Issue 9, 2023
From the journal:

Organic Chemistry Frontiers

Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions†

Ding-Xing Wang, ORCID logo a   Hui Wang,a   Yao Xu,a   Chi Zhang ORCID logo *a  and  Chao Feng ORCID logo *a  

* Corresponding authors

a Technical Institute of Fluorochemistry (TIF), Institute of Advanced Synthesis (IAS) State Key Laboratory of Material-Oriented Chemical Engineering, School of Chemistry and Molecular Engineering, Nanjing Tech University, 30 South Puzhu Road, Nanjing 211816, P. R. China
E-mail: 202110007083@njtech.edu.cn, iamcfeng@njtech.edu.cn

Abstract

A photoredox catalysed 1,3-oxylallylation of aryl cyclopropanes was accomplished by reaction with carboxylic acids and allyl sulfones. The redox-neutral reaction proceeded in a highly regioselective manner under mild conditions with good functional group compatibility. Simple operation and successful application to the late-stage functionalization of several natural product and pharmaceutical molecule related carboxylic acids add extra merits to the current protocol.

Graphical abstract: Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

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Article information

DOI
https://doi.org/10.1039/D3QO00281K
Article type
Research Article
Submitted
23 Nah 2023
Accepted
24 Cig 2023
First published
01 Agd 2023

Org. Chem. Front., 2023,10, 2147-2154

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Visible light mediated regioselective 1,3-oxylallylation of aryl cyclopropanes under redox-neutral conditions

D. Wang, H. Wang, Y. Xu, C. Zhang and C. Feng, Org. Chem. Front., 2023, 10, 2147 DOI: 10.1039/D3QO00281K

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