Issue 45, 2020
From the journal:

Dalton Transactions

Reductive halocyclosilazane polymerization†

Carlton P. Folster, ORCID logo a   Phi N. Nguyena  and  Rebekka S. Klausen ORCID logo *a  

* Corresponding authors

a Department of Chemistry, Johns Hopkins University, 3400 N. Charles St, Baltimore, MD 21218, USA
E-mail: klausen@jhu.edu

Abstract

The synthesis of a chloro-functionalized six-membered cyclosilazane (Si5N) is reported. Subsequent reductive polymerizations yielded low molecular weight polysilazanes. 1H and 29Si NMR characterization suggest the identity of the reducing metal influences the polysilazane structure. Optical characterization is consistent with extended σ-conjugation upon polymerization.

Graphical abstract: Reductive halocyclosilazane polymerization

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C9DT04468J
Article type
Paper
Submitted
19 Xim 2019
Accepted
23 Qun 2020
First published
24 Qun 2020

Dalton Trans., 2020,49, 16125-16132

Author version available


Download author version (PDF)

Permissions

Request permissions

Reductive halocyclosilazane polymerization

C. P. Folster, P. N. Nguyen and R. S. Klausen, Dalton Trans., 2020, 49, 16125 DOI: 10.1039/C9DT04468J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements