Issue 24, 2024

Homo- and heterobimetallic transition metal cluster derived from [Cp*Fe(η5-E5)] (E = P, As) – unprecedented structural motifs of the resulting polypnictogen ligands

Abstract

A general synthetic procedure to neutral homo- and heterobimetallic cage compounds exhibiting various structural motifs of the polypnictogen ligands starting from [Cp*Fe(η5-E5)] (E = P (1), As (2); Cp* = C5Me5) is reported. The impact of the implemented transition metal precursors {Cp′′′M} (M = Cr, Mn, Fe, Ni; Cp′′′ = 1,2,4-tBu3C5H2) emphasises the variability of the isolated complexes exhibiting a broad variety of structural motifs of the pnictogen ligands. Spectroscopic, crystallographic, and theoretical investigations provide insight into the structure of the partially unprecedented polypnictogen ligands.

Graphical abstract: Homo- and heterobimetallic transition metal cluster derived from [Cp*Fe(η5-E5)] (E = P, As) – unprecedented structural motifs of the resulting polypnictogen ligands

Supplementary files

Article information

Article type
Paper
Submitted
19 Agd 2024
Accepted
24 Cax 2024
First published
27 Cax 2024

Dalton Trans., 2024,53, 10201-10207

Homo- and heterobimetallic transition metal cluster derived from [Cp*Fe(η5-E5)] (E = P, As) – unprecedented structural motifs of the resulting polypnictogen ligands

S. B. Dinauer, R. Szlosek, M. Piesch, G. Balázs, S. Reichl, L. Prock, C. Riesinger, M. D. Walter and M. Scheer, Dalton Trans., 2024, 53, 10201 DOI: 10.1039/D4DT01160K

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements