Issue 70, 2019

A self-catalyzed reaction of 1,2-dibenzoyl-o-carborane with hydrosilanes – formation of new hydrofuranes

Abstract

The activation of Si–H bonds is a very important transformation both in organic and inorganic chemistry. Herein we report that 1,2-dibenzoyl-o-carborane (1) reacts with Si–H bonds, yielding new hydrofurane-type products. The mechanism of this Si–H bond activation was studied both experimentally and by DFT calculations, and supposedly proceeds in an FLP-type manner.

Graphical abstract: A self-catalyzed reaction of 1,2-dibenzoyl-o-carborane with hydrosilanes – formation of new hydrofuranes

Supplementary files

Article information

Article type
Communication
Submitted
21 Jun. 2019
Accepted
06 Aug. 2019
First published
06 Aug. 2019

Chem. Commun., 2019,55, 10448-10451

A self-catalyzed reaction of 1,2-dibenzoyl-o-carborane with hydrosilanes – formation of new hydrofuranes

K. Jaiswal, S. Volodarsky, V. Kampel and R. Dobrovetsky, Chem. Commun., 2019, 55, 10448 DOI: 10.1039/C9CC04780H

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