Issue 25, 2017

The proof is in the powder: revealing structural peculiarities in the Yb3Rh4Sn13 structure type

Abstract

Compounds adopting the Yb3Rh4Sn13 structure type have drawn attention because of the revelation of exotic states such as heavy fermion behavior, superconductivity, charge density wave, and quantum critical behavior. The prototypical structure has historically been modeled with a primitive cubic space group, Pm[3 with combining macron]n; however, structural studies have led to the realization of disordered atomic sites, requiring lower symmetry models. We will review the low symmetry models required to describe the structural distortions in the related Yb3Rh4Sn13 structure type. In addition, we present the structure determination of a new analogue, Lu3Ir4Ge13, which adopts a new structural model in I41/amd.

Graphical abstract: The proof is in the powder: revealing structural peculiarities in the Yb3Rh4Sn13 structure type

Supplementary files

Article information

Article type
Highlight
Submitted
28 Nah 2017
Accepted
18 Agd 2017
First published
18 Agd 2017

CrystEngComm, 2017,19, 3381-3391

The proof is in the powder: revealing structural peculiarities in the Yb3Rh4Sn13 structure type

I. W. H. Oswald, B. K. Rai, G. T. McCandless, E. Morosan and J. Y. Chan, CrystEngComm, 2017, 19, 3381 DOI: 10.1039/C7CE00419B

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements