Issue 21, 2019

Cobalt substitution in a flexible metal–organic framework: modulating a soft paddle-wheel unit for tunable gate-opening adsorption

Abstract

Developing feasible ways to achieve tunable gate-opening pressure (Pgo) while minimizing the side effects on the adsorption capacity and enthalpy is greatly desired for flexible MOFs. In this work, we focused on solving this issue by cobalt substitution. We showed the successful modulation of the energy required for the reversible transformation of a soft paddle-wheel so that the whole framework presented a substitution-dependent Pgo for CO2 adsorption.

Graphical abstract: Cobalt substitution in a flexible metal–organic framework: modulating a soft paddle-wheel unit for tunable gate-opening adsorption

Supplementary files

Article information

Article type
Communication
Submitted
09 Qun 2019
Accepted
08 Cig 2019
First published
25 Cig 2019

Dalton Trans., 2019,48, 7100-7104

Cobalt substitution in a flexible metal–organic framework: modulating a soft paddle-wheel unit for tunable gate-opening adsorption

J. Zhu, J. Chen, T. Qiu, M. Deng, Q. Zheng, Z. Chen, Y. Ling and Y. Zhou, Dalton Trans., 2019, 48, 7100 DOI: 10.1039/C9DT00115H

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