Issue 22, 2024

Spin crossover {[Fe(atrz)3](OTs)2}n monolith: a green synthesis approach for Robust switchable materials

Abstract

This work presents a straightforward, room-temperature synthesis of a robust {[Fe(atrz)3](OTs)2}n monolith. This approach offers a green alternative to traditional nanoparticle synthesis for manipulating spin crossover (SCO) behaviour. The monolith exhibits a more gradual SCO transition at lower temperatures compared to the bulk material, aligning with observations in smaller particle systems. Notably, the synthesis employs a solvent- and surfactant-free approach, simplifying the process and potentially reducing environmental impact, aligning with the principles of green chemistry.

Graphical abstract: Spin crossover {[Fe(atrz)3](OTs)2}n monolith: a green synthesis approach for Robust switchable materials

Supplementary files

Article information

Article type
Communication
Submitted
06 Cig 2024
Accepted
02 Cax 2024
First published
22 Cax 2024

Dalton Trans., 2024,53, 9257-9261

Spin crossover {[Fe(atrz)3](OTs)2}n monolith: a green synthesis approach for Robust switchable materials

A. Martinez-Martinez, P. Albacete, M. García-Hernández, E. Resines-Urien, D. Fairen-Jimenez and J. Sánchez Costa, Dalton Trans., 2024, 53, 9257 DOI: 10.1039/D4DT00684D

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