Issue 11, 2018

N-rich carbon coated CoSnO3 derived from in situ construction of a Co–MOF with enhanced sodium storage performance

Abstract

In this study, N-rich carbon coated interconnected CoSnO3 nanoboxes (CoSnO3–NCs) with controllable amounts of N-rich carbon ranging from 7.5% to 24.6% were firstly prepared by the carbonization of CoSnO3–MOFs. Impressively, the preparation of CoSnO3–MOFs has been realized for the first time by directly utilizing CoSnO3 as the precursor under solvent-free conditions, bridging between the cobalt(II) ion in the skeleton of CoSnO3 and the 2-methylimidazole. Interestingly, the growth of these CoSnO3–MOFs can be manipulated by changing the amount of 2-methylimidazole used, resulting in a tunable N-rich carbon content. Furthermore, the electrochemical storage behavior of these materials for SIBs was initially explored. Compared with the pure CoSnO3, the as-resulted CoSnO3–NC materials showed largely enhanced sodium storage performance with a reversible capacity of 493.9 mA h g−1 at a current density of 0.1 A g−1 after 100 cycles. Moreover, the as-prepared materials showed an excellent high rate storage performance with a remarkable capacity of 273.8 mA h g−1 at 1 A g−1 after 1000 cycles. This work provides a new approach for constructing Co–MOFs as well as providing an efficient N-rich carbon-coating route, which may be expanded to other Co-based oxides and can greatly expand the development of new species of Co-based MOFs.

Graphical abstract: N-rich carbon coated CoSnO3 derived from in situ construction of a Co–MOF with enhanced sodium storage performance

Supplementary files

Article information

Article type
Paper
Submitted
28 Xim 2017
Accepted
19 Nah 2018
First published
19 Nah 2018

J. Mater. Chem. A, 2018,6, 4839-4847

N-rich carbon coated CoSnO3 derived from in situ construction of a Co–MOF with enhanced sodium storage performance

G. Zou, H. Hou, G. Zhao, P. Ge, D. Yin and X. Ji, J. Mater. Chem. A, 2018, 6, 4839 DOI: 10.1039/C7TA10448K

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