Issue 2, 2019

Porous graphene-coated stainless-steel fiber for direct immersion solid-phase microextraction of polycyclic aromatic hydrocarbons

Abstract

Porous graphene (PG), a type of graphene-based material with some holes/pores within the atomic plane, has recently attracted great attention. In this study, PG was prepared by combustion method and used as a new coating on stainless-steel fibers for direct immersion solid-phase microextraction (SPME) of polycyclic aromatic hydrocarbons (PAHs). Compared to polydimethylsiloxane-coated fiber, PG-coated SPME fiber showed higher enrichment factors (EFs), which increased with the number of aromatic rings. The excellent extraction ability was mainly due to the existence of nanopores. Moreover, PG also provided π–π stacking interaction and hydrophobic properties for better extraction efficiency of aromatic compounds. Additionally, PG-coated fibers exhibited good precision (<8%), wide linear ranges (0.002–10 μg L−1), and low limits of detection (1–2 ng L−1) for PAHs. The results verified that this novel PG coating was a promising sorbent for extraction and trace analysis of PAHs in environmental water samples.

Graphical abstract: Porous graphene-coated stainless-steel fiber for direct immersion solid-phase microextraction of polycyclic aromatic hydrocarbons

Supplementary files

Article information

Article type
Paper
Submitted
25 Dit 2018
Accepted
02 Kax 2018
First published
03 Kax 2018

Anal. Methods, 2019,11, 213-218

Porous graphene-coated stainless-steel fiber for direct immersion solid-phase microextraction of polycyclic aromatic hydrocarbons

Y. Huang, J. Chen, Z. Li, L. Wang, M. Guan and H. Qiu, Anal. Methods, 2019, 11, 213 DOI: 10.1039/C8AY02330A

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