Issue 25, 2019

meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization

Abstract

A concise and convenient synthetic methodology leading to an unambiguous isolation of two hitherto unknown highly stable single conformers of meso-aryl substituted unorthodox 5,10-porphodimethenes has been developed by the inclusion of N-methyl pyrrole units with α,β and β,β-linkages into the core of heterocyclic macrocycles.

Graphical abstract: meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization

Supplementary files

Article information

Article type
Communication
Submitted
08 Cax 2019
Accepted
31 Cax 2019
First published
31 Cax 2019

Org. Biomol. Chem., 2019,17, 6131-6135

meso-Aryl substituted stable unorthodox 5,10-porphodimethenes with α,β and β,β-N-methyl pyrrole connectivities: synthesis and spectroscopic, solid state and theoretical characterization

N. Halder, M. Sangeetha, D. Usharani and H. Rath, Org. Biomol. Chem., 2019, 17, 6131 DOI: 10.1039/C9OB01062A

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