Issue 30, 2015

Heating-rate dependence of spin-crossover hysteresis observed in an iron(ii) complex having tris(2-pyridyl)methanol

Abstract

Me4N[Fe(py3COH)(NCS)3](H2O) showed an abrupt spin-crossover with thermal hysteresis, and temperature-scan rate dependence was recorded upon heating at 10–0.02 K min−1. At the slowest scan the product of magnetic susceptibility and temperature initially increased at 246 K, then decreased at around 250 K and finally increased again to reach the high-spin state at around 280 K. A polymorphic spin-crossover model is plausible.

Graphical abstract: Heating-rate dependence of spin-crossover hysteresis observed in an iron(ii) complex having tris(2-pyridyl)methanol

Supplementary files

Article information

Article type
Communication
Submitted
02 Agd 2015
Accepted
26 Agd 2015
First published
27 Agd 2015

J. Mater. Chem. C, 2015,3, 7784-7787

Author version available

Heating-rate dependence of spin-crossover hysteresis observed in an iron(II) complex having tris(2-pyridyl)methanol

M. Yamasaki and T. Ishida, J. Mater. Chem. C, 2015, 3, 7784 DOI: 10.1039/C5TC00926J

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