Robust luminogens as cutting-edge tools for efficient light emission in recent decades

Abstract

Blue luminogens play a vital role in white lighting and potential metal-free fluorescent materials and their high-lying excited states contribute to harvesting triplet excitons in devices. However, in TADF-OLEDs (ΔE_ST < 0.1 eV), although T₁ excitons transfer to S₁via RISC with 100% IQE, the longer lifetime of blue TADF suffers from efficiency roll-off (RO). In this case, hybridized local and charge transfer (HLCT) materials have attracted significant interest in lighting owing to their 100% hot exciton harvesting and enhanced efficiency. Both academics and industrialists widely use the HLCT strategy to improve the efficiency of fluorescent organic light-emitting diodes (FOLEDs) by harvesting dark triplet excitons through the RISC process. Aggregation-induced emissive materials (AIEgens) possess tight packing in the aggregation state, and twisted AIEgens with HLCT behaviour have a shortened conjugation length, inducing blue emission and making them suitable candidates for OLED applications. TTA-OLEDs are used in commercial BOLEDs because of their moderate efficiency and reasonable operation lifetime. In this review, we discuss the devices based on TTA fluorophores, TADF fluorophores, HLCT fluorophores, AIEgens and HLCT-sensitized fluorophores (HLCT-SF), which break through the statistical limitations.