Issue 1, 2017

Investigating the role of amine in InP nanocrystal synthesis: destabilizing cluster intermediates by Z-type ligand displacement

Abstract

The reaction of primary amines with In37P20(O2CR)51 is found to remove In(O2CR)3 subunits from In37P20(O2CR)51. This loss of Z-type ligands coincides with structural rearrangement to alleviate core strain and passivate phosphorus atoms. This result consolidates conflicting claims that primary amines both promote and retard precursor conversion rates for InP nanocrystals.

Graphical abstract: Investigating the role of amine in InP nanocrystal synthesis: destabilizing cluster intermediates by Z-type ligand displacement

Supplementary files

Article information

Article type
Communication
Submitted
30 Way 2016
Accepted
15 Xim 2016
First published
23 Xim 2016

Chem. Commun., 2017,53, 161-164

Investigating the role of amine in InP nanocrystal synthesis: destabilizing cluster intermediates by Z-type ligand displacement

D. C. Gary, A. Petrone, X. Li and B. M. Cossairt, Chem. Commun., 2017, 53, 161 DOI: 10.1039/C6CC07952K

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