Issue 83, 2020

All-metal Baird aromaticity

Abstract

Baird's rule has been applied to a large scope of organic molecular systems for rationalizing the aromaticity reversal in the lowest-lying triplet state. In this study, we demonstrate that Baird's rule can also be extended to all-metal systems with σ- and π-aromaticity.

Graphical abstract: All-metal Baird aromaticity

Supplementary files

Article information

Article type
Communication
Submitted
17 Leq 2020
Accepted
07 Way 2020
First published
07 Way 2020

Chem. Commun., 2020,56, 12522-12525

All-metal Baird aromaticity

D. Chen, D. W. Szczepanik, J. Zhu and M. Solà, Chem. Commun., 2020, 56, 12522 DOI: 10.1039/D0CC05586G

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