Solventless thermolysis of bismuth(III) dithiolates Bi2[S(CH2)nS]3 at 145–170 oC is designed to prepare cyclic disulfides ((CH2)nS2, n = 3, 4 and 5) with 95–100% conversion efficiency, whose production is enabled by their low formation energy and a dithiyl diradical cyclization pathway.
X. Liu, T. Wang, L. Li and J. Wang, Chem. Commun., 2025, Accepted Manuscript , DOI: 10.1039/D5CC01572C
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