Issue 21, 2019

Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C–C coupling reaction

Abstract

A 2D porous MOF, {[Cu(1,2,3-btc)(bpe)(H2O)]·H2O}n (1), has been synthesized using a mixed linker system. The structural determination showed non-coordinated carboxylate groups decorating the pore surface. The desolvated MOF (1a) with pendant carboxylate groups was used as a template for the stabilization of Pd nps (2–3 nm) and the resulting composite Pd(0)@1a showed efficient catalytic activity for the Suzuki–Miyaura C–C coupling reaction.

Graphical abstract: Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C–C coupling reaction

Supplementary files

Article information

Article type
Communication
Submitted
03 Kax 2018
Accepted
26 Cig 2019
First published
26 Cig 2019

Dalton Trans., 2019,48, 7117-7121

Polar functional groups anchored to a 2D MOF template for the stabilization of Pd(0) nps for the catalytic C–C coupling reaction

S. A. Adalikwu, V. S. Mothika, A. Hazra and T. K. Maji, Dalton Trans., 2019, 48, 7117 DOI: 10.1039/C8DT04766A

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