Issue 17, 2015

A spectral sieve-based strategy for sensing inorganic and organic traces on solid surfaces using laser-induced breakdown spectroscopy

Abstract

Laser-induced breakdown spectroscopy (LIBS) has been used in recent years as a powerful tool for diagnosing dangerous residues on a variety of surfaces. While not itself straightforward, the task becomes much simpler when scenarios are custom designed. A more difficult question then arises when the scenario is unknown. The inherent ambiguity within the spectral resources gathered from this type of scenario presents a challenge to the analytical power of LIBS. Since no tools are available for confident identification of the optical emissions of the surface, the residue, or both, a novel method is now proposed based on sieving the spectral data. The strategy is based on threshold splitting of the spectral responses in the dataset using linear correlation measurements. The output of such splitting allows the emission spectrum of the surface to be predicted, thereby identifying uncorrelated emission signals with the potential residue. The strengths and weaknesses of the methodology are critically discussed. The suggested method allows accurate identification of the emission spectrum of the surface in scenarios for which 60% of the spectral resources correspond exclusively to a ‘clean’ surface. In the case of scenarios that are complex, in that the chemical composition of the surface and the residue are similar, the use of emission intensity ratios instead of considering the entire spectrum improves the methodology. The results presented suggest that this approach gives greater selectivity to the LIBS technique in the assessment of unknown targets in the recognition of explosives.

Graphical abstract: A spectral sieve-based strategy for sensing inorganic and organic traces on solid surfaces using laser-induced breakdown spectroscopy

Article information

Article type
Paper
Submitted
19 Nah 2015
Accepted
27 Agd 2015
First published
29 Agd 2015

Anal. Methods, 2015,7, 7280-7289

A spectral sieve-based strategy for sensing inorganic and organic traces on solid surfaces using laser-induced breakdown spectroscopy

J. Moros and J. J. Laserna, Anal. Methods, 2015, 7, 7280 DOI: 10.1039/C5AY00461F

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements