Issue 20, 2018

Covalent organic frameworks: a platform for the experimental establishment of the influence of intermolecular distance on phosphorescence

Abstract

We report herein a two-dimensional (2D) COF (BZL-COF) based on an representative crystallization-induced phosphorescence (CIP) organic phosphor, benzil, for phosphorescence study. In BZL-COF, the CIP building blocks are arranged in an eclipsed fashion similar to the face-to-face mode in H-aggregates. The phosphorescence behavior significantly changed from on to off at cryogenic temperature upon altering the interlayer distance from 3.7 Å to 3.4 Å by removing the solvent molecules trapped between the 2D polymeric layers. In comparison, a single crystal of the model compound that adopts an H-type aggregation with an intermolecular distance of 4.1 Å can exhibit strong phosphorescence at room temperature. Our study shows that, in addition to the restriction of intramolecular rotation and H-aggregated packing, suitable intermolecular distance also plays a vital role in enhancing the phosphorescence.

Graphical abstract: Covalent organic frameworks: a platform for the experimental establishment of the influence of intermolecular distance on phosphorescence

Supplementary files

Article information

Article type
Communication
Submitted
04 Agd 2018
Accepted
08 Cax 2018
First published
08 Cax 2018

J. Mater. Chem. C, 2018,6, 5369-5374

Covalent organic frameworks: a platform for the experimental establishment of the influence of intermolecular distance on phosphorescence

S. Wang, L. Ma, Q. Wang, P. Shao, D. Ma, S. Yuan, P. Lei, P. Li, X. Feng and B. Wang, J. Mater. Chem. C, 2018, 6, 5369 DOI: 10.1039/C8TC01559G

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements