Issue 43, 2019

Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

Abstract

Step-scan Fourier-transform infrared spectroscopy was used to monitor the photochemical reactions following the 266 nm-photolysis of aqueous ferrioxalate solutions on microsecond-to-millisecond time scales. Together with most recent observations from ultrafast infrared spectroscopy the reported results finally disclose the full molecular-level mechanism of a photochemical system that is widely known as the Hatchard–Parker actinometer.

Graphical abstract: Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

Article information

Article type
Communication
Submitted
23 Way 2019
Accepted
23 Dit 2019
First published
23 Dit 2019

Phys. Chem. Chem. Phys., 2019,21, 23803-23807

Time-resolved Fourier-transform infrared spectroscopy reveals the hidden bimolecular process of the ferrioxalate actinometer

F. H. Pilz, J. Lindner and P. Vöhringer, Phys. Chem. Chem. Phys., 2019, 21, 23803 DOI: 10.1039/C9CP05233J

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements