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Given the significance of organogermanium compounds in materials science, medicinal chemistry, and synthetic chemistry, transition-metal-catalyzed C–Ge coupling reactions have become a focal point in organic synthesis, driving innovation in organogermane chemistry. This review examines the development and recent advancements in transition-metal-catalyzed C–Ge coupling reactions, aiming to provide new insights and inspire further research and applications in this rapidly evolving field.

Graphical abstract: Transition-metal-catalyzed C–Ge coupling reactions

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