Issue 39, 2017
From the journal:

Dalton Transactions

Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect†

Jeffrey S. Derrick,a   Yujeong Kim,bc   Hyeonwoo Tak,d   Kiyoung Park,*e   Jaeheung Cho, ORCID logo *d   Sun Hee Kim ORCID logo *bc  and  Mi Hee Lim ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Ulsan National Institute of Science and Technology (UNIST), Ulsan 44919, Republic of Korea
E-mail: mhlim@unist.ac.kr

b Western Seoul Center, Korea Basic Science Institute (KBSI), Seoul 03759, Republic of Korea
E-mail: shkim7@kbsi.re.kr

c Department of Chemistry and Nano Science, Ewha Womans University, Seoul 03760, Republic of Korea

d Department of Emerging Materials Science, Daegu Gyeongbuk Institute of Science and Technology (DGIST), Daegu 42988, Republic of Korea
E-mail: jaeheung@dgist.ac.kr

e Department of Chemistry, Korea Advanced Institute of Science and Technology (KAIST), Daejeon 34141, Republic of Korea
E-mail: kiyoung.park@kaist.ac.kr

Abstract

Metal(TMC) complexes (TMC = tetramethylcyclam) exclusively form trans-I diastereoisomers; thus, little is known about the trans-III isomers. Herein, we report a new method to prepare the trans-III-[Cu(TMC)]2+ complex via an anion effect. Our crystallographic, spectroscopic, and computational analyses validated that [Cu(TMC)](NO3)2 produced the trans-III complex, different from the trans-I structure of [Cu(TMC)](ClO4)2.

Graphical abstract: Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect

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Article information

DOI
https://doi.org/10.1039/C7DT01489A
Article type
Communication
Submitted
25 Agd 2017
Accepted
19 Cax 2017
First published
19 Cax 2017

Dalton Trans., 2017,46, 13166-13170

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Stereochemistry of metal tetramethylcyclam complexes directed by an unexpected anion effect

J. S. Derrick, Y. Kim, H. Tak, K. Park, J. Cho, S. H. Kim and M. H. Lim, Dalton Trans., 2017, 46, 13166 DOI: 10.1039/C7DT01489A

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