Issue 34, 2018

Octacyanometallate qubit candidates

Abstract

We report the temperature dependence of the spin dynamics of the octacyanometallates [Mo(CN)8]3− and [W(CN)8]3−. At 5 K, these complexes display remarkably long spin–lattice relaxation times of 1.05 s, and 0.63 s, respectively. We probe the contributing factors to the spin relaxation and demonstrate the impact of spin–orbit coupling as a handle to tune vibrationally mediated spin–lattice relaxation.

Graphical abstract: Octacyanometallate qubit candidates

Supplementary files

Article information

Article type
Communication
Submitted
05 Qas 2018
Accepted
04 Qad 2018
First published
11 Qad 2018

Dalton Trans., 2018,47, 11744-11748

Author version available

Octacyanometallate qubit candidates

T. J. Pearson, D. W. Laorenza, M. D. Krzyaniak, M. R. Wasielewski and D. E. Freedman, Dalton Trans., 2018, 47, 11744 DOI: 10.1039/C8DT02312C

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements