Issue 17, 2019

Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides)

Abstract

Exposure of bis-amidinate and -guanidinate supported thorium dialkyl complexes to dioxygen results in facile oxygen atom insertion and formation of the corresponding thorium bis(alkoxide) species. Preliminary mechanistic studies suggest a radical propagation mechanism is operative. All new complexes were fully characterized by 1H and 13C NMR spectroscopy, IR, EA and X-ray crystallography.

Graphical abstract: Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides)

Supplementary files

Article information

Article type
Paper
Submitted
22 Nah 2019
Accepted
26 Cig 2019
First published
27 Cig 2019

Dalton Trans., 2019,48, 5569-5573

Author version available

Dioxygen reacts with metal–carbon bonds in thorium dialkyls to produce bis(alkoxides)

N. S. Settineri, A. A. Shiau and J. Arnold, Dalton Trans., 2019, 48, 5569 DOI: 10.1039/C9DT00811J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements