Issue 61, 2024

Amplification of negative gas adsorption in a multivariate framework

Abstract

The approach of employing multivariate MOFs was used to fine-tune the mechanical properties of the flexible framework DUT-49. In situ XRD, NMR and physisorption studies showed that the partial incorporation of a more rigid linker into the DUT-49 framework enables stabilization of the metastable open pore phase, which led to a two-fold amplification of the expelled gas amount upon the “negative gas adsorption” transition.

Graphical abstract: Amplification of negative gas adsorption in a multivariate framework

Supplementary files

Article information

Article type
Communication
Submitted
24 Cax 2024
Accepted
20 Qas 2024
First published
21 Qas 2024

Chem. Commun., 2024,60, 7886-7889

Amplification of negative gas adsorption in a multivariate framework

F. Walenszus, V. Bon, A. De and S. Kaskel, Chem. Commun., 2024, 60, 7886 DOI: 10.1039/D4CC02540G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements