Issue 21, 2011

Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch

Abstract

Mild Lewis acids enhance the rate of the thermal conversion of vinylheptafulvene (VHF) to dihydroazulene (DHA). In the absence of light, stronger Lewis acids promote the otherwise photoinduced DHA to VHF conversion.

Graphical abstract: Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch

Supplementary files

Article information

Article type
Communication
Submitted
11 Nah 2011
Accepted
01 Agd 2011
First published
18 Agd 2011

Chem. Commun., 2011,47, 6102-6104

Lewis acid enhanced switching of the 1,1-dicyanodihydroazulene/vinylheptafulvene photo/thermoswitch

C. R. Parker, C. G. Tortzen, S. L. Broman, M. Schau-Magnussen, K. Kilså and M. B. Nielsen, Chem. Commun., 2011, 47, 6102 DOI: 10.1039/C1CC10804B

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