CdS nanodroplets over silica microballs for efficient room-temperature LPG detection

Abstract

An efficient room-temperature sensor for liquified petroleum gas (LPG) is demonstrated by employing CdS:SiO₂ nanocomposite thin films (CdS:SiO₂ NCTFs) for the first time. CdS:SiO₂ NCTFs exhibiting the morphology of CdS nanodroplets on micron-sized spherical balls of SiO₂ were deposited using the pulsed laser deposition (PLD) method, followed by thermal annealing. The targets of chemically synthesized CdS nanoparticles and commercially procured SiO₂ were used to deposit CdS:SiO₂ NCTFs by swapping them at a frequency ratio of 2 : 8 laser pulses per second, which was selected to ensure nearly the same ratio of CdS to SiO₂ in NCTFs and was confirmed by X-ray photoelectron spectroscopy. Sensor fabrication was carried out on bare CdS thin films and as-grown and annealed CdS:SiO₂ NCTFs using an Ag paste over Pt interdigitated electrodes to measure the resistance of the films in air and in the presence of reducing gases, viz., LPG, H₂, H₂S, NO₂ and CO₂. The present sensor showed the highest response for LPG and the observed value was ∼71% for 1000 ppm at RT with the response time and recovery time of 91 s and 140 s, respectively. The response of the sensor was sustainable up to 75 °C and then decreased, which suggested its promising usage for low-temperature regions as well. A low detection limit of 20 ppm at RT for LPG was determined; however, a significant response was observed only at 50 ppm. The sensor retained ∼96% of its initial response even after 8 weeks and that too at 100 °C. The present LPG sensor is highly promising due to its high sensitivity, low detection limit, low response and recovery times, good reproducibility, RT operation and simple fabrication technique.