Issue 7, 2022
From the journal:

Journal of Materials Chemistry C

Single crystal field-effect transistor of tetrabenzoporphyrin with a one-dimensionally extended columnar packing motif exhibiting efficient charge transport properties†

Juanjuan Zhu,a   Hironobu Hayashi, ORCID logo *a   Meng Chen,b   Chengyi Xiao, ORCID logo b   Kyohei Matsuo, ORCID logo a   Naoki Aratani, ORCID logo a   Lei Zhang*b  and  Hiroko Yamada ORCID logo *a  

* Corresponding authors

a Division of Materials Science, Nara Institute of Science and Technology (NAIST), 8916-5 Takayama-cho, Ikoma, Nara 630-0192, Japan
E-mail: hhayashi@ms.naist.jp, hyamada@ms.naist.jp

b Beijing Advanced Innovation Center for Soft Matter Science and Engineering & State Key Laboratory of Organic–Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, P. R. China
E-mail: zhl@buct.edu.cn

Abstract

5,15-Bis(triisopropylsilyl)ethynyltetrabenzoporphyrin (TIPS-H2BP) gave a one-dimensionally extended columnar packing motif. The single crystal field-effect transistor of TIPS-H2BP exhibited clearly better hole mobility (2.16 cm2 V−1 s−1) than its metal complexes (ca. 0.1 cm2 V−1 s−1), with efficient charge transport through π–π stacking along the tetrabenzoporphyrin units.

Graphical abstract: Single crystal field-effect transistor of tetrabenzoporphyrin with a one-dimensionally extended columnar packing motif exhibiting efficient charge transport properties

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Article information

DOI
https://doi.org/10.1039/D1TC03547A
Article type
Communication
Submitted
30 Qad 2021
Accepted
08 Way 2021
First published
09 Way 2021

J. Mater. Chem. C, 2022,10, 2527-2531

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Single crystal field-effect transistor of tetrabenzoporphyrin with a one-dimensionally extended columnar packing motif exhibiting efficient charge transport properties

J. Zhu, H. Hayashi, M. Chen, C. Xiao, K. Matsuo, N. Aratani, L. Zhang and H. Yamada, J. Mater. Chem. C, 2022, 10, 2527 DOI: 10.1039/D1TC03547A

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