Issue 14, 2012
From the journal:

Dalton Transactions

Inclusion and dielectric properties of a vinylidene fluoride oligomer in coordination nanochannels†

Nobuhiro Yanai,a   Takashi Uemura,*a   Wataru Kosaka,b   Ryotaro Matsuda,b   Tetsuhiro Kodani,c   Meiten Koh,c   Takashi Kanemurac  and  Susumu Kitagawa*abd  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto, Japan
E-mail: uemura@sbchem.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2734

b ERATO Kitagawa Integrated Pores Project, Japan Science and Technology Agency (JST), Kyoto Research Park Bldg #3, Shimogyo-ku, Kyoto, Japan
E-mail: ryotaro.matsuda@kip.jst.go.jp
Fax: +81-75-325-3572
Tel: +81- 75-325-3571

c DAIKIN INDUSTRIES, LTD. Chemical Research & Development Center, Nishi Hitotsuya, Settsu, Osaka, Japan
E-mail: tetsuhiro.kodani@daikin.co.jp
Fax: +81-6-6349-4751
Tel: +81-6-6349-4751

d Institute for Integrated Cell-Material Sciences, Kyoto University, Yoshida, Sakyo-ku, Kyoto, Japan
E-mail: kitagawa@icems.kyoto-u.ac.jp
Fax: +81-75-383-2732
Tel: +81-75-383-2733

Abstract

The dynamics of oligo(vinylidene fluoride) (OVDF) confined in regular nanochannels of a porous coordination polymer (PCP) was studied by means of dielectric spectroscopy. The OVDF chains in the PCP nanopores showed two Arrhenius–type relaxation processes at lower temperatures than the relaxation temperature observed for the neat OVDF, showing the enhanced mobility of the confined OVDF.

Graphical abstract: Inclusion and dielectric properties of a vinylidene fluoride oligomer in coordination nanochannels

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Article information

DOI
https://doi.org/10.1039/C2DT11891B
Article type
Paper
Submitted
07 Oct 2011
Accepted
22 Dec 2011
First published
07 Feb 2012

Dalton Trans., 2012,41, 4195-4198

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Inclusion and dielectric properties of a vinylidene fluoride oligomer in coordination nanochannels

N. Yanai, T. Uemura, W. Kosaka, R. Matsuda, T. Kodani, M. Koh, T. Kanemura and S. Kitagawa, Dalton Trans., 2012, 41, 4195 DOI: 10.1039/C2DT11891B

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