Issue 8, 2023

Post-synthetic modulation of UiO-66-NH2 with a cobaloxime catalyst for efficient hydrogen production

Abstract

Post synthetically-modified UiO-66-NH2 with a molecular cobaloxime [Co(DMG)2Cl2] (DMG = dimethylglyoxime) catalyst displays excellent photo-(404 μmol g−1 h−1) and electrocatalytic H2 evolution activity in an aqueous solution. Several analytical and spectroscopic methods, including femtosecond transient absorption spectroscopy and DFT, revealed the unique interaction between cobaloxime and the MOF leading to enhanced catalytic activity.

Graphical abstract: Post-synthetic modulation of UiO-66-NH2 with a cobaloxime catalyst for efficient hydrogen production

Supplementary files

Article information

Article type
Communication
Submitted
07 Apr. 2023
Accepted
19 Jun. 2023
First published
19 Jun. 2023
This article is Open Access
Creative Commons BY-NC license

Energy Adv., 2023,2, 1116-1121

Post-synthetic modulation of UiO-66-NH2 with a cobaloxime catalyst for efficient hydrogen production

S. Sk, S. P. Shelake, D. Dolui, S. Karim, R. Ghosh, M. V. Jyothirmai, A. V. S. Sainath, U. Pal and A. Dutta, Energy Adv., 2023, 2, 1116 DOI: 10.1039/D3YA00151B

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