Issue 22, 2017

Improved dispersion of transition metals in mesoporous materials through a polymer-assisted melt infiltration method

Abstract

Melt infiltration (MI) has been described as an effective way to disperse transition metals (TM) in ordered mesoporous supports. The alternative method described here is based on the infiltration of molten precursors into the support pores in the presence of a support polymer porogen. The resulting materials contain metal oxide particles (metallic particles after reduction) smaller than 2 nm, dispersed within the support micropores, which prove to be stable upon reduction up to 900 °C and to exhibit improved catalytic performances for the hydrogenation of cinnamaldehyde due to the high fraction of the active metal exposed.

Graphical abstract: Improved dispersion of transition metals in mesoporous materials through a polymer-assisted melt infiltration method

Supplementary files

Article information

Article type
Paper
Submitted
15 Cax 2017
Accepted
13 Way 2017
First published
14 Way 2017

Catal. Sci. Technol., 2017,7, 5448-5456

Improved dispersion of transition metals in mesoporous materials through a polymer-assisted melt infiltration method

C. Ciotonea, B. Dragoi, A. Ungureanu, C. Catrinescu, S. Petit, H. Alamdari, E. Marceau, E. Dumitriu and S. Royer, Catal. Sci. Technol., 2017, 7, 5448 DOI: 10.1039/C7CY00963A

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