Issue 30, 2022

Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy

Abstract

A novel method for the oxidative C–S bond cleavage of benzyl thiols was developed. In situ-activated silver species enabled the controlled bond cleavage of benzyl thiols to afford aldehydes and ketones in the absence of a photocatalyst. The desired carbonyl compounds were obtained under mild reaction conditions via two different reaction pathways.

Graphical abstract: Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy

  • This article is part of the themed collection: New Talent

Supplementary files

Article information

Article type
Communication
Submitted
14 Qun 2022
Accepted
15 Nah 2022
First published
15 Nah 2022

Org. Biomol. Chem., 2022,20, 5938-5942

Visible-light-mediated oxidative C–S bond cleavage of benzyl thiols through in situ activation strategy

B. Hong and A. Lee, Org. Biomol. Chem., 2022, 20, 5938 DOI: 10.1039/D2OB00089J

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