Supramolecular ligand–ligand and ligand–substrate interactions for highly selective transition metal catalysis

Stefano Carboni, Cesare Gennari, Luca Pignataro and Umberto Piarulli

Dalton Trans., 2011, 40, 4355
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Martin B. Smith

Annu. Rep. Prog. Chem., Sect. A: Inorg. Chem., 2010, 106, 207
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Enantioselective synthesis of 1-vinyltetrahydroisoquinolines through palladium-catalysed intramolecular allylic amidation with chiral PhthalaPhos ligands

Luca Pignataro, Enrico Marelli, Cesare Gennari and Raffaella Ferraccioli

Tetrahedron: Asymmetry, 2014, 25, 844
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The use of mixtures of ligands in the Ir-catalyzed asymmetric reductive amination of 6-methyl-2,3,4,9-tetrahydro-1H-carbazol-1-one

S. E. Lyubimov, D. V. Ozolin, A. A. Pavlov, P. Yu. Ivanov, K. B. Mayorov, V. S. Velezheva, V. A. Davankov and B. V. Nikonenko

Russ Chem Bull, 2015, 64, 1591
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Synthesis of a 4‐Vinyltetrahydrocarbazole by Palladium‐Catalyzed Asymmetric Allylic Alkylation of Indole‐Containing Allylic Carbonates

Luca Pignataro, Daniele Fiorito, Vito Vece, Raffaella Ferraccioli and Cesare Gennari

Eur J Org Chem, 2015, 2015, 6669
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Ligand relay catalysis for cobalt-catalyzed sequential hydrosilylation and hydrohydrazidation of terminal alkynes

Yufeng Sun, Jun Guo, Xuzhong Shen and Zhan Lu

Nat Commun, 2022, 13
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Recent Advances in Enantioselective Pd-Catalyzed Allylic Substitution: From Design to Applications

Oscar Pàmies, Jèssica Margalef, Santiago Cañellas, Jinju James, Eric Judge, Patrick J. Guiry, Christina Moberg, Jan-E. Bäckvall, Andreas Pfaltz, Miquel A. Pericàs and Montserrat Diéguez

Chem. Rev., 2021, 121, 4373
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Phosphine Oxide Based Supramolecular Ligands in the Rhodium-Catalyzed Asymmetric Hydrogenation

Julien Daubignard, Remko J. Detz, Bas de Bruin and Joost N. H. Reek

Organometallics, 2019, 38, 3961
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Riding the Wave of Monodentate Ligand Revival: From the A/B Concept to Noncovalent Interactions

Luca Pignataro and Cesare Gennari

The Chemical Record, 2016, 16, 2544
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Strategic convergence in ligand exchange relay catalysis: unifying coordination of ’dual-ligand/single-metal’ and ’dual-metal/single-ligand’ paradigms in advanced catalysis

Ankit Kachore, Varun Aggarwal, Ekta Bala, Hemant Singh, Manickam Selvaraj, Mohammed A. Assiri, Saima, Rakesh Kumar and Praveen Kumar Verma

Journal of Catalysis, 2026, 457, 116822
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Selective hydroformylation of 1-hexene to branched aldehydes using rhodium complex of modified bulky phosphine and phosphite ligands

Aasif A. Dabbawala, Raksh V. Jasra and Hari C. Bajaj

Catalysis Communications, 2011, 12, 403
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Nonsimple relationships between the P∗-chiral diamidophosphite and the arylphosphine moieties in Pd-catalyzed asymmetric reactions: combinatorial approach and P,P∗-bidentate phosphine-diamidophosphites

Konstantin N. Gavrilov, Alexei A. Shiryaev, Sergey V. Zheglov, Vladislav K. Gavrilov, Nikolay N. Groshkin, Marina G. Maksimova, Alexandr N. Volov and Ilya A. Zamilatskov

Tetrahedron, 2014, 70, 616
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Phosphite-Containing Ligands for Asymmetric Catalysis

Piet W. N. M. van Leeuwen, Paul C. J. Kamer, Carmen Claver, Oscar Pàmies and Montserrat Diéguez

Chem. Rev., 2011, 111, 2077
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PhthalaPhos: Chiral Supramolecular Ligands for Enantioselective Rhodium‐Catalyzed Hydrogenation Reactions

Luca Pignataro, Stefano Carboni, Monica Civera, Raffaele Colombo, Umberto Piarulli and Cesare Gennari

Angew Chem Int Ed, 2010, 49, 6633
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Minimizing Aryloxy Elimination in RhI‐Catalyzed Asymmetric Hydrogenation of β‐Aryloxyacrylic Acids using a Mixed‐Ligand Strategy

Yang Li, Zheng Wang and Kuiling Ding

Chemistry A European J, 2015, 21, 16387
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Dynamic multiligand catalysis: A polar to radical crossover strategy expands alkyne carboboration to unactivated secondary alkyl halides

Shin-Ho Kim-Lee, Pablo Mauleón, Ramón Gómez Arrayás and Juan C. Carretero

Chem, 2021, 7, 2212
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Rhodium(I)‐Catalyzed Enantioselective Hydrogenation of Substituted Acrylic Acids with Sterically Similar β,β‐Diaryls

Yang Li, Kaiwu Dong, Zheng Wang and Kuiling Ding

Angew Chem Int Ed, 2013, 52, 6748
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Catalytic Asymmetric Hydrogenation of α‐CF3‐ or β‐CF3‐Substituted Acrylic Acids using Rhodium(I) Complexes with a Combination of Chiral and Achiral Ligands

Kaiwu Dong, Yang Li, Zheng Wang and Kuiling Ding

Angew Chem Int Ed, 2013, 52, 14191
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Rhodium‐Catalyzed Asymmetric Hydrogenation of Olefins with PhthalaPhos, a New Class of Chiral Supramolecular Ligands

Luca Pignataro, Michele Boghi, Monica Civera, Stefano Carboni, Umberto Piarulli and Cesare Gennari

Chemistry A European J, 2012, 18, 1383
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Synthesis and Characterization of New, Chiral P−N Ligands and Their Use in Asymmetric Allylic Alkylation

Kurtis E. Thiesen, Kalyani Maitra, Marilyn M. Olmstead and Saeed Attar

Organometallics, 2010, 29, 6334
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PhthalaPhos: Chiral Supramolecular Ligands for Enantioselective Rhodium‐Catalyzed Hydrogenation Reactions

Luca Pignataro, Stefano Carboni, Monica Civera, Raffaele Colombo, Umberto Piarulli and Cesare Gennari

Angewandte Chemie, 2010, 122, 6783
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ChemInform Abstract: Combination of a Binaphthol‐Derived Phosphite and a C1‐Symmetric Phosphinamine Generates Heteroleptic Catalysts in Rh‐ and Pd‐Mediated Reactions.

Luca Pignataro, Benita Lynikaite, Raffaele Colombo, Stefano Carboni, Martin Krupicka, Umberto Piarulli and Cesare Gennari

ChemInform, 2009, 40
DOI: 10.1002/chin.200943025

Synthesis, complexation behavior and application of a new diphosphite ligand in rhodium-catalyzed hydroformylation

Igor S. Mikhel, Natalia V. Dubrovina, Ivan A. Shuklov, Wolfgang Baumann, Detlef Selent, Haijun Jiao, Andrea Christiansen, Robert Franke and Armin Börner

Journal of Organometallic Chemistry, 2011, 696, 3050
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Catalytic Asymmetric Hydrogenation of α‐CF3‐ or β‐CF3‐Substituted Acrylic Acids using Rhodium(I) Complexes with a Combination of Chiral and Achiral Ligands

Kaiwu Dong, Yang Li, Zheng Wang and Kuiling Ding

Angewandte Chemie, 2013, 125, 14441
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Asymmetric iridium-catalyzed hydrogenation of 2-methylindole using phosphite ligands

Sergey E. Lyubimov, Dmitry V. Ozolin and Vadim A. Davankov

Tetrahedron Letters, 2014, 55, 3613
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Rhodium(I)‐Catalyzed Enantioselective Hydrogenation of Substituted Acrylic Acids with Sterically Similar β,β‐Diaryls

Yang Li, Kaiwu Dong, Zheng Wang and Kuiling Ding

Angewandte Chemie, 2013, 125, 6880
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A Library Approach to the Development of BenzaPhos: Highly Efficient Chiral Supramolecular Ligands for Asymmetric Hydrogenation

Luca Pignataro, Chiara Bovio, Monica Civera, Umberto Piarulli and Cesare Gennari

Chemistry A European J, 2012, 18, 10368
DOI: 10.1002/chem.201201032