series of Fe(II) Scorpionate Complexes: Assessing the Relationship between Halide Identity and Zero-Field Splitting

Daniel J. SantaLucia, Laxmi Devkota, Sergey V. Lindeman, Andrew Ozarowski, J. Krzystek, Mykhaylo Ozerov, Samuel M. Greer, Daniel C. Cummins, Klaus H. Theopold, Mihail Atanasov, Joshua Telser and Adam T. Fiedler

Inorg. Chem., 2025, 64, 16135
DOI: 10.1021/acs.inorgchem.5c02691

Unraveling the Stability and Magnetic Properties of Bis-Hydrated Mn(II) Complexes via Tailored Ligand Design

Niharika Keot and Manabendra Sarma

J. Phys. Chem. A, 2024, 128, 8346
DOI: 10.1021/acs.jpca.4c03053

Synthesis and electron paramagnetic resonance studies of seven coordinated Mn(II) complexes with tridentate N-donor ligands

Katerina N. Lazarou, Ioannis Stamatopoulos, Vassilis Psycharis, Carole Duboc, Catherine P. Raptopoulou and Yiannis Sanakis

Polyhedron, 2018, 155, 291
DOI: 10.1016/j.poly.2018.08.014

Advanced Paramagnetic Resonance Studies on Manganese and Iron Corroles with a Formal d4 Electron Count

J. Krzystek, Alexander Schnegg, Azar Aliabadi, Karsten Holldack, Sebastian A. Stoian, Andrew Ozarowski, Scott D. Hicks, Mahdi M. Abu-Omar, Kolle E. Thomas, Abhik Ghosh, Kenneth P. Caulfield, Zachary J. Tonzetich and Joshua Telser

Inorg. Chem., 2020, 59, 1075
DOI: 10.1021/acs.inorgchem.9b02635

Simultispin: A versatile graphical user interface for the simulation of solid‐state continuous wave EPR spectra

Florian Molton

Magnetic Reson in Chemistry, 2020, 58, 718
DOI: 10.1002/mrc.5019

Dangling and Hydrolyzed Ligand Arms in [Mn3] and [Mn6] Coordination Assemblies: Synthesis, Characterization, and Functional Activity

Krishna Chattopadhyay, Gavin A. Craig, María José Heras Ojea, Moumita Pait, Animesh Kundu, Junseong Lee, Mark Murrie, Antonio Frontera and Debashis Ray

Inorg. Chem., 2017, 56, 2639
DOI: 10.1021/acs.inorgchem.6b02813

ChemInform Abstract: Determination and Prediction of the Magnetic Anisotropy of Mn Ions

Carole Duboc

ChemInform, 2016, 47
DOI: 10.1002/chin.201649238

Molecular magnetism, quo vadis? A historical perspective from a coordination chemist viewpoint☆

Jesús Ferrando-Soria, Julia Vallejo, María Castellano, José Martínez-Lillo, Emilio Pardo, Joan Cano, Isabel Castro, Francesc Lloret, Rafael Ruiz-García and Miguel Julve

Coordination Chemistry Reviews, 2017, 339, 17
DOI: 10.1016/j.ccr.2017.03.004

Structural, spectroscopic, electrochemical, and magnetic properties for manganese(II) triazamacrocyclic complexes

Atanu Banerjee, Azam S. Tolla, Slavica Stjepanovic, Michael D. Sevilla, Justin L. Goodsell, Alexander Angerhofer, William W. Brennessel, Reza Loloee and Ferman A. Chavez

Inorganica Chimica Acta, 2019, 486, 546
DOI: 10.1016/j.ica.2018.11.013

Formation and Reactivity of an Elusive Monomeric Mn(IV)-Oxo Species Inside a Cavitand Pore

Galon Green, Kamal Uddin Ansari, Thejasree Munikrishna, Sagi Ezov, Donia Shamali, Laxmi-Narayan Nanda, Vitaly Gutkin, Orit Cohen, Daphna Shimon and Yuri Tulchinsky

J. Am. Chem. Soc., 2025, 147, 30647
DOI: 10.1021/jacs.5c02637

Stable manganese(II) complex with chlorido-substituted hexadentate Schiff base: Syntheses, crystal structure and spectral properties

Martin Schoeller, Karin Preinerová, Vladimír Jorík, Milan Mazúr and Jan Moncoľ

Inorganic Chemistry Communications, 2023, 147, 110237
DOI: 10.1016/j.inoche.2022.110237

Manganese–Cobalt Oxido Cubanes Relevant to Manganese-Doped Water Oxidation Catalysts

Andy I. Nguyen, Daniel L. M. Suess, Lucy E. Darago, Paul H. Oyala, Daniel S. Levine, Micah S. Ziegler, R. David Britt and T. Don Tilley

J. Am. Chem. Soc., 2017, 139, 5579
DOI: 10.1021/jacs.7b01792

Electron Paramagnetic Resonance in Rechargeable Battery Science: A Review

Wang Hu, Jinyang Li, Shuai Chen, Haiting Yu, Susana Suttor, Katarina Cicvarić and Aliaksandr S. Bandarenka

ACS Electrochem., 2026, 2, 25
DOI: 10.1021/acselectrochem.5c00371

Organic carboxylic acid fuels as structural modulators in combustion-synthesized CdFe2O4: enhanced pH-dependent photocatalytic performance

Dharmaraj J. Patil and Harpreet Singh Grewal

Environ Sci Pollut Res, 2026, 33, 4954
DOI: 10.1007/s11356-026-37620-3

Two-step magnetic ordering into a canted state in ferrimagnetic monoclinic Mn3As2

Manohar H. Karigerasi, Bao H. Lam, Maxim Avdeev and Daniel P. Shoemaker

Journal of Solid State Chemistry, 2021, 294, 121901
DOI: 10.1016/j.jssc.2020.121901

Controlling Zero-Field Splitting in Molecular Spin Qubits via Conjugation with Insights into Optical Addressability

Soumyasree Jena, Kalpak Ghosh and Sharma S. R. K. C. Yamijala

J. Phys. Chem. A, 2026, 130, 2350
DOI: 10.1021/acs.jpca.5c08126

Room Temperature Magnetic Switchability Assisted by Hysteretic Valence Tautomerism in a Layered Two-Dimensional Manganese-Radical Coordination Framework

Anthony Lannes, Yan Suffren, Jean Bernard Tommasino, Rodica Chiriac, François Toche, Lhoussain Khrouz, Florian Molton, Carole Duboc, Isabelle Kieffer, Jean-Louis Hazemann, Christian Reber, Andreas Hauser and Dominique Luneau

J. Am. Chem. Soc., 2016, 138, 16493
DOI: 10.1021/jacs.6b10544

Competing magnetostructural phases in a semiclassical system

Kenneth R. O’Neal, Jun Hee Lee, Maeng-Suk Kim, Jamie L. Manson, Zhenxian Liu, Randy S. Fishman and Janice L. Musfeldt

npj Quant Mater, 2017, 2
DOI: 10.1038/s41535-017-0065-0

The Critical Role of Ligand Flexibility on the Activity of Free and Immobilized Mn Superoxide Dismutase Mimics

Micaela Richezzi, Sharon Signorella, Claudia Palopoli, Nora Pellegri, Christelle Hureau and Sandra R. Signorella

Inorganics, 2023, 11, 359
DOI: 10.3390/inorganics11090359

A precisely space-separated strategy of donor-acceptor for intense red emitting composite borosilicate glass co-doped with CsPbCl3 quantum dots and Mn2+ ions

Lu-Yu Cao, Shuai-Chen Si, Jin-Bo Yu, Chong-Geng Ma, Jian-Bei Qiu and Jing Wang

Chemical Engineering Journal, 2021, 417, 129177
DOI: 10.1016/j.cej.2021.129177

Combined Experimental and Theoretical Investigation of the Origin of Magnetic Anisotropy in Pentagonal Bipyramidal Isothiocyanato Co(II), Ni(II), and Fe(III) Complexes with Quaternary-Ammonium-Functionalized 2,6-Diacetylpyridine Bisacylhydrazone

Darinka Darmanović, Igor N. Shcherbakov, Carole Duboc, Vojislav Spasojević, Darko Hanžel, Katarina Anđelković, Dušanka Radanović, Iztok Turel, Milica Milenković, Maja Gruden, Božidar Čobeljić and Matija Zlatar

J. Phys. Chem. C, 2019, 123, 31142
DOI: 10.1021/acs.jpcc.9b08066

Effect of Axial Ligands on Easy‐Axis Anisotropy and Field‐Induced Slow Magnetic Relaxation in Heptacoordinated FeII Complexes

Arpan Mondal, Shu‐Qi Wu, Osamu Sato and Sanjit Konar

Chemistry A European J, 2020, 26, 4780
DOI: 10.1002/chem.201905166

Homochiral Mn3+ Spin-Crossover Complexes: A Structural and Spectroscopic Study

Irina A. Kühne, Andrew Ozarowski, Aizuddin Sultan, Kane Esien, Anthony B. Carter, Paul Wix, Aoife Casey, Mooneerah Heerah-Booluck, Tony D. Keene, Helge Müller-Bunz, Solveig Felton, Stephen Hill and Grace G. Morgan

Inorg. Chem., 2022, 61, 3458
DOI: 10.1021/acs.inorgchem.1c03379

A manganese (II) dimer bearing the reduced derivatives of nitronyl nitroxides

Dimitris I. Alexandropoulos, Fanmiao Kong, Federico Lombardi, Peter N. Horton, Simon J. Coles and Lapo Bogani

Polyhedron, 2021, 209, 115427
DOI: 10.1016/j.poly.2021.115427

Overlooked Complexation and Competition Effects of Phenolic Contaminants in a Mn(II)/Nitrilotriacetic Acid/Peroxymonosulfate System: Inhibited Generation of Primary and Secondary High-Valent Manganese Species

Hongyu Zhou, Shuang Zhong, Junwen Chen, Shiying Ren, Wei Ren, Bo Lai, Xiaohong Guan, Tianyi Ma, Shaobin Wang and Xiaoguang Duan

Environ. Sci. Technol., 2024, 58, 19080
DOI: 10.1021/acs.est.4c07370

Double Dicyanamide Decorated Double Phenoxide Bridged Mn(Iii) Dimer with Single-Molecule Magnetic Behaviour and Bio-Catalytic Activity

RAJAT SAHA, Somen Goswami, Soumen Singha, Priyanka Chakraborty, Samia Benmansour, Subrata Kumar Dey, Carlos Gόmez-Garcίa and Sanjay Kumar

SSRN Journal, 2022
DOI: 10.2139/ssrn.4185520

Multiple Magnetic Responses in a Host–Guest Mononuclear Manganese(II) Complex

Shan-Nan Du, Wei Deng, Yan-Cong Chen, Jun-Liang Liu and Ming-Liang Tong

Crystal Growth & Design, 2026, 26, 374
DOI: 10.1021/acs.cgd.5c01337

Understanding the Effect of the Electron Spin Relaxation on the Relaxivities of Mn(II) Complexes with Triazacyclononane Derivatives

Rocío Uzal-Varela, Laura Valencia, Daniela Lalli, Marcelino Maneiro, David Esteban-Gómez, Carlos Platas-Iglesias, Mauro Botta and Aurora Rodríguez-Rodríguez

Inorg. Chem., 2021, 60, 15055
DOI: 10.1021/acs.inorgchem.1c02057

Double dicyanamide decorated double phenoxide bridged MnIII dimer with single-molecule magnetic behaviour and bio-catalytic activity

Somen Goswami, Soumen Singha, Bhaskar Khanra, Priyanka Chakraborty, Rajat Saha, Samia Benmansour, Subrata Kumar Dey, Carlos J. Gómez García and Sanjay Kumar

Inorganica Chimica Acta, 2023, 550, 121370
DOI: 10.1016/j.ica.2022.121370

Understanding Degradation at the Lithium-Ion Battery Cathode/Electrolyte Interface: Connecting Transition-Metal Dissolution Mechanisms to Electrolyte Composition

Di Huang, Chaiwat Engtrakul, Sanjini Nanayakkara, David W. Mulder, Sang-Don Han, Meng Zhou, Hongmei Luo and Robert C. Tenent

ACS Appl. Mater. Interfaces, 2021, 13, 11930
DOI: 10.1021/acsami.0c22235

Red Phosphor Rb2NbOF5:Mn4+ for Warm White Light-Emitting Diodes with a High Color-Rendering Index

Zhengliang Wang, Zhiyu Yang, Zhaofeng Yang, Qianwen Wei, Qiang Zhou, Li Ma and Xiaojun Wang

Inorg. Chem., 2019, 58, 456
DOI: 10.1021/acs.inorgchem.8b02676

An overview of solid-state electron paramagnetic resonance spectroscopy for artificial fuel reactions

Jeremy A. Bau, Abdul-Hamid Emwas and Magnus Rueping

iScience, 2022, 25, 105360
DOI: 10.1016/j.isci.2022.105360

Magnetic Anisotropy in Heterobimetallic Complexes

Scott C. Coste, Tyler J. Pearson and Danna E. Freedman

Inorg. Chem., 2019, 58, 11893
DOI: 10.1021/acs.inorgchem.9b01459

Synthesis, Structure, and Magnetic Properties of a Mononuclear Chiral (Acetato)bis(aminoalkoxido)manganese(III) Complex

Arkadiusz Kornowicz, Michał Terlecki, Daniel Prochowicz, Céline Pichon, Iwona Justyniak, Wojciech Bury, Zbigniew Wróbel, Jean‐Pascal Sutter and Janusz Lewiński

Eur J Inorg Chem, 2017, 2017, 1392
DOI: 10.1002/ejic.201700084

Record High Magnetic Anisotropy in Three-Coordinate MnIII and CrII Complexes: A Theoretical Perspective

Arup Sarkar, Reshma Jose, Harshit Ghosh and Gopalan Rajaraman

Inorg. Chem., 2021, 60, 9680
DOI: 10.1021/acs.inorgchem.1c00978

Iron(III) Complexes of a Hexadentate Thioether-Appended 2-Aminophenol Ligand: Redox-Driven Spin State Switchover

Akram Ali, Saumitra Bhowmik, Suman K. Barman, Narottam Mukhopadhyay, Christine E. Glüer (nee Schiewer), Francesc Lloret, Franc Meyer and Rabindranath Mukherjee

Inorg. Chem., 2022, 61, 5292
DOI: 10.1021/acs.inorgchem.1c03992

Spin-orbit driven electrical manipulation of the zero-field splitting in high-spin centers in solids

Timur Biktagirov and Uwe Gerstmann

Phys. Rev. Research, 2020, 2
DOI: 10.1103/PhysRevResearch.2.023071

Effect of Coulomb Correlation on the Magnetic Properties of Mn Clusters

Chengxi Huang, Jian Zhou, Kaiming Deng, Erjun Kan and Puru Jena

J. Phys. Chem. A, 2018, 122, 4350
DOI: 10.1021/acs.jpca.8b00540

Structural Engineering of Layered Nanomaterials for Biomedical Applications

Tingting Hu, Yu Yang, Tao Wang, Min Ge, Chaojie Yu, Jiajia Zha, Xiangrong Pan, Zhan Zhou, Lufang Ma, Ruizheng Liang and Chaoliang Tan

Chem. Rev., 2025, 125, 8764
DOI: 10.1021/acs.chemrev.5c00193

From antiferromagnetic to ferromagnetic exchange in a family of phenoxido-bridged heterodinuclear Cu(II)-Mn(II) complexes: A magneto-structural theoretical study

Shuchang Luo, Xiaoyuan Sun, Bing Zeng and Pengfei Zheng

Polyhedron, 2021, 194, 114955
DOI: 10.1016/j.poly.2020.114955

Experimental and theoretical investigations on magneto-structural correlation in trinuclear copper(II) hydroxido propellers

Luca Rigamonti, Alessandra Forni, Maurizio Sironi, Alessandro Ponti, Anna M. Ferretti, Carlo Baschieri and Alessandro Pasini

Polyhedron, 2018, 145, 22
DOI: 10.1016/j.poly.2018.01.028

Spontaneous Formation of an Fe/Mn Diamond Core: Models for the Fe/Mn Sites in Class 1c Ribonucleotide Reductases

Patrick M. Crossland, Yisong Guo and Lawrence Que

Inorg. Chem., 2021, 60, 8710
DOI: 10.1021/acs.inorgchem.1c00684

Electronic Structure Study of Rhombic MnII Complexes with Hexadentate N4O2 Chelate Ligands

Conor T. Kelly, Brittany Grimm, Eimear Harrison, Vibe B. Jakobsen, Ross Jordan, Solveig Felton, Helge Müller-Bunz, Stephen Hill and Grace G. Morgan

Inorg. Chem., 2026, 65, 6464
DOI: 10.1021/acs.inorgchem.5c05377

Monitoring of Fe(II) Spin Transition in Cu(II)-Doped Spin-Crossover Nanoparticles

Alexander Charitos, Vassilis Tangoulis, John Parthenios, Ondrej Malina, Radim Mach, Nikolaos Ioannidis and Nikolia Lalioti

Molecules, 2025, 30, 1258
DOI: 10.3390/molecules30061258

Manganese Telluride Carbonyl Complexes: Facile Syntheses and Exotic Properties—Reversible Transformations, Hydrogen Generation, Paramagnetic, and Semiconducting Properties

Minghuey Shieh, Yu-Hsin Liu, Tien-Sung Lin, Yu-Chun Lin, Wen-Kai Cheng and Ru Yan Lin

Inorg. Chem., 2020, 59, 6923
DOI: 10.1021/acs.inorgchem.0c00412

The QTAIM and ELF approaches to chemical bonding in chalcogen-bridging tetra-manganese carbonyl clusters: [E2Mn4(CO)12]2− (E = S, Se, Te)

Ahlam Hussein Hassan, Nadia Ezzat Al-kirbasee, Emad Salaam Abood, Waqed H. Hassan and Muhsen Abood Muhsen Al-Ibadi

Computational and Theoretical Chemistry, 2026, 1255, 115528
DOI: 10.1016/j.comptc.2025.115528

Magnetic Properties and Electronic Structure of the S = 2 Complex [MnIII{(OPPh2)2N}3] Showing Field-Induced Slow Magnetization Relaxation

Yiannis Sanakis, J. Krzystek, Dimitrios Maganas, Alexios Grigoropoulos, Eleftherios Ferentinos, Marios G. Kostakis, Vasiliki Petroulea, Michael Pissas, Komalavalli Thirunavukkuarasu, Wolfgang Wernsdorfer, Frank Neese and Panayotis Kyritsis

Inorg. Chem., 2020, 59, 13281
DOI: 10.1021/acs.inorgchem.0c01636

Influence of the Disposition of the Anisotropy Axes into the Magnetic Properties of MnIII Dinuclear Compounds with Benzoato Derivative Bridges

Beltzane Garcia-Cirera, Silvia Gómez-Coca, Mercè Font-Bardia, Eliseo Ruiz and Montserrat Corbella

Inorg. Chem., 2017, 56, 8135
DOI: 10.1021/acs.inorgchem.7b00877

Interplay of Manganese Doping in Lead-Free Cs3Bi2Br9 Nanocrystals

James Harry Martin, Eliseo Ruiz, Luis Lezama, Shahzada Ahmad and Samrana Kazim

ACS Appl. Opt. Mater., 2025, 3, 2725
DOI: 10.1021/acsaom.5c00416

Electron Spin Relaxation of Mn(IV) Complexes in Glassy Solvent Mixtures

Tanden A. Hovey, Manveer Singh, Surendra N. Mahapatro, Sandra S. Eaton and Gareth R. Eaton

Appl Magn Reson, 2026, 57
DOI: 10.1007/s00723-026-01827-x

Moiré Superlattices of Zn2+ Mediated 2D Assembly of Mn2+-Cysteine Complex Nanoparticles Alter Electron Spin Transitions in the X-Band

Archismita Hajra and Arun Chattopadhyay

Chem. Mater., 2024, 36, 8523
DOI: 10.1021/acs.chemmater.4c01779