Issue 16, 2024

Mechanochemical ignition of self-propagating reactions in equimolar Al–Ni powder mixtures and multilayers

Abstract

This work addresses a long standing question in the field of mechanochemistry, namely the role of mesostructure in the initiation of self-propagating high-temperature reactions in exothermic chemical systems, commonly referred to as ignition. In an attempt to find robust evidence in this regard, we compare the ignition behaviour of equimolar Al–Ni powder mixtures and equimolar Al–Ni multilayers. To achieve the best possible control of experimental conditions and allowing high reproducibility, we used elemental powders sieved in the range between 20 μm and 44 μm, and multilayers with bi-layer thickness between 10 nm and 800 nm. We carried out systematic ball milling experiments involving pristine powder mixtures and multilayers as well as a mix of pristine material and material prone to ignition suitably prepared. Experimental findings suggest that pristine powder mixtures and multilayers with bi-layer thickness of 240 nm have analogous ignition behaviour. Along the same lines, data suggest that pristine powder mixtures undergo ignition when they attain a mesostructure similar to that of multilayers with bi-layer thickness of 10 nm.

Graphical abstract: Mechanochemical ignition of self-propagating reactions in equimolar Al–Ni powder mixtures and multilayers

Article information

Article type
Paper
Submitted
07 Nov. 2023
Accepted
09 Apr. 2024
First published
12 Apr. 2024

Phys. Chem. Chem. Phys., 2024,26, 12316-12323

Mechanochemical ignition of self-propagating reactions in equimolar Al–Ni powder mixtures and multilayers

M. Carta and F. Delogu, Phys. Chem. Chem. Phys., 2024, 26, 12316 DOI: 10.1039/D3CP05401B

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