Issue 38, 2022

Metallacycle-cored fluorescent supramolecular polymer networks for the detection of acidic environments

Abstract

Despite the challenges, supramolecular polymers (SPs) have received significant attention. In this study, pH-responsive fluorescent SPs were prepared by a bottom-up strategy. The rhombohedral metallacycle-cored supramolecular coordination complex (SCC) was first prepared by metal–ligand coordination between the 120° pyridinedione boron difluoride and the 60° crown ether-based platinum, which then interacted with ammonium salt-containing covalent polymers to form SP networks. These networks can potentially be used for the detection of organic acid solutions and inorganic acid vapours.

Graphical abstract: Metallacycle-cored fluorescent supramolecular polymer networks for the detection of acidic environments

Supplementary files

Article information

Article type
Communication
Submitted
26 Leq 2022
Accepted
23 Way 2022
First published
24 Way 2022

Dalton Trans., 2022,51, 14434-14438

Metallacycle-cored fluorescent supramolecular polymer networks for the detection of acidic environments

H. Jia, J. Zhang, Y. Li, D. Xu and S. Yin, Dalton Trans., 2022, 51, 14434 DOI: 10.1039/D2DT02783F

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