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Chiral oligopeptide-naphthalene/Eu(III) hybridized luminophores emit strong circularly polarised solution-state luminescence (CPL) from Eu(III) at 592 and 614 nm (|gCPL| ≤ 2.1 × 10−2). Although the peptide ligands have matching absolute configurations, the CPL sign is controllable by varying the number of naphthalene units and peptide/Eu(III) coordination ratio.

Graphical abstract: Circularly polarised luminescence (CPL) control of oligopeptide–Eu(iii) hybridized luminophores by interaction with peptide side chains

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